A treatment method and apparatus is provided to effectively use a combustible waste such as waste plastic, waste tires, rice husk, wood shavings, PKS, RDF and sludge while maintaining stable operation; to improve the combustion efficiency of a fossil fuel such as coal and coke; and furthermore to reduce the NOx concentration in a cement kiln exhaust gas. An apparatus 1 for treating a combustible, the apparatus comprising: a mixer 3 for mixing a combustible C with a preheated raw material R2, which has a temperature of 600° C. or higher and 900° C. or lower and which is drawn from a preheater cyclone of a cement burning device 10, to gasify the combustible; and a feeder 5 for feeding the gasified combustible and the preheated raw material (mixed raw material M) to a region from an inlet end 13a of the cement burning device to a calciner 12. When the combustible and the preheated raw material are mixed, moisture may be added to cause water gas shift reaction, and the resultant water gas and the preheated raw material may be introduced to the region from the inlet end of the cement burning device to the calciner.

The present disclosure provides systems for carbon capture in combination with production of one or more industrially useful materials. The disclosure also provides methods for carrying out carbon capture in combination with an industrial process. In particular, carbon capture can include carrying out calcination in a reactor, separation of carbon dioxide rich flue gases from industrially useful products, and capture of at least a portion of the carbon dioxide for sequestration of other use, such as enhanced oil recovery.

A catalyst comprises a mixture of 95% vol. to 30% vol. of an activated carbon catalyst and from 5% vol. to 70% vol. of a filler material as well as a configuration of such a catalyst for the removal of SO.sub.2, heavy metals and/or dioxins form waste gas and liquids.

A contaminated gas stream can be passed through an in-line mixing device, positioned in a duct containing the contaminated gas stream, to form a turbulent contaminated gas stream. One or more of the following is true: (a) a width of the in-line mixing device is no more than about 75% of a width of the duct at the position of the in-line mixing device; (b) a height of the in-line mixing device is no more than about 75% of a height of the duct at the position of the in-line mixing device; and (c) a cross-sectional area of the mixing device normal to a direction of gas flow is no more than about 75% of a cross-sectional area of the duct at the position of the in-line mixing device. An additive can be introduced into the contaminated gas stream to cause the removal of the contaminant by a particulate control device.

Described herein is a system (100) for storage and releasing of carbon dioxide comprising at least one solids reactor (1), at least one compressor (7, 8) for compressing the carbon dioxide-containing gas or fluid, respectively, which is introduced through the inlet (3) of the solids reactor, wherein the compressor (7, 8) is constructed in such a way that it adiabatically expands the gas or fluid, respectively, depleted of carbon dioxide that is discharged from the reactor by means of the outlet (2) of the solids reactor, and at least one countercurrent recuperator (6), which is constructed for the heat exchange of the compressed exhaust gas or fluid, respectively, that contains carbon dioxide and the gas or fluid, respectively, depleted of carbon dioxide.

Described is furthermore a solids reactor for storage and releasing carbon dioxide, comprising a gas-tight or fluid-tight, respectively, housing, which has an interior, at least one inlet for feeding in fluids and at least one outlet for discharging of gases or fluids, respectively, wherein the interior of the housing is filled with at least two different solids, wherein one solid is provided for storing thermal energy and the other solid is provided for regenerative storage and releasing of carbon dioxide.

Furthermore described is a method for storage and releasing of carbon dioxide.

A thermo-electrochemical reactive capture apparatus includes an anode and a cathode, wherein the anode includes a first catalyst, wherein the cathode includes a second catalyst, a porous ceramic support positioned between the anode and the cathode, an electrolyte mixture in pores of the ceramic support, and a steam flow system on an outer side of the cathode. The outer side of the cathode is opposite an inner side of the cathode and the inner side of the cathode is adjacent to the ceramic support. In addition, the electrolyte mixture is configured to be molten at a temperature below about 600° C.

Calcium hydroxide-containing compositions can be manufactured by slaking quicklime, and subsequently drying and milling the slaked product. The resulting calcium hydroxide-containing composition can have a size, steepness, pore volume, and/or other features that render the compositions suitable for treatment of exhaust gases and/or removal of contaminants. In some embodiments, the calcium hydroxide-containing compositions can include a D.sub.10 from about 0.5 microns to about 4 microns, a D.sub.90 less than about 30 microns, and a ratio of D.sub.90 to D.sub.10 less than 20, wherein individual particles include a surface area greater than or equal to about 25 m.sup.2/g.

A method of exhaust gas scrubbing includes providing recycled concrete fines as a waste material rich in carbonatable Ca and/or Mg phases and with d.sub.90≤1000 μm and a Rosin-Rammler slope n from 0.6 to 1.4 , injecting the waste material into an exhaust gas stream containing CO.sub.2 and/or SO.sub.x for reaction with CO.sub.2 and/or SO.sub.x at a relative humidity of 50 to 100 Vol.-% and a temperature from 40 to 130° C. in an amount of dry waste material ranging from 5 to 30 kg/m.sup.3, withdrawing a partly carbonated and/or sulphurized waste material and purified exhaust gas, and recycling a part of the partly carbonated and sulphurized waste material while the remainder is discharged, as well as use of a waste material slurry for exhaust gas cleaning of CO.sub.2 and/or SO.sub.x.

Provided is a method of fixing a sufficient amount of carbon dioxide contained in a carbon dioxide-containing gas (e.g., a plant exhaust gas) simply, at low cost, and efficiently. The method of fixing carbon dioxide includes a contact step of bringing a carbon dioxide-containing gas into contact with powdery or grainy particles, which are each formed of a cementitious hardened body and each have a particle size of 40 mm or less, at a temperature of from 75° C. to 110° C. to fix carbon dioxide contained in the carbon dioxide-containing gas to the powdery or grainy particles, wherein the relative humidity of the carbon dioxide-containing gas is adjusted in accordance with the particle size of the powdery or grainy particles and the state of adjustment of moisture content of the powdery or grainy particles before the contact step.

The present invention relates to a method of capturing CO.sub.2 from a gas stream. The method uses a two liquid phase capture composition.