An integrated fuel combustion system with gas separation (adsorptive, absorptive, membrane or other suitable gas separation) separates a portion of carbon dioxide from a combustion gas mixture and provides for recycle of separated carbon dioxide to the intake of a fuel combustor for combustion. A process for carbon dioxide separation and recycle includes: admitting combustion gas to an adsorptive gas separation system contactor containing adsorbent material; adsorbing a portion of carbon dioxide; recovering a first product stream depleted in carbon dioxide for release or use; desorbing carbon dioxide from the adsorbent material and recovering a desorbed second product stream enriched in carbon dioxide for sequestration or use; admitting a conditioning and/or desorption fluid into the contactor and desorbing a second portion of carbon dioxide to recover a carbon dioxide enriched conditioning stream; and recycling a portion of the carbon dioxide enriched conditioning stream to an inlet of fuel combustor to pass through the fuel combustor for combustion.

A gas stream is purified by a TSA adsorption scheme including at least two adsorbers following, in an offset manner, a cycle including an adsorption phase, and a subsequently, a regeneration phase. The regeneration phase includes a depressurization step, a pre-regeneration step and a regeneration step. A gas circulator is used to circulate the gas within the adsorber in the pre-regeneration step in a closed loop while the circulating gas is heated with a heater.

An adsorption process is provided to remove oxygen from a hydrogen stream through the use of a copper material in combination with layers of adsorbent to remove water and nitrogen from a hydrogen stream. This process is particularly useful for purification of hydrogen product gas from water electrolyzers with the hydrogen product gas having greater than 99.9 mol % purity.

A device for drying compressed gas with an inlet for compressed gas to be dried originating from a compressor and an outlet for dried compressed gas, where this device includes a number of vessels that are filled with a regeneratable drying agent and a controllable valve system that connects the aforementioned inlet and outlet to the aforementioned vessels, where the device includes at least three vessels, where the aforementioned valve system is such that at least one vessel is always being regenerated, while the other vessels dry the compressed gas, where due to the control of the valve system the vessels are each successively regenerated in turn.

In a method of operating an adsorption apparatus including a plurality of adsorption beds each packed with a physical adsorbent, when an adsorption step is performed in a part of the adsorption beds and another adsorption bed is to be regenerated, after the adsorption target component adsorbed on the physical adsorbent is desorbed, a gas for cooling is caused to flow through the another adsorption bed so that the another adsorption bed is cooled until an outlet temperature of the another adsorption bed reaches a temperature set in advance. Further, the cooled adsorption bed stands by for switching to the adsorption step while a gas for standby for maintaining a cooled state is caused to flow through the cooled adsorption bed.

A carbon capture system can include a plurality of CO.sub.2 thermal swing adsorption (TSA) beds. The plurality of CO.sub.2 TSA beds can include at least a first TSA bed, a second TSA bed, and a third TSA bed configured to capture CO.sub.2 within a capture temperature range and to regenerate the captured CO.sub.2 at a regeneration temperature range above the capture temperature range. The carbon capture system can include a plurality of valves and associated flow paths configured to allow switching operational modes of each of the first, second, and third TSA beds.

Generally, a cyclic sorptive gas separation process can comprise a feed or sorbing step followed by a regenerating step. In embodiments, the sorbing step can involve admitting said feed stream into a contactor, sorbing at least a portion of a first component onto a sorbent, producing a first product stream, and recovering a first product stream. In embodiments, the regenerating step can comprise admitting or feeding the first regeneration stream into the contactor, sorbing a fraction of a third component onto the contactor, desorbing a fraction of the first component, and recovering a second product stream from the contactor, wherein the regeneration step further comprises controlling a partial pressure of the third component to a partial pressure threshold equal to or greater than 0.4 Bara.

A method for operating a temperature swing adsorption plant having three adsorption units which are operated in an adsorption phase, a feed phase, a regeneration phase, a flush phase, and a cooling phase, wherein in the adsorption phase a first gas mixture at a first temperature is guided over an adsorbent in the adsorption units with obtention of a second gas mixture and adsorption onto the adsorbent of components of the first gas mixture, in the regeneration phase the adsorption units are heated and the components adsorbed by the adsorbent during the adsorption mode are at least partially desorbed, and in the flush phase the components which were desorbed during the regeneration mode are at least partially flushed using a third gas mixture with obtention of a fourth gas mixture. In the cooling phase, the adsorption units are at least partially cooled to the first temperature.

An adsorption process is provided to remove oxygen from a hydrogen stream through the use of a copper material in combination with layers of adsorbent to remove water and nitrogen from a hydrogen stream. This process is particularly useful for purification of hydrogen product gas from water electrolyzers with the hydrogen product gas having greater than 99.9 mol % purity.

Provided is method for concentrating ozone gas the method including the steps of: allowing ozone gas to be adsorbed onto the adsorbent by introducing ozone gas-containing raw material mixed gas into an adsorption vessel (20) that houses an adsorbent for adsorbing ozone gas; reducing a pressure in a concentration vessel (30) in a state where the concentration vessel (30) does not communicate with the adsorption vessel (20), the concentration vessel (30) being configured to be connected to the adsorption vessel (20) so as to be interswitchable between a state where the concentration vessel (30) communicates with the adsorption vessel (20) and a state where the concentration vessel does not communicate with the adsorption vessel (20); and introducing concentrated mixed gas including ozone gas with a higher ozone gas concentration than the ozone gas concentration in the raw material mixed gas into the concentration vessel (30) by desorbing the ozone gas adsorbed onto the adsorbent using a pressure difference between the internal pressure of the concentration vessel (30) and an internal pressure of the adsorption vessel (20) in a state where the concentration vessel (30) having a reduced internal pressure communicates with the adsorption vessel (20) that houses the adsorbent onto which the ozone gas is adsorbed, and delivering the desorbed ozone gas into the concentration vessel (30). Also provided is an apparatus (1) for concentrating ozone gas for implementing the method.