Patent classifications
B01D2258/014
HONEYCOMB CATALYTIC CONVERTER
The present invention relates to a honeycomb catalytic converter, including: a honeycomb structured body in which multiple through-holes are arranged longitudinally in parallel with one another with a partition wall therebetween; and Pd and Rh supported on the partition walls of the honeycomb structured body, wherein the honeycomb structured body is an extrudate containing a ceria-zirconia complex oxide and alumina, a Pd-carrying region where only Pd is supported is formed on the partition walls within a predetermined width from one end of the honeycomb structured body, and a Rh-carrying region where only Rh is supported is formed on the partition walls within a predetermined width from the other end of the honeycomb structured body, and the Pd-carrying region extends to at least 50% of the length of the honeycomb structured body, and the Rh-carrying region extends to at least 20% of the length of the honeycomb structured body.
ELECTRICALLY HEATED CATALYST
An electrically heated catalyst includes a honeycomb substrate, an electrode, and a joining section. The honeycomb substrate and the joining section include matrices and conductive fillers. The matrices contain borosilicate including at least one of an alkali metal and an alkaline earth metal. The joining section preferably has a softening point lower than that of the honeycomb substrate.
Exhaust gas purification catalyst
An exhaust gas purification catalyst, characterized by having a catalyst layer containing palladium, rhodium, and alumina, which supports a sulfate of an alkaline-earth metal selected from barium sulfate and strontium sulfate, and the correlation coefficients .sub.Pd,AE and .sub.Rh,AE calculated from the characteristic X-ray intensity measured using an electron beam micro-analyzer for the palladium, rhodium, and alkaline-earth metal being +0.75 to +1.00 and 0.00 to +0.25, respectively, using 350 points as measurement points obtained by equally dividing the catalyst layer into 351 parts in the thickness direction on a virtual straight line that runs through the catalyst layer in the thickness direction.
Exhaust purification system of internal combustion engine
An exhaust purification system includes an LAF sensor provided in an exhaust pipe and generates a signal corresponding to an air-fuel ratio of exhaust gas. An upstream catalytic converter is downstream of the LAF sensor and has a catalyst to purify the exhaust gas. An O2 sensor is downstream of the upstream catalytic converter, and generates a signal corresponding to the air-fuel ratio of the exhaust gas. A GPF is downstream of a the O2 sensor and purifies the exhaust gas. An ECU controls an air-fuel mixture in an engine using output signal KACT of the LAF sensor and an output signal VO2 of the O2 sensor such that the air-fuel ratio of exhaust gas flowing into the GPF converges to a target value near the stoichiometric ratio. The GPF has a filter substrate and a downstream TWC supported by a partition of the filter substrate.
CHABAZITE ZEOLITE CATALYSTS HAVING LOW SILICA TO ALUMINA RATIOS
Disclosed are zeolite catalysts having the CHA crystal structure with a low silica to alumina ratio, as well as articles and systems incorporating the catalysts and methods for their preparation and use. The catalysts can be used to reduce NOx from exhaust gas streams, particularly those emanating from gasoline or diesel engines.
PROMOTER METAL CONTAINING PEROVSKITE-TYPE COMPOUND FOR GASOLINE EXHAUST GAS APPLICATIONS
A three-way catalyst composition, and its use in an exhaust system for internal combustion engines, is disclosed. The composition can comprise a compound of formula (I): A.sub.x-yA.sub.yB.sub.1-zB.sub.zO.sub.3 and a promoter metal component, wherein A is an ion of a metal of group 2 or 3 of the periodic table of elements; wherein A is an ion of a metal of group 1, 2, or 3 of the periodic table of elements; wherein B and B are ions of metal of groups 4, 6, 7, 8, 9, 10, 11, or 13 of the periodic table of elements; wherein x is from 0.7 to 1; wherein y is from 0 to 0.5; and wherein z is from 0 to 0.5.
Exhaust purification filter
Provided is a GPF capable of exhibiting better than conventional three-way purification function. A gasoline particulate filter (GPF) that is provided in an exhaust pipe of an engine and that performs purification by capturing particulate matter (PM) in exhaust gas is provided with a filter substrate in which a plurality of cells extending from an exhaust gas inflow-side end face to an outflow-side end face are defined by porous partition walls and in which openings at the inflow-side end face and openings at the outflow-side end face of the cells are alternately sealed; and a three-way catalyst (TWC) supported by the partition wall. The three-way catalyst is the GPF comprising a catalytic metal containing at least Rh, and a composite oxide having an oxygen storage capacity and containing Nd and Pr in a crystal structure.
DELAFOSSITE-TYPE OXIDE FOR EXHAUST GAS PURIFICATION CATALYST, AND EXHAUST GAS PURIFICATION CATALYST USING SAME
In relation to a Cu-based delafossite-type oxide that is effective as an exhaust gas purification catalyst, Cu is placed in a high catalytic activity low-valence state, whereby a novel Cu-based delafossite-type oxide having higher activity than in the past is provided. Proposed is a delafossite-type oxide for an exhaust gas purification catalyst that is represented by a general formula ABO.sub.2, wherein Cu and Ag are contained in the A site of the general formula, one or two or more elements selected from the group consisting of Mn, Al, Cr, Ga, Fe, Co, Ni, In, La, Nd, Sm, Eu, Y, V, and Ti are contained in the B site of the general formula, and Ag is contained at a ratio of 0.001 at. % or more and less than 20 at. % in the A site of the general formula.
Three layer NOx adsorber catalyst
A lean NO.sub.x trap catalyst and its use in an emission treatment system for internal combustion engines is disclosed. The lean NO.sub.x trap catalyst comprises a first layer, a second layer, and a third layer.
Chabazite zeolite catalysts having low silica to alumina ratios
Disclosed are zeolite catalysts having the CHA crystal structure with a low silica to alumina ratio, as well as articles and systems incorporating the catalysts and methods for their preparation and use. The catalysts can be used to reduce NOx from exhaust gas streams, particularly those emanating from gasoline or diesel engines.