An object of the present disclosure is to provide an exhaust gas purification catalyst demonstrating superior storage of NOx contained in exhaust gas.

The exhaust gas purification catalyst of the present disclosure has a substrate, a first catalyst layer containing a catalytic metal for NOx reduction and a NOx storage material and formed on the substrate, and a second catalyst layer containing a catalytic metal for NOx oxidation and formed on the first catalyst layer. In the exhaust gas purification catalyst of the present disclosure, the value obtained by dividing the volume of all large pores having a pore volume of 1000 μm.sup.3 or more by the total volume of all medium pores of having a pore volume of 10 μm.sup.3 to 1000 μm.sup.3 in the second catalyst layer is 2.44 or less.

A catalyst for abating a nitrogen oxide includes: a honeycomb substrate including a plurality of cell passages partitioned by a cell barrier rib; and a coating layer positioned on the internal side of the cell passages. The coating layer includes a support including Mg-substituted alumina (MgAl.sub.2O.sub.4), ceria (Ce), and a composite ceria; and Ba and a noble metal catalyst selected from the group consisting of Pt, Pd, Rh and combinations thereof, which are supported on the support. Also provided is a catalyst system for abating a nitrogen oxide includes the coating layer.

An exhaust gas purification system for diesel engines of utility motor vehicles, includes an oxidation catalytic converter disposed in an exhaust tract, a reducing agent dosing device having a reducing agent injection device, a reducing agent decomposition device, a soot particle separator, a reduction catalytic converter and a muffler for the exhaust gases. The oxidation catalytic converter is disposed within a minimum distance directly downstream of outlet valves of the engine and a maximum distance of 0.75 m from an exhaust collecting pipe or an outlet of a turbocharger. The reducing agent decomposition device, the soot particle separator and the reduction catalytic converter are disposed separately from the oxidation catalytic converter.

The manufacturing method includes a step of mixing a coarse particle zeolite, a fine particle zeolite, and a raw material of an inorganic bonding material to prepare a zeolite raw material; a step of forming the prepared zeolite raw material into a honeycomb shape to prepare a honeycomb formed body; and a step of firing the prepared honeycomb formed body to prepare the honeycomb structure. In the step of preparing the zeolite raw material, as the coarse particle zeolite, a chabazite type zeolite having a specific average particle diameter, the fine particle zeolite having a specific average particle diameter, the raw material of the inorganic bonding material which includes at least basic aluminum lactate is used.

In an internal combustion engine of the present invention, an exhaust purification catalyst (13) and a hydrocarbon supply valve (15) are disposed in an engine exhaust path, and NO.sub.x contained in exhaust gas is purified by injecting hydrocarbon from the hydrocarbon supply valve (15) at a predetermined cycle. With respect to the injection amount per unit time of the hydrocarbon from the hydrocarbon supply valve (15), there is a difference provided between the first half and the second half of one injection time period, and in the first-half injection time period (Y), the injection amount per unit time of hydrocarbon is made to be less as compared to the second-half injection time period (X).

An after-treatment system includes, in series along an exhaust gas flow direction through the after-treatment system: a diesel oxidation catalyst (DOC), a diesel exhaust fluid (DEF) delivery device, a soot-reducing device and a selective catalytic reduction (SCR) catalyst.

A layered catalyst composite for the treatment of exhaust gas emissions, effective to provide lean NO.sub.x trap functionality and three-way conversion functionality is described. Layered catalyst composites can comprise catalytic material on a substrate, the catalytic material comprising at least two layers. The first layer comprising rare earth oxide-high surface area refractory metal oxide particles, an alkaline earth metal supported on the rare earth oxide-high surface area refractory metal oxide particles, and at least one first platinum group metal component supported on the rare earth oxide-high surface area refractory metal oxide particles. The second layer comprising a second platinum group metal component supported on a first oxygen storage component (OSC) and/or a first refractory metal oxide support and, optionally, a third platinum group metal supported on a second refractory metal oxide support or a second oxygen storage component.

The present invention relates to cerium oxide particles that have excellent heat resistance and/or pore volume especially useful for catalysts, functional ceramics, solid electrolyte for fuel cells, polishing, ultraviolet absorbers and the like, and particularly suitable for use as a catalyst or cocatalyst material, for instance in catalysis for purifying vehicle exhaust gas. The present invention also relates to a method for preparing such cerium oxide particles, and a catalyst, such as for purifying exhaust gas, utilizing these cerium oxide particles.

A method for removing NO.sub.X from an oxygen-rich exhaust flow produced by a combustion source that is combusting a lean mixture of air and fuel may include passing the oxygen-rich exhaust flow through an exhaust aftertreatment system that includes a NO.sub.X oxidation catalyst that includes perovskite oxide particles, a NO.sub.X storage catalyst, and a NO.sub.X reduction catalyst.

The invention relates to a catalyst system for reducing nitrogen oxides, which comprises a nitrogen oxide storage catalyst and an SCR catalyst, wherein the nitrogen oxide storage catalyst consists of at least two catalytically active washcoat layers on a supporting body, wherein a lower washcoat layer A contains cerium oxide, an alkaline earth compound and/or alkali compound, as well as platinum and palladium, and an upper washcoat layer B, which is arranged over the washcoat layer A, contains cerium oxide, platinum and palladium, and no alkali compound and no alkaline earth compound. The invention also relates to a method for converting NOx in exhaust gases of motor vehicles that are operated by means of engines that are operated in a lean manner.