The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of this gas processing system.

The integration of plasma processes with combined cycle power plant, simple cycle power plant, and steam reforming processes. A method of producing purified hydrogen gas and fuel is described including compressing a feed stream of hydrogen, adding tail gas from a plasma process to the feed stream, passing the tail gas modified feed stream into a pressure swing adsorption system generating a purified hydrogen product and a pressure swing adsorption tail gas, separating and compressing the purified hydrogen product, and separating and compressing the pressure swing adsorption tail gas for use as fuel. A method of generating and recapturing electricity from a single or combined cycle power plant is also described including flowing natural gas into a plasma process and hydrogen generating plant, flowing the hydrogen produced into the power plant, flowing natural gas into the power plant, resulting in the production of electricity. The electricity is flowed back into the plasma process plant, and in the case of the combined cycle power plant the electricity is partially flowed into a power grid as well. A method of generating and recapturing electricity from a steam power plant is also described, including inputting electricity and natural gas into a plasma process air and hydrogen generating plant, flowing the air and hydrogen produced into a steam generating boiler, flowing the steam generated into a steam power plant, resulting in the production of electricity which is flowed back into the plasma process plant.

A carbon dioxide recovery system for collecting carbon dioxide from an exhaust gas generated in a facility including a combustion device includes: a first exhaust gas passage through which the exhaust gas containing carbon dioxide flows; a fuel cell including an anode, a cathode disposed on the first exhaust gas passage so that the exhaust gas from the first exhaust gas passage is supplied to the cathode, and an electrolyte transferring, from the cathode to the anode, a carbonate ion derived from carbon dioxide contained in the exhaust gas from the first exhaust gas passage; and a second exhaust gas passage diverging from the first exhaust gas passage upstream of the cathode so as to bypass the cathode. A part of the exhaust gas is introduced to the second exhaust gas passage.

A method and device for purifying heptafluoroisobutyronitrile and a dilution gas from a used gas mixture comprising heptafluoroisobutyronitrile, a dilution gas and arcing by-products. The method comprising the steps of (a) contacting the used gas mixture with at least one adsorbent material to generate a gas stream depleted in arcing by-products; (b) contacting the gas stream depleted in by-products with a first membrane to obtain a first permeate stream rich in the dilution gas, and a first retentate stream rich in heptafluoroisobutyronitrile; (c) contacting the first permeate stream rich in the dilution gas with a second membrane to obtain a second permeate stream rich in the dilution gas and a second retentate stream rich in heptafluoroisobutyronitrile; and (d) combining the first and second retentate streams rich in heptafluoroisobutyronitrile.

Steam reforming processes can include treatment of syngas by water gas shift, water separation, and hydrogen separation by pressure swing adsorption (PSA). Additionally, CO.sub.2 can be scrubbed from the syngas prior to the PSA. PSA tail gas, including CH.sub.4, CO, and H.sub.2, can be recompressed and recycled to the PSA for further hydrogen separation and to the steam reformer feed to convert eventually all carbon in the feedstock into CO.sub.2 for the scrubber to separate. Fuel requirements can be fulfilled by part of the hydrogen product to eliminate stack CO.sub.2 emissions. The hydrogen used as fuel is heated and turbo-expanded to provide power before being combusted as fuel. A nitrogen purge may be added.

A reactor for oxidizing low concentrations of methane in air or other oxidizable fluid mixtures using a porous heat exchanger and a non-porous heat exchanger and an activation zone that allows the oxidation of very weak streams of methane in air or of other oxidizable fluid mixtures.

The present invention relates to methods of preferentially sorbing, from a target mixture, one or more target substance(s) over one or more non-target substance(s). In particular, porous organic cages (POCs) may be deployed in the quantum sieving of mixtures of hydrogen isotopes to selectively sorb heavy hydrogen isotopes (e.g. diatomic deuterium) over lighter isotopes (diatomic protium).

An adsorption process is provided to remove oxygen from a hydrogen stream through the use of a copper material in combination with layers of adsorbent to remove water and nitrogen from a hydrogen stream. This process is particularly useful for purification of hydrogen product gas from water electrolyzers with the hydrogen product gas having greater than 99.9 mol % purity.

Embodiments of the invention are directed to methods, processes, and systems for safely and reliably purifying hydrogen from a gas mixture containing hydrogen and oxygen.

A carbon molecular sieve (CMS) membrane may advantageously be made by pyrolyzing a membrane precursor composition comprised of a carbon forming polymer (e.g., polyimide) blended with a polyvinylidene chloride copolymer (PVDC), the polyvinylidene chloride copolymer being the reaction product of at least 60% to 97% by weight of vinylidene chloride and at least one other comonomer and the carbon forming polymer to polyvinylidene chloride copolymer has a weight ratio of greater than 1 to 99. The membrane precursor composition may be formed by dissolving the carbon forming polymer and PVDC in a solvent to form a dope solution. The dope solution may be shaped, for example, into an asymmetric hollow fiber. The asymmetric hollow fiber may be heated to a temperature to dehydrochorinate the PVDC and then subsequently heated in a non-oxidizing atmosphere to carbonize the polymers of the shaped membrane to form the CMS membrane.