A process to treat/clean a gas, containing SO.sub.2, CO.sub.2 and O.sub.2 comprising the steps of: bringing the gas in contact with an activated carbon catalyst, converting SO.sub.2 to SO.sub.3/H.sub.2SO.sub.4 on the activated carbon catalyst, washing the SO.sub.3/H.sub.2SO.sub.4 from the activated carbon catalyst to obtain a sulfuric acid solution and a SO.sub.2 depleted gas; bringing the SO.sub.2 depleted gas in contact with an aqueous ammonia solution wherein CO.sub.2 is converted to obtain a SO.sub.2 and CO.sub.2 depleted gas containing ammonia; and bringing the SO.sub.2 and CO.sub.2 depleted gas containing ammonia in contact with the sulfuric acid solution obtained in step a. to form a solution containing ammonium sulfate and a treated, clean gas.

The invention pertains to processes for separating gases, acid gas, hydrocarbons, air gases, or combinations thereof. The processes may employ using a liquid phase cloud point with or without subsequent liquid-liquid separation. In some embodiments membranes can be employed with reverse osmosis to regenerate a solvent and/or an antisolvent. In some embodiments thermal switching phase changes may be employed during absorption or desorption to facilitate separation.

The invention relates to the technical field of the treatment of exhaust gases containing sulfur oxides, especially exhaust gases from technical combustion plants, the so-called flue gases, or exhaust gases from technical processes, such as steel production (e.g. blast furnace gases, etc.) Especially, the invention relates to a method for the treatment of exhaust gases containing sulfur oxides, in particular from technical combustion plants, such as flue gases, or from technical processes, for the purpose of removing and/or separating off the sulfur oxides or for the purpose of reducing the sulfur oxide content, as well as a system for carrying out the method.

The present invention relates to a system and method for desulfurization and denitrification integrated treatment and recycling of flue gas by using red mud, and belongs to the recycling and environmental protection technology field. The system includes a desulfurization spray tower, an ozone generator, a denitration spray tower, a slurry mixing tank, a slurry storage tank, a vacuum filter, an ammonia water neutralization tank, an aluminum hydroxide precipitation tank, an ammonia water tank, an aluminum hydroxide storage tank, a filter press, an ammonia distillation tower, a dephlegmator, a cooler, a concentrated ammonia water storage tank, a gypsum precipitation tank, and an anaerobic biochemical pool. In the present invention, red mud slurry is used for desulfurization and denitrification treatment of flue gas to remove SO.sub.2 and NO in the flue gas, so that SO.sub.2 and NO in the flue gas reach an emission standard.

The present disclosure provides systems for carbon capture in combination with production of one or more industrially useful materials. The disclosure also provides methods for carrying out carbon capture in combination with an industrial process. In particular, carbon capture can include carrying out calcination in a reactor, separation of carbon dioxide rich flue gases from industrially useful products, and capture of at least a portion of the carbon dioxide for sequestration of other use, such as enhanced oil recovery.

An efficient long-service-life blowing method include the steps of introducing vanadium extraction converter flue gas and decarburization converter flue gas into an oxygen combustor; obtaining first-purity CO.sub.2N.sub.2 mixed gas through the vanadium extraction converter flue gas; obtaining second-purity CO.sub.2N.sub.2 mixed gas through the decarburization converter flue gas; obtaining O.sub.2CO.sub.2N.sub.2 mixed gas through the decarburization converter flue gas; obtaining first-purity CO.sub.2 gas through the second-purity CO.sub.2N.sub.2 mixed gas; and using the first-purity CO.sub.2N.sub.2 mixed gas for bottom blowing of the vanadium extraction converter, using the second-purity CO.sub.2N.sub.2 mixed gas as a carrier gas for blowing iron ore powder into the vanadium extraction converter, and using the O.sub.2CO.sub.2N.sub.2 mixed gas and the first-purity CO.sub.2 gas as a carrier gas for bottom blowing of the decarburization converter and bottom injecting of lime powder into the decarburization converter.

The invention discloses a method for simultaneously removing SO.sub.2 and NO.sub.x in flue gas: uniformly mixing a water-soluble ruthenium salt with ammonia water to obtain an aqueous solution of a ruthenium-amine complex; subjecting the flue gas and the aqueous solution of the ruthenium-amine complex to a countercurrent contact reaction under the temperature of 5-60 C., pH of 7.5-12 to obtain a solution A and purified gas; discharging the solution A of the step (2) into a crystallization tank to crystallize and separate an ammonium salt to obtain a solution B, returning the solution B to replace the aqueous solution of the ruthenium-amine complex. The invention utilizes the ruthenium-amine complex having a strong capability of complexing with NO as well as residual oxygen in the flue gas to carry out liquid phase catalytic oxidation to convert the NO.sub.x into ammonium nitrate, and the removal efficiency of the NO.sub.x and the SO.sub.2 is high.

A denitration catalyst for removing nitrogen oxide in an exhaust gas is represented by the following chemical formula: Ba.sub.3Y.sub.(4-x)A.sub.xO.sub.9, wherein A is an element selected from the group consisting of Bi, Sn, Ga, Mn, Ti, and Al; and X is 0.4 or more and 2 or less. A denitration device has the denitration catalyst for removing nitrogen oxide in an exhaust gas discharged from an exhaust gas generation source including a gas engine, a gas turbine, a melting furnace, or a boiler.

The present process invention in continuation to the U.S. Ser. No. 14/392,066 appertains to Advanced Combustion in post-combustion carbon capture, wherein the CO.sub.2-containing flue gas, said CO2-Stream, is cleaned from harmful constituents, recirculated, oxygenized and employed for combustion for the fossil fuels, referred to Flue Gas Oxy-Fueling in order to obtain a CO.sub.2-rich gas upstream to CO2-CC with significantly less gas flow rate subject to further processing. This continuation process patent also presents processing to prepare a CO.sub.2-rich CO2-Stream for the pre-combustion carbon capture downstream of gasification and gas cleaning process; or from the secondary CO2-Stream that stems from the cathodic syngas [CO/2H.sub.2] downstream of HPLTE-SG of patent parent, then downstream of the HP/IP-water shift converters in [CO.sub.2/3H.sub.2] composition, whereas the CO.sub.2-rich CO2-Stream from either pre-combustion process is routed to the CO2-CC for CO.sub.2 cooling and condensation section of the U.S. Ser. No. 14/392,066 to obtain liquid carbon dioxide for re-use as new fossil energy resource.

A denitration catalyst for removing nitrogen oxide in an exhaust gas is represented by the following chemical formula: Ba.sub.3Y.sub.(4-x)A.sub.xO.sub.9, wherein A is an element selected from the group consisting of Bi, Sn, Ga, Mn, Ti, and Al; and X is 0.4 or more and 2 or less. A denitration device has the denitration catalyst for removing nitrogen oxide in an exhaust gas discharged from an exhaust gas generation source including a gas engine, a gas turbine, a melting furnace, or a boiler.