B01D2255/504

Diesel oxidation catalyst and exhaust system

An exhaust system for a diesel engine comprises an oxidation catalyst for treating an exhaust gas from the diesel engine and an emissions control device, wherein the oxidation catalyst comprises: a first washcoat zone for oxidizing carbon monoxide (CO) and hydrocarbons (HCs), wherein the first washcoat zone comprises a first platinum group metal (PGM), which is a combination of platinum and palladium, a first support material and a hydrocarbon adsorbent material, which is a zeolite, and wherein the first washcoat zone does not comprise rhodium and is substantially free of manganese or an oxide thereof; a second washcoat zone for oxidizing nitric oxide (NO), wherein the second washcoat zone comprises platinum (Pt) and manganese (Mn) disposed or supported on a second support material, wherein the second support material comprises a refractory metal oxide, wherein the refractory metal oxide is silica-alumina or an alumina doped with silica in a total amount of 0.5 to 45% by weight of the alumina, and wherein the second washcoat zone does not comprise a hydrocarbon adsorbent material, which is a zeolite; and a substrate having and inlet end and an outlet end, and wherein the second washcoat zone is disposed at an outlet end of the substrate, and the first washcoat zone disposed at an inlet end of the substrate; and wherein the emissions control device is a selective catalytic reduction (SCR) catalyst, a selective catalytic reduction filter catalyst, a diesel particulate filter (DPF), or a catalyzed soot filter (CSF).

ASC/DEC with rear-concentrated exotherm generation

A catalyst article including a substrate with an inlet side and an outlet side, a first zone and a second zone, where the first zone includes an ammonia slip catalyst (ASC) comprising a platinum group metal on a support and a first SCR catalyst; where the second zone includes a catalyst selected from the group consisting of a diesel oxidation catalyst (DOC) and a diesel exotherm catalyst (DEC); and where the first zone is located upstream of the second zone. The first zone may include a bottom layer with a blend of: (1) the platinum group metal on a support and (2) the first SCR catalyst; and a top layer comprising a second SCR catalyst, the top layer located over the bottom layer.

Catalyst article for use in an emission treatment system

A catalyst article for treating a flow of a combustion exhaust gas comprises: a catalytically active substrate comprising one or more channels extending along an axial length thereof through which, in use, a combustion exhaust gas flows, the one or more channels having a first surface for contacting a flow of combustion exhaust gas; wherein the substrate is formed of an extruded vanadium-containing SCR catalyst material, wherein a first layer is provided on at least a portion of said first surface, wherein the first layer comprises an ammonia slip catalyst composition comprising one or more platinum group metals supported on titania, a silica-titania mixed oxide, a CeZr mixed oxide, or a mixture thereof, and a second layer is provided on at least a portion of the first layer and comprises an SCR catalyst composition.

INTRA-CRYSTALLINE BINARY CATALYSTS AND USES THEREOF
20200316571 · 2020-10-08 ·

The present disclosure describes, inter alia, binary catalyst compositions including a (metal) zeolite having a crystal lattice that incorporates a metal oxide, wherein the metal oxide is covalently bound to elements within the crystal lattice. The metal oxide forms an integral part of the (metal) zeolite crystal lattice, forming covalent bonds with at least the Si or Al atoms within the crystal lattice of the (metal) zeolite, and is dispersed throughout the (metal) zeolite crystal lattice. The metal oxide can substitute atoms within the crystal lattice of the (metal) zeolite.

SELECTIVE CATALYTIC REDUCTION SYSTEM AND A METHOD FOR NOx REDUCTION
20200300140 · 2020-09-24 ·

A selective catalytic reduction system applying diesel oil as reductant for converting nitrogen oxides by means of a catalyst into diatomic nitrogen and water in a diesel engine is provided. The selective catalytic reduction system includes an oil injection system, a reactor and a number of selective catalytic reduction catalysts provided in a first section. The selective catalytic reduction system includes at least one additional section including a number of selective catalytic reduction catalysts. The at least one additional section is provided in a non-zero from the first section.

Preparation of a ZSM-5-based catalyst; use in ethylbenzene dealkylation process

A process of preparing a catalyst composition which process comprises the steps of (a) treating ZSM-5 zeolite with an alkaline solution having a pH of at least (8) followed by ion exchange to obtain a treated zeolite, (b) extruding a mixture of the treated zeolite and binder and contacting the zeolite with a fluorocompound containing solution, (c) increasing the temperature of the extrudates obtained in step (b) to at least 200 C., and (d) combining the extrudates obtained in step (c) with one or more metals selected from the group consisting of Group (10) and (11) of the IUPAC Periodic Table of Elements and a process for the conversion of an aromatic hydrocarbons containing feedstock using a catalyst composition prepared by such process.

Catalyst for treating an exhaust gas, an exhaust system and a method

A catalyst for treating an exhaust gas comprising SO.sub.2, NO.sub.x and elemental mercury in the presence of a nitrogenous reductant comprises a composition containing oxides of: (i) Molybdenum (Mo) and/or Tungsten (W); (ii) Vanadium (V); (iii) Titanium (Ti), and (iv) an MFI zeolite, wherein the composition comprises, based on the total weight of the composition: (i) 1 to 6 wt % of MoO.sub.3 and/or 1 to 10 wt % WO.sub.3; and (ii) 0.1 to 3 wt % V.sub.2O.sub.5, and (iii) 48.5 to 94.5 wt % TiO.sub.2; and (iv) 35 to 50 wt % MFI zeolite.

Passive nitrogen oxide adsorber catalyst

The present invention relates to a catalyst comprising a carrier substrate of the length L, a passive nitrogen oxide adsorber and means to control the temperature of the carrier substrate, as well as a process for cleaning of an exhaust gas emitted from a lean burn engine.

Hybrid binary catalysts, methods and uses thereof
10675586 · 2020-06-09 · ·

The present disclosure describes hybrid binary catalysts (HBCs) that can be used as engine aftertreatment catalyst compositions. The HBCs provide solutions to the challenges facing emissions control. In general, the HBCs include a porous primary catalyst and a secondary catalyst. The secondary catalyst partial coats the surfaces (e.g., the internal porous surface and/or the external surface) of the primary catalyst resulting in a hybridized composition. The synthesis of the HBCs can provide a primary catalyst whose entire surface, or portions thereof, can be coated with the secondary catalyst.

Method for preparing molecular sieve-multielement oxide composite integrally extruded denitration catalyst

A preparation method for a molecular sieve-multiple oxide composite integral extrusion type denitration catalyst includes constructing an organic structure coating on the surface of a metal ion-exchanged molecular sieves and synchronously adding multiple oxide components, thus obtaining an ion-exchanged molecular sieve-multiple oxide composite denitration catalyst active component; and then mixing, kneading into paste, staling, carrying out integral extrusion forming, drying, and calcining, thus obtaining the integral extrusion type denitration catalyst. The molecular sieve-multiple oxide composite integral extraction type denitration catalyst has a denitration efficiency more than 80% at the temperature ranging from 250 C. to 420 C. in the presence of 10% steam and 500 ppm sulfuric dioxide.