An oxidation catalyst is described for treating an exhaust gas produced by a diesel engine comprising a catalytic region and a substrate, wherein the catalytic region comprises a catalytic material comprising: bismuth (Bi), antimony (Sb) or an oxide thereof; a platinum group metal (PGM) selected from the group consisting of (i) platinum (Pt), (ii) palladium (Pd) and (iii) platinum (Pt) and palladium (Pd); and a support material, which is a refractory oxide: wherein the platinum group metal (PGM) is supported on the support material; and wherein the bismuth (Bi), antimony (Sb) or an oxide thereof is supported on the support material and/or the refractory oxide comprises the bismuth, antimony or an oxide thereof.

An exhaust system for a compression ignition engine comprising an oxidation catalyst for treating carbon monoxide (CO) and hydrocarbons (HCs) in exhaust gas from the compression ignition engine, wherein the oxidation catalyst comprises: a platinum group metal (PGM) component selected from the group consisting of a platinum (Pt) component, a palladium (Pd) component and a combination thereof; an alkaline earth metal component; a support material comprising a modified alumina incorporating a heteroatom component; and a substrate, wherein the platinum group metal (PGM) component, the alkaline earth metal component and the support material are disposed on the substrate.

The present disclosure describes zoned three way catalyst (TWC) systems including Rhodium-iron overcoat layers and NbZrAl Oxide overcoat layers. Disclosed herein are TWC sample systems that are configured to include a substrate and one or more of a washcoat layer, an impregnation layer, and/or an overcoat layer. In catalyst systems disclosed herein, closed-coupled catalysts include a first catalyst zone with an overcoat layer formed using a slurry that includes an oxide mixture and an Oxygen Storage Material (OSM). In catalyst systems disclosed herein, oxide mixtures include niobium oxide (Nb.sub.2O.sub.5), zirconia, and alumina. Further, catalyst systems disclosed herein include a second catalyst zone with an overcoat layer formed to include a rhodium-iron catalyst. Yet further, catalyst systems disclosed herein include impregnation layers that include one or more of Palladium, Barium, Cerium, Neodymium, and Rhodium.

The present invention relates to a catalyzed particulate filter and methods comprising the filter for treatment of an exhaust gas from a gasoline engine, the catalyzed particulate filter comprising a gasoline particulate filter (GPF); a major catalytic layer coated onto or within an inlet side, an outlet side, or both sides of the GPF surfaces, the major catalytic layer comprising a first composition, wherein the first composition comprising a first support material; and a first platinum group metal (PGM); and a minor functional material layer placed onto or within an inlet side, an outlet side, or both sides of the GPF surfaces; the minor catalytic layer comprising a second composition; wherein the major catalytic layer has a higher loading than the minor functional material layer; the minor functional material layer is placed on top of the major catalytic layer, or the major catalytic material layer is placed on top of the minor functional layer. The catalyzed particulate filter provides an improved catalytic efficiency in conjunction with an efficient filter.

Close-coupled catalysts (CCC) for TWC applications are disclosed. The novel CCCs are implemented using light-weighted ceramic substrates in which a thin coating employing a low loading of Iron (Fe)-activated Rhodium (Rh) material composition, with Iron loadings and an OSM of Ceria-Zirconia, are deposited onto the substrates. Different CCC samples are produced to determine and/or verify improved light-off (LO) and NO.sub.X conversion of the CCCs. Other CCC samples produced are a CCC including a standard (non-activated) Rh thin coating and a heavily loaded CCC with a single coating of Pd/Rh material composition. The CCC samples are aged under dyno-aging using the multi-mode aging cycle and their performance tested using a car engine with ports on the exhaust to measure the emissions, according to the testing protocol in the Environmental Protection Agency Federal Test Procedure 75. During testing, the thin coatings of Fe-activated Rh exhibit improved light-off and NO.sub.x conversion efficiency.

This catalyst includes a lower catalytic layer 2 having catalytic ability to oxidize HC and CO and an upper catalytic layer 3 having catalytic ability to reduce NO.sub.x. The lower catalytic layer 2 contains Pt and Pd acting as catalytic metals, zeolite, a Ce-containing oxide, and activated alumina, and the upper catalytic layer 3 contains activated alumina loading an Rh-doped Ce-containing oxide and an NO.sub.x storage material.

An exhaust gas purification catalyst apparatus, which is superior in oxidation performance of, in particular, nitrogen monoxide, among hydrocarbons, carbon monoxide, nitrogen oxides and particulate components such as soot, included in exhaust gas from a lean burn engine, and combustion performance of light oil. The exhaust gas purification apparatus arranged with an oxidation catalyst (DOC) comprising a noble metal component for oxidizing carbon monoxide, hydrocarbons, in particular, nitrogen monoxide among nitrogen oxides, and for combusting light oil, a catalyzed soot filter (CSF) including a noble metal component for collecting a particulate component such as soot and removing by combustion (oxidation). The oxidation catalyst (DOC) has a catalyst layer where platinum (Pt), palladium (Pd) and barium oxide (BaO) are supported on alumina (Al.sub.2O.sub.3) having a pore size of 12 to 120 nm, and ratio of platinum and palladium is 1:1 to 11:2 in weight equivalent.

The present invention discloses a catalyst for in-situ CO2 capture and coupling reduction with biomass oxidation, a preparation method therefor and an application thereof. The catalyst is applied to the coupling reaction of photocatalytic CO2 reduction and biomass oxidation. The preparation of the catalyst is to synthesize layered double hydroxides (LDHs) containing CO32 between layers by using coprecipitation method, hydrothermal method, sol-gel method and the like, wherein the chemical formula is [M1x2+Mx3+(OH)2]x+(An)x/n.Math.mH2O, which has a thickness of 20-30 nm and an average particle diameter of 60-90 nm. Then metal ion vacancy defects are produced on LDHs laminate by using a NaOH/KOH selective etching to obtain the corresponding catalyst. The catalyst is used in photocatalytic reaction, characterized in that CO32 is continuously consumed in the reaction process, and the catalyst can absorb CO2 in the air for recovery after the reaction, and can be repeatedly used to continuously consume CO2 in the air, thus realizing the direct capture and effective utilization of CO2.

The present invention relates to a porous composite structure catalyst comprising a porous substrate and a catalyst coating layer, wherein the catalyst coating layer comprises: a porous support including meso-pores; and a composite catalyst, which is gold nanoparticles impregnated into pores of the porous support.