An exhaust gas purification method by which carbon monoxide (CO), hydrocarbon (HC), and nitrogen oxide (NOx), particularly NOx, which are hazardous components contained in an exhaust gas can be removed efficiently. The disclosure relates to a catalyst for exhaust gas purification including: a three-dimensional structure; and a catalyst component layer composed of one or more constituting layers on the three-dimensional structure, wherein the catalyst component layer contains (a) a noble metal-unsupported alumina having mesopores, (b) NOx storage material-supported cerium, (c) a refractory inorganic oxide, and (d) a noble metal, and the constituting layer of the uppermost surface among the one or more constituting layers contains (a) the noble metal-unsupported alumina and (b) the NOx storage material-supported cerium, a method for producing the same, and an exhaust gas purification method using the catalyst.

A method for producing a catalyst using an additive layer method includes: (i) forming a layer of a powdered catalyst or catalyst support material, (ii) binding or fusing the powder in said layer according to a predetermined pattern, (iii) repeating (i) and (ii) layer upon layer to form a shaped unit, and (iv) optionally applying a catalytic material to said shaped unit.

A method of making a supported catalytic species comprising an alloy of at least two metals, comprises the steps of: (i) combining a particulate support material, a solution of a first metal compound, a solution of a second metal compound, and a solution of an alkaline precipitating agent to form a slurry mixture; (ii) agitating the resultant mixture; and (iii) contacting the solids with a reducing agent, wherein the first metal in the first metal compound and the second metal in the second metal compound is each independently selected from the group consisting of gold, palladium, platinum, rhodium, iridium, silver, osmium and ruthenium; and wherein the first metal is not the same as the second metal.

A satisfactory oxygen storage material and a method for producing it are provided. The oxygen storage material comprises zirconia particles with a ceria-zirconia complex oxide supported on the zirconia particles. The ceria-zirconia complex oxide includes a pyrochlore phase and has a mean crystallite diameter of 10 nm to 22.9 nm.

A method for producing a catalyst using an additive layer method includes: (i) forming a layer of a powdered catalyst or catalyst support material, (ii) binding or fusing the powder in said layer according to a predetermined pattern, (iii) repeating (i) and (ii) layer upon layer to form a shaped unit, and (iv) optionally applying a catalytic material to said shaped unit.

An exhaust gas purification catalyst contains an oxide 1 and an oxide 2. The catalyst has pores P.sub.1-260 with a pore size of from 1 nm to 260 nm, that can be measured by the nitrogen absorption method, and the total sum PV.sub.1-260 of the pore volume PV.sub.1-260 of the pores is equal to or greater than 0.79 cm.sup.3/g.

The oxide 1 is an oxide with an oxygen release capability. The oxide 2 is represented by La.sub.xM.sub.1-xMO.sub.3- (2), where M is at least one element selected from the group consisting of Ba, Sr and Ca, M is at least one element selected from the group consisting of Fe, Co, Ni and Mn, is the amount of oxygen deficiency, x satisfies 0x1, and satisfies 01.

A method of making a supported catalytic species comprising an alloy of at least two metals, comprises the steps of: (i) combining a particulate support material, a solution of a first metal compound, a solution of a second metal compound, and a solution of an alkaline precipitating agent to form a slurry mixture; (ii) agitating the resultant mixture; and (iii) contacting the solids with a reducing agent, wherein the first metal in the first metal compound and the second metal in the second metal compound is each independently selected from the group consisting of gold, palladium, platinum, rhodium, iridium, silver, osmium and ruthenium; and wherein the first metal is not the same as the second metal.

Methods and catalyst compositions for oxidizing CO to CO.sub.2 at low temperatures arc disclosed. In embodiment, a method of oxidizing CO to CO.sub.2 may involve heating a gaseous mixture comprising at least CO and O.sub.2 with a catalyst mixture comprising Pd disposed on a Mn.sub.3O.sub.4mesoporous support at a temperature of about 0 C. to about 60 C., and wherein the CO to CO.sub.2 conversion rate is about 40% to about 100%.

An organo-template free method for the manufacture of a ferrierite (FER) zeolite and the ferrierite producible by the method. The method comprises (i) forming a reaction gel comprising an aluminium source, sodium and/or potassium hydroxide, and silica sol; and (ii) heating the reaction gel to a temperature and for a duration suitable for the growth of the FER zeolite. The reaction gel does not comprise seed crystals. Moreover the reaction gel does not comprise an organic structure directing agent (OSDA). The ferrierite (FER) zeolite has the following features: a) a SAR of between 11 and 20; b) a BET surface area of between 320 and 380 m.sup.2/g; and c) a micropore volume of between 0.1 and 0.2 cm.sup.3/g.

The present invention provides an exhaust gas purification catalyst having an excellent purification performance for purifying chemically stable methane. A catalyst material 30 includes a carrier 32 formed of alumina and a catalyst 34 formed of at least one of palladium and a palladium oxide directly supported on the carrier 32. A specific surface area of the carrier 32 is preferably 20 m.sup.2/g or more 90 m.sup.2/g or less. In one preferred aspect, a proportion of Pd(100) and PdO(101) in crystal planes of the catalyst 34 at a joint surface between the catalyst 34 and the carrier 32 is 20 number % or more.