Disclosed herein are metal-organic frameworks and methods of making and use thereof.

A process is presented to treat a process gas stream containing hydrogen sulfide using a reverse jet absorber with a liquid treatment solution containing a chelated metal catalyst. A treat gas substantially free of the hydrogen sulfide is separated from a spent liquid treatment solution containing elemental sulfur which can then be regenerated in an oxidation vessel where it is contacted with an oxygen containing gas to convert the spent liquid treatment solution to a regenerated liquid treatment solution that can be recycled for introduction into the reverse jet absorber.

A dosing composition and method for treatment of reductant urea solutions utilizing organometallic catalyst precursors in combination with one or more surfactants to promote decomposition of relatively high molecular weight deposits which deposits may otherwise reduce selective catalytic reduction efficiency.

A metal organic framework (MOF)-polymer composite for detoxifying a chemical warfare agent (CWA) comprises MOF nanoparticles having catalytically active Lewis acid sites and at least one polymer having catalytically active basic sites. The composite is configured such that the at least one polymer is in surrounding relation to the MOF nanoparticles such that at least a portion of the Lewis acid sites of the MOF nanoparticles are in proximal relation to at least a portion of the basic sites of the at least one polymer thereby forming a plurality of proximal acid-base interfaces thus enabling a bifunctional catalytic mechanism for detoxifying the CWA. The MOF-polymer composite can provide CWA detoxification without the presence of a basic compound.

This invention relates to a Cu-BTC MOF which is water stable. The Cu-BTC MOF has open coordination sites and has been post synthesis modified by partially occupying the open sites with a ligand such as acetonitrile (CH.sub.3CN). The resultant MOF retains at least 40% of its as synthesized surface area after exposure to liquid water at 60° C. for 6 hours. This is an unexpected result versus the MOF which has not been post treated with ligands such as acetonitrile. This MOF can be used to abate contaminants such as ammonia in gas streams and especially air streams.

A dosing composition and method for treatment of reductant urea solutions utilizing organometallic catalyst precursors in combination with one or more surfactants to promote decomposition of relatively high molecular weight deposits which deposits may otherwise reduce selective catalytic reduction efficiency.

A filter includes a filter medium having an average pore size of 1 to 5 mm, and photocatalyst particles deposited on the filter medium. The photocatalyst particle contains a titanium compound particle and a metal compound bonded to the surface of the titanium compound particle with an oxygen atom. The metal compound contains a metal atom and a hydrocarbon group. The titanium compound particle has absorption at wavelengths of 450 nm and 750 nm in the visible absorption spectrum of the titanium compound particle.

The present invention describes a fluid which is suitable for the decontamination of heat engines which can carry out both, at the same time, the catalytic reduction of oxides of nitrogen (NOx) contained in exhaust gases and assist in the regeneration of the particulate filter (PF). The invention also describes several embodiments of said fluid.

Disclosed herein are methods for removing acetylene from an ethylene gas stream wherein a catalyst reacts with the acetylene to polymerize said acetylene forming an ethylene gas stream substantially free of acetylene.

This invention relates to a Cu-BTC MOF which is water stable. The Cu-BTC MOF has been modified by substituting some of the BTC ligand (1,3,5, benzene tricarboxylic acid) with 5-aminoisophthalic acid (AIA). The resultant MOF retains at least 40% of its as synthesized surface area after exposure to liquid water at 60 C. for 6 hours. This is an unexpected result versus the MOF containing only the BTC ligand. This MOF can be used to abate contaminants such as ammonia in gas streams and especially air streams.