The present invention relates to units for separation of gas mixtures using hollow fiber membranes and may be used in chemical, oil, gas and other industries. More specifically, this invention relates to the structure of the membrane gas separation module which may be applied, for instance, in membrane separation units for helium concentrate. The membrane gas separation module comprises the horizontal body with end covers and membrane cartridges made of a bundle of hollow fibers and located in an inversed manner in relation to the center. The body comprises symmetrical end sections of large diameter which are mated by conical transition sections with the central section of minor diameter. In this case length of end sections corresponds with length restricted by the body end and input area of membrane cartridges, and central section inner diameter is configured to provide both free mounting/dismounting of membrane cartridges and tight fit thereof at the sealing point with ring gaskets. Feed gas input nozzles are located on end sections of the body perpendicularly to its longitudinal axis in front of input areas of membrane cartridges, permeate output nozzles are located on end sections of the body near end covers perpendicularly to the body longitudinal axis. The technical result is reduction of weight and dimensional properties of the membrane module and the whole gas separation unit in general, as well as reduction of labor intensity of operations during mounting/dismounting of body end covers of the membrane module.

Methods for purifying a hydrogen gas stream are provided that can include: introducing the hydrogen gas stream into the hydrogen pumping cell, and collecting a purified hydrogen gas from the hydrogen pumping cell. The hydrogen gas stream can include hydrogen sulfide in an amount of about 10 ppm to about 1,000 ppm, and can have a relative humidity of about 0.1% or more at the operational temperature and pressure of the hydrogen pumping cell.

The gas separation method is executed under a condition in which a partial pressure of a first gas (G1) in a feed gas that contains at least mutually different gases being the first gas (G1) and a second gas (G2) becomes less than or equal to a total pressure of a permeate-side space (S2) of a gas separation membrane (30). The gas separation method includes a step of causing flow of a sweep gas that contains at least a third gas (G3) being a different gas from the first gas (G1) and the second gas (G2) into the permeate-side space (S2) of the gas separation membrane (30) while supplying a feed gas to a feed-side space (S1) of the gas separation membrane (30). The permeation rate of the first gas (G1) in the gas separation membrane (30) is greater than the permeation rate respectively of the second gas (G2) and the third gas (G3).

A semi-porous composite membrane and a method of manufacturing the semi-porous composite membrane. The semi-porous composite membrane includes a base supporting substrate comprising α-Al.sub.2O.sub.3, an outer layer comprising silica, and an intermediate layer comprising crystalline fibers of boehmite, and at least one of a secondary metal oxide and a synthetic polymer, wherein the intermediate layer is disposed between the base supporting substrate and the outer layer. The crystalline fibers of boehmite are a length of 5-150 nm. The semi-porous composite membrane may be employed in membrane reactors.

A process and apparatus for producing a hydrogen-enriched product and recovering CO.sub.2 from an effluent stream from a hydrogen production process unit are described. The process utilizes a CO.sub.2 recovery system integrated with a PSA system that produces at least two product streams to recover additional hydrogen and CO.sub.2 from the tail gas stream of a hydrogen PSA unit in the hydrogen production process.

A process and apparatus for producing a hydrogen-enriched product and recovering CO.sub.2 from an effluent stream from a hydrogen production unit are described. The effluent from the hydrogen production unit, which comprises a mixture of gases comprising hydrogen, carbon dioxide, water, and at least one of methane, carbon monoxide, nitrogen, and argon, is sent to a PSA system that produces at least two product streams for separation. The PSA system that produces at least two product streams separates the gas mixture into a high-pressure hydrogen stream enriched in hydrogen, optionally a second gas stream containing the majority of the impurities, and a low-pressure tail gas stream enriched in CO.sub.2 and some impurities. The CO.sub.2-rich tail gas stream is compressed and sent to a CO.sub.2 recovery unit, where a CO.sub.2-enriched stream is recovered. The CO.sub.2-depleted overhead gas stream is recycled to the PSA system that produces at least two product streams.

A device for producing purified oxygen, has a feed (1, 1′) of a mixture of oxygen and argon, and has at least one bed (2, 2A, 2B) of oxygen adsorption material, a purge (3, 3′) for discharging the separated argon and a circuit (4, 4′) for injecting a portion of the purified oxygen produced, into the feed (1, 1′). The device has a programmable logic controller (PLC) for treating the degree of purity and/or the production flow rate that can be set by the user and a control of said purge (3, 3′) as a function of the degree of purity of the purified oxygen and/or of the production flow rate which are desired by the user.

A process for separating components or a fluid mixture using membranes comprising a selective layer made from copolymers of an amorphous per fluorinated dioxolane and a fluorovinyl monomer. The resulting membranes have superior selectivity performance for certain fluid components of interest while maintaining fast permeance compared to membranes prepared using conventional perfluoropolymers, such as Teflon® AF, Hyflon® AD, and Cytop®.

A method for adjusting a gas stream separation unit having N adsorbers, where N≥2, each following a PSA, VSA or VPSA adsorption cycle, with a time lag of a phase time, said adjustment method including continuously measuring a physical parameter associated with the gas stream entering and/or leaving the adsorber; for at least one step of the adsorption cycle, determining at least one characteristic value of the step chosen in step a) which is selected from the values of the physical parameter measured in step a) or a function of those values; comparing this characteristic value with a target value; and modifying the flow of the gas stream in order to obtain the target value, in the event of a variation between the value of this (these) difference(s) and the target values.

The present invention relates to a polymer layered hollow fiber membrane based on poly(2,5-benzimidazole) (ABPBI), ABPBI copolymers and substituted polybenzimidazole (PBI) and a process for preparation thereof.