An article includes a closed-environment air purification system that has a purifier through which air can be recirculated. The purifier is capable at a temperature of equal or less than 35° C. of converting hydrogen in the air to water and converting carbon monoxide in the air to carbon dioxide. The purifier has a reactor bed that includes media comprised of support particles and a metal catalyst disposed on the support particles.

A honeycomb body (300) including a plurality of radially-extending walls (322) intersecting with a plurality of circumferentially-extending walls (324), the plurality of radially-extending walls (322) and the plurality of circumferentially-extending walls (324) form a plurality of circumferential zones (334A, 334B, 334C) of cells (308). The plurality of circumferential zones (334A, 334B, 334C) of cells (308) includes a first zone of cells (334A) including two or more first rings of cells (330) and having a first cell density, and a second zone of cells (334B) including two or more rings of cells (330) having varying cell densities across the two or more rings of cells. Other structures and extrusion dies are disclosed.

A catalyst article and its use in an exhaust system for internal combustion engines is disclosed. The catalyst article comprises a substrate which is a wall-flow filter, a first catalyst composition, and a second catalyst composition. The first and second catalyst compositions each independently comprise an oxygen storage component (OSC) derived from a CeZr mixed oxide sol having a D90 of less than 1.3 micron and a particulate inorganic oxide having a D90 of from 1 to 20 microns.

A crystal-orientation controlled complex comprising a connected assembly having a thin film shape, in which a plurality of crystal pieces are connected with each other, the crystal pieces having a flake shape and having a main surface and an end surface, wherein the main surface has a crystal orientation relative to a specific crystal plane, and the thin film shaped connected assembly has a polarization singularity.

A substrate (11) includes an inflow-side cell (21), an outflow-side cell (22), and a porous, gas-permeable partition wall (23) that separates the inflow-side cell (21) and the outflow-side cell (22) from each other, and also includes a first catalyst portion (14) that is provided on a side of the partition wall (23) that faces the inflow-side cell (21) at least at a portion in upstream side in an exhaust gas flow direction, and a second catalyst portion (15) that is provided on a side of the partition wall that faces the outflow-side cell at least at a portion in downstream side. With respect to a pore volume of pores with a pore size of 10 to 18 m, when a measured value of the pore volume in the first catalyst portion (14) and the partition wall (23) within a region where the first catalyst portion (14) is provided is defined as a first pore volume, and a measured value of the pore volume in the second catalyst portion (15) and the partition wall (23) within a region where the second catalyst portion (15) is provided is defined as a second pore volume, the first pore volume is greater than the second pore volume. A catalytically active component contained in the first catalyst portion (14) and a catalytically active component contained in the second catalyst portion (15) are of different types.

Coated particulate filters and methods for their manufacture disclosed. The particulate filters comprise a honeycomb body having a plurality of porous channel walls defining channels extending from an inlet end to an outlet end. The honeycomb body has an upstream zone having an upstream zone gas permeability and a downstream zone disposed closer to the outlet end than the upstream zone and having a downstream zone gas permeability. SCR catalyst is present in a loading in the downstream zone at localized loading in a range of from about 50 g/L to about 200 g/L such that the upstream zone gas permeability is in a range of about 5 to about 90 times the downstream zone gas permeability.

A honeycomb body having a porous ceramic honeycomb structure with a first end, a second end, and a plurality of walls having wall surfaces defining a plurality of inner channels. A highly porous layer is disposed on one or more of the wall surfaces of the honeycomb body. The highly porous layer has a porosity greater than 90%, and has an average thickness of greater than or equal to 0.5 m and less than or equal to 10 m. A method of making a honeycomb body includes depositing a layer precursor on a ceramic honeycomb body and binding the layer precursor to the ceramic honeycomb body to form the highly porous layer.

A method for preparing a sol comprising TiO.sub.2 and ZrO.sub.2 and/or hydrated forms of TiO.sub.2 and ZrO.sub.2. The method includes mixing a material which includes metatitanic acid in an aqueous phase with a zirconyl compound or with a mixture of several zirconyl compounds. The material is provided either as a suspension or as a filter cake from the sulfate method. The material includes a H.sub.2SO.sub.4 content of 3 to 15 wt.-% relative to a quantity of TiO.sub.2 in the material. The zirconyl compound or the mixture of several zirconyl compounds is mixed in a quantity that is sufficient to provide the sol depending on the H.sub.2SO.sub.4 content.

A honeycomb structure includes a pillar-shaped honeycomb structure body having a porous partition wall defining a plurality of cells serving as fluid through channel extending from an inflow end face to an outflow end face; and a circumferential wall surrounding the partition wall, wherein in a plane orthogonal to cell extending direction, the honeycomb structure body has a circumferential cell structure, a center cell structure having a cell structure different from the circumferential cell structure, and a boundary wall, the honeycomb structure body has intersection parts of the partition wall, including basic intersection parts and thick intersection parts having a thickness larger than that of the basic intersection parts, the thick intersection parts include at least one of: first thick intersection parts and second thick intersection parts, and in the circumferential cell structure, the intersection parts at least include the circumferential basic intersection parts.

Honeycomb bodies, honeycomb structures and extrusion dies, including a transition structural component. A honeycomb structure (100) includes a plurality of interconnected webs (106) defining a plurality of cell channels (108) in a honeycomb matrix (109) having a central axis (110) orthogonal to its transverse cross-section. Radial webs (116) diverge outwardly from the central axis (110). Radial webs (116) include a first radial web (150) and a second radial web (152). Tangential webs (120) are arranged concentrically with respect to the central axis (110), wherein at least one of the tangential webs (120) is a tangential transition web (142). At least one transition structural component (140) is located radially inward from the tangential transition web (124) and includes a first inclined web (144) having a first end (144A) coupled to the first radial web (150) and a second inclined web (146) having a first end (146A) coupled to the second radial web (152). Extrusion dies configured to make the honeycomb structures are provided, as are other aspects.