B01D2258/014

Exhaust gas purification catalyst

The present disclosure provides the exhaust gas purification catalyst with the improved purification performance under the high Ga condition and the atmosphere where the A/F is rich. The present disclosure relates to an exhaust gas purification catalyst including a catalyst coating layer on a substrate, the catalyst coating layer containing a noble metal and a metal oxide, wherein in the catalyst coating layer: an average thickness of the coating layer is in a range from 50 m to 100 m; a porosity measured by a weight-in-water method is in a range from 50% by volume to 80% by volume; and high-aspect-ratio pores having an aspect ratio of 5 or more account for 0.5% by volume to 50% by volume of a whole volume of voids, the high-aspect-ratio pore having an equivalent circle diameter in a range from 2 m to 50 m in a cross-sectional image of a catalyst coating layer cross section perpendicular to an exhaust gas flow direction of the substrate and having an average aspect ratio in a range from 10 to 50, and wherein when a surface side in contact with an exhaust gas in a thickness direction of the catalyst coating layer is defined as 0% and a side in contact with the substrate is defined as 100%, 80% by mass or more of a total amount of the noble metal is present in a range from 0% to 25% or more and 70% or less.

CATALYST ARTICLE AND THE USE THEREOF FOR FILTERING FINE PARTICLES

A catalyst article and its use in an exhaust system for internal combustion engines is disclosed. The catalyst article comprises a substrate which is a wall-flow filter, a first catalyst composition, and a second catalyst composition. The first and second catalyst compositions each independently comprise an oxygen storage component (OSC) derived from a CeZr mixed oxide sol having a D90 of less than 1.3 micron and a particulate inorganic oxide having a D90 of from 1 to 20 microns.

EXHAUST GAS PURIFICATION SYSTEM FOR STOICHIOMETRIC-COMBUSTION ENGINES

The present invention relates to a stoichiometric-combustion spark-ignition engine comprising a specific exhaust gas system for reducing harmful exhaust gases resulting from the combustion process. The exhaust gas system consists in the through-flow direction of a three-way catalytic converter close to the engine, an oxidation catalyst and a gasoline particulate filter.

PGM nanoparticles TWC catalysts for gasoline exhaust gas applications

A three-way catalyst article, and its use in an exhaust system for internal combustion engines, is disclosed. The catalyst article for treating exhaust gas comprising: a substrate; and a first catalytic region on the substrate; wherein the first catalytic region comprises a first platinum group metal (PGM) component and a first inorganic oxide, wherein the first PGM component comprises PGM nanoparticles, wherein the PGM nanoparticles have no more than 100 PGM atoms, and wherein the PGM nanoparticles have a mean particle size of 1 nm to 10 nm with a standard deviation (SD) no more than 1 nm.

NOVEL MULTI-REGION TWC FOR TREATMENT OF EXHAUST GAS FROM GASOLINE ENGINE

Disclosed are a three-way catalyst product, and the use thereof in an exhaust system for an internal combustion engine. The catalyst product for exhaust gas treatment contains a carrier comprising an inlet end and an outlet end and having an axial length L; a first catalytic region starting from the inlet end and extending by a length less than the axial length L, wherein the first catalytic region contains a first palladium component; a second catalytic region starting from the outlet end and extending by a length less than the axial length L, wherein the second catalytic region contains a second palladium component; and a third catalytic region starting from the outlet end and extending by a length less than the axial length L, wherein the third catalytic region contains a third rhodium component, and the third catalytic region is stacked on the second catalytic region.

CATALYTICALLY ACTIVE PARTICULATE FILTER

The present invention relates to a particulate filter which comprises a wall flow filter of length L and two different catalytically active coatings Y and Z, wherein the wall flow filter comprises channels E and A that extend in parallel between a first and a second end of the wall flow filter and are separated by porous walls which form the surfaces O.sub.E and O.sub.A, respectively, and wherein the channels E are closed at the second end and the channels A are closed at the first end. The invention is characterized in that the coating Y is located in the channels E on the surfaces O.sub.E and the coating Z is located in the channels A on the surfaces O.sub.A.

EXHAUST GAS PURIFICATION CATALYST

The present disclosure provides the exhaust gas purification catalyst with the improved purification performance under the high Ga condition and the atmosphere where the A/F is rich. The present disclosure relates to an exhaust gas purification catalyst including a catalyst coating layer on a substrate, the catalyst coating layer containing a noble metal and a metal oxide, wherein in the catalyst coating layer: an average thickness of the coating layer is in a range from 50 m to 100 m; a porosity measured by a weight-in-water method is in a range from 50% by volume to 80% by volume; and high-aspect-ratio pores having an aspect ratio of 5 or more account for 0.5% by volume to 50% by volume of a whole volume of voids, the high-aspect-ratio pore having an equivalent circle diameter in a range from 2 m to 50 m in a cross-sectional image of a catalyst coating layer cross section perpendicular to an exhaust gas flow direction of the substrate and having an average aspect ratio in a range from 10 to 50, and wherein when a surface side in contact with an exhaust gas in a thickness direction of the catalyst coating layer is defined as 0% and a side in contact with the substrate is defined as 100%, 80% by mass or more of a total amount of the noble metal is present in a range from 0% to 25% or more and 70% or less.

NOVEL PGM NANOPARTICLES TWC CATALYSTS FOR GASOLINE EXHAUST GAS APPLICATIONS
20200353445 · 2020-11-12 ·

A three-way catalyst article, and its use in an exhaust system for internal combustion engines, is disclosed. The catalyst article for treating exhaust gas comprising: a substrate; and a first catalytic region on the substrate; wherein the first catalytic region comprises a first platinum group metal (PGM) component and a first inorganic oxide, wherein the first PGM component comprises PGM nanoparticles, wherein the PGM nanoparticles have no more than 100 PGM atoms, and wherein the PGM nanoparticles have a mean particle size of 1 nm to 10 nm with a standard deviation (SD) no more than 1 nm.

Monometallic rhodium-containing four-way conversion catalysts for gasoline engine emissions treatment systems

Catalyzed particulate filters comprise three-way conversion (TWC) catalytic material, which comprises rhodium as the only platinum group metal, that permeates walls of a particulate filter. Such catalyzed particulate filters may be located downstream of close-coupled three-way conversion (TWC) composites in an emission treatment system downstream of a gasoline direct injection engine for treatment of an exhaust stream comprising hydrocarbons, carbon monoxide, nitrogen oxides, and particulates.

Catalyst Article, Method and Use
20200346166 · 2020-11-05 ·

A three-way catalyst article is provided for the treatment of exhaust gas from a positive ignition engine, the catalyst article comprising: a substrate having a first layer provided thereon, wherein a second layer is provided on the first layer, wherein the first layer comprises a first metal and a first alumina, and wherein the second layer comprises a second metal and a second alumina, wherein either (i) the first metal is Pd and the second metal is Rh; or (ii) the first metal is Rh and the second metal is Pd; and wherein at least one of the first and second aluminas comprises theta alumina.