A method is disclosed for removing ozone from a gas. According to this method, the gas is contacted with an adsorbent that includes a transition metal oxide or metal organic framework to form a treated gas. The treated gas is contacted with a noble metal catalyst to catalytically decompose ozone in the treated gas, thereby forming an ozone-depleted treated gas.

A fuel tank inerting system is disclosed. The system includes a fuel tank and a catalytic reactor with an inlet, an outlet, a reactive flow path between the inlet and the outlet, and a catalyst on the reactive flow path. The catalytic reactor is arranged to receive fuel from a fuel flow path in operative communication with the fuel tank and oxygen from an oxygen source, and to catalytically react a mixture of the fuel and oxygen along the reactive flow path to generate an inert gas. An inert gas flow path provides inert gas from the catalytic reactor to the fuel tank. An adsorbent is disposed along the fuel flow path or along the reactive flow path.

The present disclosure provides catalysts comprising zinc and one or more ligands that improve the hydration of carbon dioxide at a zinc metal center, including but not limited to ethylenediaminetetraacetic acid and its derivatives. In certain embodiments, one or more of the ligands on the zinc is water that is replaced with carbon dioxide. In certain embodiments, the zinc catalyst coordinates an appropriate carbon dioxide adsorption solvent to reduce the activation energy for carbon dioxide hydration. Methods and apparatuses that are designed to efficiently utilize sorbents with improved sorption and desorption characteristics, such as those that include an inorganic catalyst or modified carbonic anhydrase, are also disclosed.

The invention is related to the sphere technologies for desulfurization and demercaptanization of gaseous hydrocarbons. It can be used for purification of any gaseous hydrocarbon medium. The device includes a catalytic reactor loaded with a catalyst solution in an organic solvent, a means of withdrawal sulfur solution from the reactor into the sulfur-separating unit, and a sulfur-separating unit. The sulfur-separation unit includes a means of sulfur extraction. The reactor design and the catalyst composition provide conversion of at least 99.99% of hydrogen sulfide and mercaptans into sulfur and disulfides. The catalyst is composed of mixed-ligand complexes of transition metals. The technical result achieved by use of claimed invention is effectively a single-stage purification of gaseous hydrocarbons from hydrogen sulfide and mercaptans with remaining concentration of SH down to 0.001 ppm while leaving no toxic waste.

The present invention relates to a process for the preparation of a catalyst for selective catalytic reduction comprising (i) preparing a mixture comprising a metal-organic framework material comprising an ion of a metal or metalloid selected from groups 2-5, groups 7-9, and groups 11-14 of the Periodic Table of the Elements, and at least one at least monodentate organic compound, a zeolitic material containing a metal as a non-framework element, optionally a solvent system, and optionally a pasting agent, (ii) calcining of the mixture obtained in (i); and further relates to a catalyst per se comprising a composite material containing an amorphous mesoporous metal and/or metalloid oxide and a zeolitic material, wherein the zeolitic material contains a metal as non-framework element, as well as to the use of said catalyst.

This application is in the field of technologies for desulfurization and demercaptanization of gaseous hydrocarbons. The device includes a catalytic reactor loaded with a catalyst solution in an organic solvent, a means of withdrawal sulfur solution from the reactor into the sulfur-separating unit, and a sulfur-separating unit. The said device has at least means of supplying gaseous hydrocarbon medium to be purified and oxygen-containing gas into the reactor, and a means of outletting the purified gas from the reactor. The sulfur-separation unit includes a means of sulfur extraction. The reactor design and the catalyst composition provide conversion of at least 99.99% of hydrogen sulfide and mercaptans into sulfur and disulfides. The catalyst is composed of mixed-ligand complexes of transition metals. The technical result achieved by use of claimed invention is single-stage purification of gaseous hydrocarbons from hydrogen sulfide and mercaptans with remaining concentration of SH down up to 0.001 ppm.

A method is disclosed for removing ozone from a gas. According to this method, the gas is contacted with an adsorbent that includes a transition metal oxide or metal organic framework to form a treated gas. The treated gas is contacted with a noble metal catalyst to catalytically decompose ozone in the treated gas, thereby forming an ozone-depleted treated gas.

A method of manufacturing a catalyst article, the method comprising: providing a complex of a compound of formula (I):

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and a PGM, R1 is H or C.sub.1-C.sub.6 alkyl, R2 is H, OH, or OC.sub.1-C.sub.4 alkyl, the PGM comprising palladium; providing a support material; applying the complex to the support material to form a loaded support material; disposing the loaded support material on a substrate; and heating the loaded support material to form nanoparticles of the PGM on the support material.

This application is in the field of technologies for desulfurization and demercaptanization of gaseous hydrocarbons. The device includes a catalytic reactor loaded with a catalyst solution in an organic solvent, a means of withdrawal sulfur solution from the reactor into the sulfur-separating unit, and a sulfur-separating unit. The said device has at least means of supplying gaseous hydrocarbon medium to be purified and oxygen-containing gas into the reactor, and a means of outletting the purified gas from the reactor. The sulfur-separation unit includes a means of sulfur extraction. The reactor design and the catalyst composition provide conversion of at least 99.99% of hydrogen sulfide and mercaptans into sulfur and disulfides. The catalyst is composed of mixed-ligand complexes of transition metals. The technical result achieved by use of claimed invention is single-stage purification of gaseous hydrocarbons from hydrogen sulfide and mercaptans with remaining concentration of SH down up to 0.001 ppm.

The present invention describes a fluid which is suitable for the decontamination of heat engines which can carry out both, at the same time, the catalytic reduction of oxides of nitrogen (NOx) contained in exhaust gases and assist in the regeneration of the particulate filter (PF). The invention also describes several embodiments of said fluid.