Methods of preparing and using a metal-organic framework (MOF) are provided herein, including methods of using an MOF comprising a repeat unit of the formula [ML].sub.n, wherein M is a divalent metal ion and L is a ligand of the formula: ##STR00001##
The MOFs provided herein may be used in the separation of two or more molecules from each other. In some embodiments, the molecules are ethylene and ethane. In some embodiments, UTSA-280 may be synthesized from calcium oxide (CaO) or calcium hydroxide (Ca(OH).sub.2) and squaric acid (SA) through mechanochemical synthesis.

Disclosed is an absorbent containing an amine for absorption of an acid gas in a biogas, and a biogas purification system using the same.

In some embodiments, the present disclosure pertains to methods of capturing CO.sub.2 from an environment by hydrating a porous material with water molecules to the extent thereby to define a preselected region of a plurality of hydrated pores and yet to the extent to allow the preselected region of a plurality of pores of the porous material to uptake gas molecules; positioning the porous material within a CO.sub.2 associated environment; and capturing CO.sub.2 by the hydrated porous material. In some embodiments, the pore volume of the hydrated porous material includes between 90% and 20% of the pre-hydrated pore volume to provide unhydrated pore volume within the porous material for enhanced selective uptake of CO.sub.2 in the CO.sub.2 associated environment. In some embodiments, the step of capturing includes forming CO.sub.2-hydrates within the pores of the porous material, where the CO.sub.2.Math.n/H.sub.2O ratio is n<4.

Multi-fiber, fiber optic cable assemblies may be configured so that the terminal ends of the cables have pre-assembled back-post assemblies that include pre-assembled ferrules, such as MPO ferrules that meet the requisite tolerances needed for fiber optic transmissions. To protect the pre-assembled components from damage prior to and during installation, pre-assembled components may be enclosed within a protective housing. The housing with pre-assembled components may be of a size smaller than fully assembled connectors so as to be sized to fit through a conduit. The remaining connector housing components for the multi-fiber connectors may be provided separately and may be configured to be attached to the back-post assembly after installation of the cable.

An environmental control system includes an air conditioning subsystem and a contaminant removal subsystem downstream of the environment to be conditioned. The contaminant removal subsystem includes: a first gas-liquid contactor-separator; a second gas-liquid contactor-separator; and a dehumidifier disposed either upstream of the first gas-liquid contactor-separator or downstream of the second gas-liquid contactor-separator.

A device and method of generating an enriched gas within a nasal vestibule of a patient includes a housing, a chamber, a chamber inlet, a pump, a molecular sieve bed, a release outlet, and a breath duct. The chamber is configured to be received within the nasal vestibule. The pump is configured to direct an ambient air from an ambient environment into the chamber. The molecular sieve bed is positioned within the chamber and configured to collect a predetermined molecule from the ambient air thereby generating the enriched gas. The release outlet is configured to discharge the enriched gas from the chamber into the nasal vestibule. The breath duct longitudinally extends through the housing such that the breath duct is configured to fluidly communicate a fluid flow through the housing for nasal breathing by the patient while the chamber is positioned within the nasal vestibule.

A method for capturing carbon dioxide includes contacting a carbon dioxide lean gas mixture with water. One or more acid gas impurities may pass from the carbon dioxide lean gas mixture to the water to form a gas mixture and an aqueous effluent. The gas mixture is passed to a pressure swing adsorption system or a temperature swing adsorption system to increase a concentration of carbon dioxide in the gas mixture to form a carbon dioxide enriched gas mixture. The carbon dioxide enriched gas mixture is contacted with the aqueous effluent in a carbon dioxide scrubber. Carbon dioxide passes from the carbon dioxide enriched gas mixture to the aqueous effluent to form a stripped gas and acid gas enriched water. The acid gas enriched water is passed to a reactive rock formation. The one or more acid gas impurities and carbon dioxide are mineralized and permanently sequestered.

A method and system for manufacturing and using a self-supporting structure in processing unit for adsorption or catalytic processes. The self-supporting structure has greater than 50% by weight of the active material in the self-supporting structure to provide an open-celled structure providing access to the active material. The self-supporting structures, which may be disposed in a processing unit, may be used in swing adsorption processes and other processes to enhance the recovery of hydrocarbons.

There is an absorbent mixture usable for the removal of sour gases from gas mixtures. The mixture has at least one organic base having a pK.sub.b (in water) less than or equal to 3.2; at least one alcoholic solvent of general formula R(OH).sub.n having a boiling temperature above or equal to 100° C. at ambient pressure, wherein R is a linear or branched saturated alkyl group having a number of carbon atoms between 2 and 20 and n is a whole number varying between 1 and 20; an aprotic polar solvent having a dielectric constant ε at 25° C. greater than or equal to 30, a viscosity μ at 25° C. less than or equal to 14 cP, preferably less than or equal to 12 cP; and a boiling temperature at normal pressure equal to or above 130° C. There is also a process for the removal of sour gases using the absorbent mixture.

Method for separating gaseous carbon dioxide from air, in particular from ambient atmospheric air (1), by cyclic adsorption/desorption using a sorbent material (3), wherein said sorbent material (3) is a solid inorganic or organic, non-polymeric or polymeric support material functionalized on the surface with amino functionalities capable of reversibly binding carbon dioxide, with a specific BET surface area, preferably measured by nitrogen adsorption, in the range of 1-20 m2/g.