A method for making a functional structural body includes a skeletal body of a porous structure composed of a zeolite-type compound, and at least one type of metallic nanoparticles present in the skeletal body, the skeletal body having channels connecting with each other, the metallic nanoparticles being present at least in the channels of the skeletal body.

The present disclosure provides perovskite catalytic materials and catalysts comprising platinum-group metals and perovskites. These catalysts may be used as oxygen storage materials with automotive applications, such as three-way catalysts. They are also useful for water or CO.sub.2 reduction, or thermochemical energy storage.

A supported catalyst for decomposing an organic substance that includes a carrier and catalyst particles supported on the carrier. The catalyst particles contain a perovskite-type composite oxide represented by A.sub.xB.sub.yM.sub.zO.sub.w, where A contains at least one of Ba and Sr, B contains Zr, M is at least one of Mn, Co, Ni, and Fe, y+z=1, x>1, z<0.4, and w is a positive value that satisfies electrical neutrality. An organic substance decomposition rate after the supported catalyst is subjected to a heat treatment at 950° C. for 48 hours is greater than 0.97 when the organic substance decomposition rate before the heat treatment is regarded as 1, and an amount of the catalyst particles peeled off when the supported catalyst is ultrasonicated in water at 28 kHz and 220 W for 15 minutes is less than 1 wt % of the catalyst particles before untrasonication.

The structured catalyst for oxidation for exhaust gas purification includes a support having a porous structure constituted by a zeolite-type compound, and at least one type of oxidation catalyst that is present in the support and selected from the group consisting of metal and metal oxide, the support having channels that communicate with each other, and the oxidation catalyst being present in at least the channels of the support.

The present disclosure provides perovskite catalytic materials and catalysts comprising platinum-group metals and perovskites. These catalysts may be used as oxygen storage materials with automotive applications, such as three-way catalysts. They are also useful for water or CO.sub.2 reduction, or thermochemical energy storage.

An organic matter decomposition catalyst that contains a perovskite type complex oxide represented by A.sub.xB.sub.yM.sub.zO.sub.w, wherein A contains 90 at % or more of at least one element selected from the group consisting of Ba and Sr, B contains 80 at % or more of Zr, M is at least one element selected from the group consisting of Mn, Co, Ni, and Fe, y+z=1, x>1, z<0.4, and w is a positive value that satisfies electrical neutrality.

A carbon dioxide recovery system separates CO.sub.2 from gas containing CO.sub.2 via an electrochemical reaction. The carbon dioxide recovery system includes an electrochemical cell including a working electrode and a counter electrode. The working electrode includes CO.sub.2 adsorbent. The CO.sub.2 adsorbent adsorbs CO.sub.2 via an oxygen reduction reaction by using electrons supplied from the counter electrode to the working electrode when a first voltage is applied between the working electrode and the counter electrode. The oxygen reduction reaction produces active oxygen via reduction of O.sub.2. The CO.sub.2 adsorbent desorbs CO.sub.2 by discharging electrons from the working electrode to the counter electrode when a second voltage different from the first voltage is applied between the working electrode and the counter electrode. The CO.sub.2 adsorbent has a promoting function for promoting the oxygen reduction reaction.

Compositions, articles, and methods related to a three-way-catalyst composition comprising a perovskite-type compound of formula (I): La.sub.zB.sub.1-qB′.sub.qO.sub.3±δ or formula (II):[BO.sub.x].sub.y:[La.sub.zBO.sub.3±δ].sub.1-y and a non-redox active component; wherein B or B′ is Fe, Mn, Co, Ni, Cu, Ti, or Zr; q is in a range from about 0 to about 0.5; x is from about 1 to about 2.5; y is from about 1 to about 30 wt %; z is about 0.6 to about 1.1; δ is in a range from about 0 to about 0.6.

A catalyst for decomposing an organic substance, the catalyst having a body which has a plurality of pores and the body contains a perovskite-type composite oxide represented by A.sub.xB.sub.yM.sub.zO.sub.w, where the A contains at least one selected from Ba and Sr, the B contains Zr, the M is at least one selected from Mn, Co, Ni, and Fe, 1.001≤x≤1.1, 0.05≤z≤0.2, y+z=1, and w is a positive value that satisfies electrical neutrality. The average pore diameter of the plurality of pores is 49 nm to 260 nm and the pore volume of each of the plurality of pores is 0.08 cm.sup.3/g to 0.37 cm.sup.3/g.

The present disclosure provides perovskite catalytic materials and catalysts comprising platinum-group metals and perovskites. These catalysts may be used as oxygen storage materials with automotive applications, such as three-way catalysts. They are also useful for water or CO.sub.2 reduction, or thermochemical energy storage.