An adsorption apparatus and associated method for capturing an target gaseous adsorbate from an atmospheric air based gaseous feed stream. The adsorption apparatus comprises: a housing enclosing at least one adsorption element for adsorbing the target gaseous adsorbate, the at least one adsorption element comprising at least one substrate coated with an adsorptive composite coating that comprises at least 50 wt % metal organic framework and at least one binder, the housing having an inlet through which the gaseous feed stream can flow to the adsorption element and an outlet through which gas can flow out from the housing; and a desorption arrangement in contact with and/or surrounding the at least one adsorption element, the desorption arrangement being selectively operable between (i) a deactivated state, and (ii) an activated state in which the arrangement is configured to heat, apply a reduced pressure or a combination thereof to the adsorptive composite coating to desorb at least a portion of the adsorbed target gaseous adsorbate from the adsorptive composite coating.

A gas separation membrane for selective separation of hydrogen and helium from gas mixtures containing carbon dioxide includes a porous support layer, an aromatic polyamide layer on the porous support layer, and a coating including a glassy polymer formed on the aromatic polyamide layer. A glass transition temperature of the glassy polymer is greater than 50° C. The gas separation membrane may be formed by contacting a solution including the glassy polymer with an aromatic polyamide layer of a composite membrane and drying the solution to form a coating of the glassy polymer on the aromatic polyamide layer. Separating hydrogen or helium from a gas stream including carbon dioxide includes contacting a gas feed stream including carbon dioxide with the gas separation membrane to yield a permeate stream having a concentration of helium or hydrogen that exceeds the concentration of helium or hydrogen, respectively, in the gas feed stream.

The present invention relates to a process for the production of asymmetric cellulose hollow fibres and the use of such fibres in the production of asymmetric carbon hollow fibre membranes (CHFMs). In particular, the present invention provides a facile and scalable process for the preparation of asymmetric CHFMs by direct pyrolysis of polymeric precursors without the need for complex pre-pyrolysis treatment steps to prevent pore collapse. The present invention also relates to the use of asymmetric CHFMs prepared according to said process in the separation of hydrogen gas from a mixed gas source, especially in the separation of hydrogen from CO.sub.2 in the steam-methane reforming reaction.

A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers.

Various illustrative embodiments of a system and process for recovering high-quality biomethane and carbon dioxide product streams from biogas sources and utilizing or sequestering the product streams are provided. The system and process synergistically yield a biomethane product which meets gas pipeline quality specifications and a carbon dioxide product of a quality and form that allows for its transport and sequestration or utilization and reduction in greenhouse gas emissions. The system and process result in improved access to gas pipelines for products, an improvement in the carbon intensity rating of the methane fuel, and improvements in generation of credits related to reductions in emissions of greenhouse gases.

The invention relates to a compressed gas storage tank, in particular for a motor vehicle, with a holder that is designed to store a compressed fuel, and with at least one pressure relief valve. Fuel is dischargeable from the holder into environment of the compressed gas tank due to the opening of at least one pressure relief valve. A catalytic converter device of the compressed gas storage tank designed to catalyze an oxidation reaction of fuel originating from the holder with oxygen. The compressed gas storage tank has at least one piezoelectric element to which a pressure can be applied by opening the at least one pressure relief valve Through the pressure, at least one spark can be generated by means of the at least one piezoelectric element. The invention furthermore relates to a method for operating a compressed gas storage tank of said type.

The invention relates to a method for synthesising a hydrogen-containing compound, wherein a synthesis gas stream (1) comprising hydrogen and carbon oxides is fed to a methanol reactor arrangement (2) for partial conversion into methanol, wherein a methanol residual gas stream (3) is obtained from the methanol reactor arrangement (2), at least part of said methanol residual gas stream (3) being fed to a CO2 remover (4) from which a synthesis recycle stream (5) and a CO2 product stream (6) are obtained, said CO2 product stream (6) having a higher molar carbon dioxide content than the methanol residual gas stream (3), and wherein part of the synthesis recycle stream (5) is fed to the methanol reactor arrangement (2). The method according to the invention is characterised in that part of the synthesis recycle stream (5) is fed to a hydrogen separator (7) from which a separation stream (8) is obtained which has a higher molar hydrogen content than the synthesis recycle stream (5). The invention also relates to a corresponding system for synthesising a hydrogen-containing compound.

The present invention relates to a method for molten metal pyrolysis of hydrocarbons to produce hydrogen gas and carbon. Liquid salt is used to separate produced carbon from the molten metal and to facilitate isolation of produced carbon.

Embodiments of the present disclosure feature an intrinsically microporous ladder-type Tröger's base polymer including a repeat unit based on a combination of W-shaped CANAL-type and V-shaped Tröger's base building blocks, methods of making the intrinsically microporous ladder-type Tröger's base polymer, and methods of using the intrinsically microporous ladder-type Tröger's base polymer to separate a chemical species from a fluid composition including a mixture of chemical species. Embodiments of the present disclosure further include ladder-type diamine monomers for reacting to form a Tröger's base in situ, and methods of making the ladder-type diamine monomers using catalytic arene-norbornene annulation.

The present disclosure provides a gas screening film including at least one gas screening element, each of the at least one gas screening element includes a transistor including a gate, an insulation spacing layer, a first electrode, a semiconductor nanosheet separation layer and a second electrode, and the insulation spacing layer is disposed between the gate and the semiconductor nanosheet separation layer. The present disclosure further provides a manufacturing method of the gas screening film and a face mask. The gas screening film can screen and separate various different gases as necessary.