Aspects of the present disclosure are directed to mixtures and methods for pneumatically conveying powdered materials. A method includes providing a pneumatic conveyance system with a gas stream having a gas velocity; providing particles of sorbent material having a median sorbent particle size d.sub.50, sorbent from 1 m to 28 m; injecting the particles of sorbent material into the gas stream; providing particles of erodant material having a median erodant particle size d.sub.50, erodant of at least 150 m, where the erodant material is provided in an amount from 0.5% to 3% by weight of the particles of sorbent material; and injecting the particles of erodant material into the gas stream, where the gas velocity is sufficient to entrain the particles of sorbent material and sufficient to convey the particles of erodant material. A mixture of sorbent material and erodant material is also disclosed.

A sorbent composition for removing mercury from flue gas is provided. The sorbent composition contains at least a powdered sorbent, an oxidant and a catalyst. Methods of cleaning flue gas are also provided, which includes injecting the sorbent composition into the flue gas, wherein the powdered sorbent has a fifty percent distribution particle size of from about 25 micrometers to about 75 micrometers.

Adsorbers have many purposes in chemical, gas-processing, and petrochemical plants. Adsorbers may be used to remove components from gas streams. Adsorbers may be subjected to various issues, including but not limited to moisture breakthrough, spent catalyst, too high or too low pressure drop, over or under heating, over or under cooling, too high or too low flow rates, which can affect their performance or result in a shutdown of the adsorbers. Monitoring the adsorbers and the processes using adsorbers may be performed to determine if the adsorbent bed is reaching saturation, other problems are occurring, or if equipment failures are imminent. Monitoring also helps to predict behavior or problems in different adsorbers used in the same plant or in other plants and/or processes.

The present disclosure relates to a flue gas treatment system (e.g. a multi-pollutant flue gas treatment system) for removal of greenhouse gases such as SO.sub.2, NO, NO.sub.2, H.sub.2S, HCl, water and CO.sub.2 as well as heavy metals (e.g. mercury, arsenic, bismuth, cadmium, lead and/or selenium) from the flue gases of fossil-fueled utility and industrial plants by reacting the raw flue gas, firstly, with chlorine in a gas-phase oxidation reaction and recovering the resulting products as marketable products, and then, secondly, treating the cleaned gas, which includes CO.sub.2, with a Sabatier reaction to produce a hydrocarbon fuel (e.g. methane). The system also includes an electrolytic unit for electrolyzing HCl to produce hydrogen gas for the Sabatier reaction as well as chlorine gas, which may then be recycled into the reactor.

Sorbent compositions, comprising a solid sorbent, a dispersive agent, and optionally a capture agent for enhanced wet-Flue Gas Desulfurization (wFGD) or wet scrubber unit function in a flue gas pollutant control stream is disclosed. The sorbent composition may include a sorbent with a dispersive agent, designed to enhance the dispersion of the sorbent in an aqueous sorption liquid of a wet scrubber unit, and therefore may be especially useful in EGU or industrial boiler flue gas streams that include one or more wet scrubber units. The sorbent composition may also include a capture agent useful in sequestering mercury and bromine, as well as other contaminants that may include arsenic, selenium and nitrates.

A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

A cryogenic technology for the cost-efficient capture of each known component of emissions, such as carbon dioxide, sulfur oxides, nitrogen oxides, carbon monoxide, any other acid vapor, mercury, steam, in a liquefied or frozen/solidified form, and unreacted nitrogen (gas) from industrial plants, such that each of the components is captured separately with minimum use of energy and is industrially useful.

Methods of preparing a mercury sorbent material are provided. The methods comprise making a copper/clay mixture by admixing a dry clay and a dry copper source; making a sulfur/clay mixture by admixing a dry clay and a dry sulfur source; admixing the copper/clay mixture and the sulfur/clay mixture, to form a mercury sorbent premixture; and shearing the mercury sorbent pre-mixture to form the mercury sorbent material. Various substrates may be used with or instead of the clay, and various additives may be added to the copper, sulfur, clay, or mixture thereof.

The invention relates to a method for cleaning flue gas, the flue gas to be cleaned and a sorption agent starting material in the form of a solid being injected into a reactor chamber of a fluidized-bed reactor, and a liquid being injected into the reactor chamber separately from the flue gas and the sorption agent starting material, the sorption agent starting material being contacted with the liquid in the fluidized-bed reactor and being converted to a sorption agent in the form of a solid.

Sorbent compositions containing calcium and iodine are added to coal to mitigate the release of mercury and/or other harmful elements into the environment during combustion of coal containing natural levels of mercury.