Patent classifications
B01D2257/404
Method for removing N2O and NOx from the nitric acid production process, and an installation suitable for same
The invention relates to a process and apparatus for preparing nitric acid by catalytic oxidation of NH.sub.3 by means of oxygen and subsequent reaction of the NO.sub.x formed with an absorption medium in an absorption tower, which comprises a catalyst bed for N.sub.2O decomposition arranged in the process gas downstream of the catalytic NH.sub.3 oxidation and upstream of the absorption tower in the flow direction and a catalyst bed for NO.sub.x reduction and effecting a further decrease in the amount of N.sub.2O arranged in the tailgas downstream of the absorption tower in the flow direction, wherein the amount of N.sub.2O removed in the catalyst bed for N.sub.2O removal arranged in the process gas is not more than that which results in an N.sub.2O content of >100 ppmv and a molar N.sub.2O/NO.sub.x ratio of >0.25 before entry of the tailgas into the catalyst bed for NO.sub.x reduction and the catalyst bed for NO.sub.x reduction and effecting a further decrease in the amount of N.sub.2O arranged in the tailgas contains at least one iron-loaded zeolite catalyst and NH.sub.3 is added to the tailgas before entry into the catalyst bed in such an amount that an NO.sub.x concentration of <40 ppmv results at the outlet from the catalyst bed and the operating parameters are selected in such a way that an N.sub.2O concentration of <200 ppmv results.
Cleaning stack gas
A method and apparatus for cleaning and recycling stack gas from coal-fired power plants, from natural or propane burning heating plants, or from cement kilns by using renewable catalysts of zeolite to separate pollutants into recyclable and reusable materials. The method reduces from the stack gas carbon monoxide (CO), carbon dioxide (CO.sub.2), nitrogen oxide (NOx), sulfur oxide (SOx) as well as halogens such as chloride and fluorides and trace metals particularly, mercury, lead, and zinc. The method and apparatus also result in production of fertilizer products by purging with gaseous or liquid nitrogen the zeolite beds through which the stack gas flows. The oxygen generated may be recycled to the burners in the plant.
PROCESSES USING MOLECULAR SIEVE SSZ-102
Uses are disclosed for a new crystalline molecular sieve designated SSZ-102 synthesized using an N,N′-dimethyl-1,4-diazabicyclo[2.2.2]octane dication as a structure directing agent. SSZ-102 has ESV framework topology.
Air Purification Device
An integrated autonomous air purification device for taking in polluted air, carrying it through the inside of the purification device where it passes through a set of filtering elements (1) that trap the dust particles contained in the air; ultraviolet-light lamps (2) that transform NO.sub.X and CO gases in the air into harmless compounds; an activated carbon filter (4) that traps and eliminates the volatile organic compounds and inorganic acidic gases; second filtering elements (5) that carry out a second filtering; and an extraction hood (6) configured to direct the air coming out of the second filtering elements (5) to at least one nozzle (7) that expels the air to the outside of the purification device.
Plasma generating apparatus and gas treating apparatus
A plasma generating apparatus may include a cathode assembly including a cathode, an anode assembly including an anode having therein a plasma generation space, and one or more magnetic force generators configured to generate a magnetic force. The anode assembly has one end portion in which a gas supply path is provided and the other end portion having an opening, the gas supply path configured to supply a plasma generating gas to the plasma generation space. The gas supply path is configured to generate a vortex of the plasma generating gas in the plasma generation space and said one or more magnetic force generators are arranged such that the magnetic force is generated in a direction opposite to a rotational direction of the vortex of the plasma generating gas.
Filter Medium for Separating Nitrogen Oxides
A filter medium is provided with a layer (A) provided with non-impregnated active carbon, a layer (B) with a solid carrier material that is impregnated with a permanganate salt, and a layer (C) with alkaline impregnated active carbon. The layer (B) and the layer (C) are arranged such that a gas flowing through the filter medium flows through the layer (B) before flowing through the layer (C). The layer (A) is arranged such that the gas flowing through the filter medium flows through the layer (A) before flowing through the layer (B) or the gas flowing through the filter medium flows through the layer (A) after flowing through the layer (C).
IN-SITU COPPER ION-EXCHANGE ON PRE-EXCHANGED COPPER ZEOLITIC MATERIAL
A process for preparing a catalyst comprising a zeolitic material comprising copper, the process comprising (i) preparing an aqueous mixture comprising water, a zeolitic material comprising copper, a source of copper other than the zeolitic material comprising copper, and a non-zeolitic oxidic material selected from the group consisting of alumina, silica, titania, zirconia, ceria, a mixed oxide comprising one or more of Al, Si, Ti, Zr, and Ce and a mixture of two or more thereof; (ii) disposing the mixture obtained in (i) on the surface of the internal walls of a substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end and a plurality of passages defined by internal walls of the substrate extending therethrough; and optionally drying the substrate comprising the mixture disposed thereon; (iii) calcining the substrate obtained in (ii).
Radial flow adsorber ‘U’ configuration
A radial U-flow adsorption unit for air purification in a TSA process, having a gas outlet at one end and at least one gas inlet at the side, preferably at the same end of the unit as the gas outlet. The simpler design of the unit facilitates manufacture, installation and transport, and reduces the capital and operating costs.
LIQUID TREATMENT APPARATUS
A liquid treatment apparatus comprises: a first tank in which a first gas containing nitrogen and oxygen and a liquid are stored; a plasma generating apparatus, including a first electrode and a second electrode, which effects discharge between the first electrode and the second electrode and thereby generates plasma that makes contact with at least part of the liquid; and a gas supply apparatus that supplies a first part of the first gas from the first tank to the plasma generating apparatus.
RENEWABLE TRANSPORTATION FUEL PROCESS WITH THERMAL OXIDATION SYSEM
A process for treating effluent streams in a renewable transportation fuel production process is described. One or more of the sour water stream and an acid gas stream are treated directly in thermal oxidation section. The process allows the elimination or size reduction of a sour water stripper unit, waste water treatment plant, and sulfur recovery unit.