An apparatus for purifying an exhaust gas passing through an exhaust pipe includes a catalytic converter disposed on the exhaust pipe. The catalytic converter is provided with a lean NOx trap (LNT) device, the LNT device having an LNT catalyst coated therein, and a catalyzed particulate filter (CPF), the CPF having a catalyst coated therein, and the LNT device and the CPF are sequentially disposed in the catalytic converter. The CPF includes at least one inlet channel extending in a longitudinal direction, the at least one inlet channel having a first end into which fluid flows and a second end which is blocked, at least one outlet channel extending in the longitudinal direction, the at least one outlet channel having a first end which is blocked and a second end through which the fluid flows out, at least one porous wall that defines a boundary between neighboring inlet and outlet channels and that extends in the longitudinal direction, and a support with the catalyst coating thereon, and the support is located within at least one among the at least one inlet channel and the at least one outlet channel.

An exhaust gas purifying system for an engine includes a three-way catalyst, a particulate filter, an ammonia sorbent unit, an exhaust gas purifying catalyst unit, and a gas injection component including an oxygen-containing gas, all coupled to an exhaust line. Methods for purifying exhaust gas from an engine include exposing the exhaust gas to a three-way catalyst and a particulate filter, thus generating ammonia. The ammonia may be stored in an ammonia sorbent unit during a cold start condition. An oxygen-containing gas may be injected into the exhaust line. Once the ammonia sorbent has reached a desorption temperature, the ammonia may be released into the exhaust line and exposed to an exhaust gas purifying catalyst unit. The exhaust gas purifying catalyst partially oxidizes the ammonia to nitrous oxides (NOx) and subsequently catalyzes a reaction between the remaining ammonia and the nitrous oxides to give nitrogen gas and water.

Process for the removal of NOx (NO, NO2) and nitrous oxide (N2O) contained in a process off-gas comprising the steps of (a) adding an amount of a NOx reducing agent into the process off-gas;(b) in a first stage passing the process off-gas admixed with the reducing agent through a catalyst active in selective catalytic reduction of NOx with the reducing agent and providing an effluent gas comprising the nitrous oxide and residual amounts of reducing agent; and(c) in a second stage passing the effluent gas through a catalyst comprising a cobalt compound and being active in decomposition of nitrous oxide and oxidation of the residual amounts of the reducing agent.

A method for controlling the operation of an exhaust aftertreatment system (EATS) in a vehicle is described. The EATS comprises a main SCR catalyst and a pre-SCR catalyst, a pre-injector arranged upstream the pre-SCR catalyst for providing reductant, a bypass channel fluidly connected to the fluid channel and arranged to bypass the pre-SCR-catalyst and the pre-injector, and a valve configured to control a split of exhaust gases between the pre-SCR catalyst and the bypass channel. The method includes determining the amount of ammonia stored in the pre-SCR catalyst; determining the temperature of the main SCR catalyst; when the ammonia storage in the pre-SCR catalyst is below an ammonia storage threshold and the temperature of the main SCR catalyst is above a temperature threshold, injecting reductant by the pre-injector and controlling the valve to allow a flow of exhaust gases to the pre-SCR catalyst sufficient for transporting the injected reductant to the pre-SCR catalyst for increasing the ammonia storage.

An exhaust gas purification system for lowering the content of impurities in a lean exhaust gas of an internal combustion engine comprising, a feeding device that feeds ammonia or a compound decomposable to ammonia into an exhaust gas stream containing nitrogen oxides; a selective catalytic reduction catalyst comprising vanadium (V-SCR catalyst) which catalyzes the nitrogen oxides with ammonia in a temperature range of about 150° C. to about 400° C. and at an NO.sub.2/NO.sub.x ratio of about 0.3 to about 0.9; and a downstream system comprising a diesel oxidation catalyst.

An exhaust gas purification device includes a substrate including an upstream end and a downstream end and having a length Ls; a first containing Pd particles, extending between the upstream end and a first position, and being in contact with the substrate; a second containing Rh particles, extending between the downstream end and a second position, and being in contact with the substrate; and a third catalyst layer containing Rh particles, extending between the upstream end and a third position, and being in contact with at least the first catalyst layer, wherein an average of a Rh particle size distribution is from 1.0 to 2.0 nm, and a standard deviation of the Rh particle size distribution is 0.8 nm or less in each of the second catalyst layer and the third catalyst layer.

Synergized platinum group metals (SPGM) with ultra-low PGM loadings employed as close-coupled (CC) three-way catalysts (TWC) systems with varied material compositions and configurations are disclosed. SPGM CC catalysts in which ZPGM compositions of binary or ternary spinel structures supported onto support oxides are coupled with commercialized PGM UF catalysts and tested under Federal Test Procedure FTP-75 within TGDI and PI engines. The performance of the TWC systems including SPGM CC (with ultra-low PGM loadings) catalyst and commercialized PGM UF catalyst is compared to the performance of commercialized PGM CC and PGM UF catalysts. The disclosed TWC systems indicate that SPGM CC TWC catalytic performance is comparable or even exceeds high PGM-based conventional TWC catalysts, with reduced tailpipe emissions.

Synergized platinum group metals (SPGM) with ultra-low PGM loadings employed as underfloor (UF) three-way catalyst (TWC) systems with varied material compositions and configurations are disclosed. SPGM UF catalysts in which ZPGM compositions of binary and ternary spinel structures supported onto support oxides are coupled with commercialized PGM close-coupled (CC) catalysts and tested under Federal Test Procedure FTP-75 within TGDI and PI engines. The performance of the TWC systems including commercialized PGM CC and SPGM UF (with ultra-low PGM loadings) catalysts is compared to the performance of commercialized PGM CC and PGM UF catalysts. The disclosed TWC systems indicate that SPGM UF TWC catalytic performance is comparable or even exceeds high PGM-based conventional TWC catalysts, with reduced tailpipe emissions.

A catalyst article having an extruded support having a plurality of channels through which exhaust gas flows during operation of an engine, and a single layer coating or a bi-layer coating on the support, where the extruded support contains a third SCR catalyst, the single layer coating and the bilayer-coating contain platinum on a support with low ammonia storage and a first SCR catalyst. The catalytic articles are useful for selective catalytic reduction (SCR) of NOx in exhaust gases and in reducing the amount of ammonia slip. Methods for producing such articles are described. Methods of using the catalytic articles in an SCR process, where the amount of ammonia slip is reduced, are also described.

A selective catalytic reduction (SCR) catalyst includes a support layer. A copper-loaded chabazite (Cu/CHA) layer is supported on the support layer. A copper-loaded beta zeolite (Cu/beta) is supported on the Cu/CHA layer. The Cu/beta may be hydrothermally pre-aged prior to use of the SCR catalyst in a vehicle. The pre-aged Cu/beta is essentially free of phosphorous (P), calcium (Ca), zinc (Zn), sodium (Na), potassium (K), magnesium (Mg), iron (Fe), CaSO.sub.4, Ca.sub.19Zn.sub.2(PO.sub.4).sub.14, CaZn.sub.2(PO.sub.4).sub.2, ash, and/or soot.