A method for simultaneous removal of NO and carbonic particles and inorganic dust from flue gases in a reactor with a catalyst for direct decomposition of nitric oxide located on a metallic monolith, includes tangential introduction of flue gases to the reactor circumference. Flue gases flow rotationally and downwards in the reactor in contact with an undulating surface of metallic foil located on an inner wall of the reactor chamber and in contact with the catalyst on a spiral band falling to the lower part of the reactor, and next flue gases jet direction counter-currently to a cylindrical inner chamber containing slices of the monolithic catalyst disturbing laminar flow of the flue gases jet. The reactor arrangement provides for simultaneous removal of NO and carbon particles and inorganic dust from flue gases.

Catalyst material comprising a ternary spinel mixed oxide for treatment of an exhaust gas stream via direct decomposition removal of NOx to N.sub.2 and O.sub.2. The low temperature (from about 400 C. to about 650 C.), direct decomposition is accomplished without the need of a reductant molecule. In one example, Mn may be incorporated into metal oxide, such as Cu.sub.yCo.sub.3-yO.sub.4 spinel oxide, synthesized using co-precipitation techniques.

Described are catalytic articles comprising a substrate having a washcoat on the substrate, the washcoat containing a catalytic component having a first average (D50) particle size and a functional binder component having a second average (D50) particle size in the range of about 10 nm to about 1000 nm, wherein the ratio of the first average (D50) particle size to the second average (D50) particle size is greater than about 10:1. The catalytic articles are useful in methods and systems to purify exhaust gas streams from an engine.

Described are catalytic articles comprising a substrate having a washcoat on the substrate, the washcoat containing a catalytic component having a first average (D50) particle size and a functional binder component having a second average (D50) particle size in the range of about 10 nm to about 1000 nm, wherein the ratio of the first average (D50) particle size to the second average (D50) particle size is greater than about 10:1. The catalytic articles are useful in methods and systems to purify exhaust gas streams from an engine.

A co-catalyst system for the removal of NO.sub.x from an exhaust gas stream has a layered oxide and a spinel of formula Ni.sub.0.15Co.sub.0.85CoAlO.sub.4. The system converts to nitric oxide to nitrogen gas with high product specificity. The layered oxide is configured to convert NO.sub.x in the exhaust gas stream to an N.sub.2O intermediate, and the spinel is configured to convert the N.sub.2O intermediate to N.sub.2.

Systems and methods of the present invention related to an exhaust gas purification system comprising: (a) a particulate filter including an inlet and an outlet with an axial length L therebetween, wherein the filter includes an oxidation catalyst capable of generating NO.sub.2 under lean burn conditions; (b) an injector for injecting ammonia or a compound decomposable to ammonia into the exhaust gas, located downstream of the filter; and (c) a downstream catalyst comprising a selective catalytic reduction (SCR) catalyst, located downstream of the injector.

An exhaust gas-purifying catalyst of the present invention comprising a substrate, a first catalyst layer comprising a first supported catalyst, a second supported catalyst, palladium, and a first nitrogen oxide storage material, and a second catalyst layer comprising a third supported catalyst having an alloying rate of platinum and palladium of 40% or more and a second nitrogen oxide storage material, wherein a mass of the second supported catalyst is greater than a mass of the first supported catalyst and greater than a mass of the third supported catalyst.

An exhaust gas treatment system (1) comprises a catalyst article (5) for the treatment of an exhaust gas, the catalyst article (5) comprising a non-metallic substrate (20) comprising a plurality of catalytically-active transition-metal-doped iron oxide magnetic particles (45), and an inductive heater (70) for inductively heating the plurality of catalytically-active magnetic particles by applying an alternating magnetic field.

A NO.sub.x adsorber catalyst and its use in an emission treatment system for internal combustion engines, is disclosed. The NO.sub.x adsorber catalyst comprises a first layer consisting essentially of a support material, one or more platinum group metals disposed on the support material, and a NO.sub.x storage material.

Process for preparing a catalyst or a trapping mass comprising the following steps: bringing a porous oxide support into contact with a metal salt comprising at least one metal belonging to groups VIB, VIIB, VIIIB, IB or IIB, of which the melting point of said metal salt is between 20 C. and 150 C., for a period of between 5 minutes and 5 hours in order to form a solid mixture, the weight ratio of said metal salt to said porous oxide support being between 0.1 and 1; heating the solid mixture with stirring at a temperature between the melting point of said metal salt and 200 C. and for 5 minutes to 12 hours; calcining the solid obtained in the preceding step at a temperature above 200 C. and below or equal to 1100 C. under an inert atmosphere or under an oxygen-containing atmosphere.