A method of continuous ozone production using a system of four absorbent beds to separate an ozone and oxygen gas mixture generated in an ozone generator. The beds are operated according to an offset sequence of cycles. Oxygen passing through the beds is at least partially recycled for use in further ozone generation. The concentration of oxygen in the ozone product can be reduced using the system to make it suitable for use in fine chemical applications.

A method for the continuous production of ozone and recovery of oxygen in a purge cycle adsorption process having four adsorbent beds. The method has the steps of feeding a mixture of ozone and oxygen to a first and second adsorbent bed wherein the first and the second adsorbent bed adsorb ozone and allow oxygen to pass through; recovering the oxygen from the first bed; feeding the oxygen from the second bed to a fourth adsorbent bed, wherein ozone is desorbed from the fourth bed; feeding clean dry air through a valve to the third adsorbent bed, and measuring the flow rate of the clean dry air through the valve, comparing this flow rate to a pre-calculated value and adjusting the flow rate of the clean dry air to equal the pre-calculated value; desorbing ozone from the third bed; and recovering ozone from the third bed and the fourth bed.

A method for producing oxygen by adsorbing a stream of atmospheric air, using four VPSA, one air compressor and two vacuum pumps, each adsorber undergoing a single pressure cycle including the following steps: a) producing a first stream of gas having an oxygen content T1 while loading the adsorber of the stream of atmospheric air upstream; b) producing a second stream of gas including an oxygen content T2<T1: c) producing a third stream of gas including an oxygen content T3<T2<T1 while simultaneously extracting a nitrogen-enriched residual stream; d) eluting the adsorber, from which the three streams of gas produced in steps a), b), and c) are taken with the second stream of gas produced in step b); e) repressurizing the adsorber consecutively with at least two streams, first and second repressurizing streams, with increasing oxygen content.

A process of treating a natural gas stream is provided comprising sending natural gas stream through a first adsorbent bed to remove water and heavy hydrocarbons (C8+) to produce a partially treated gas stream in which the first adsorbent bed is regenerated by a temperature swing adsorption process and then sending the partially treated gas stream through a second adsorption bed to remove carbon dioxide and lighter hydrocarbons (C7) to produce a purified natural gas stream wherein said second adsorption bed is regenerated by a temperature pressure swing adsorption process.

Methods and systems for capture of CO.sub.2 from a hydrated gaseous stream are described. Systems can be utilized for direct air capture of CO.sub.2 and incorporate a low energy temperature-vacuum swing adsorption (TVSA) process. A TVSA process can include a multi-step CO.sub.2 capture bed regeneration process that includes depressurization of the bed, heating of the bed, venting and purging of the bed, and cooling of the bed. Multiple beds can be cycled between CO.sub.2 capture and regeneration, during which captured CO.sub.2 is recovered. Off-gas from a CO.sub.2 capture bed can be used in regenerating a parallel bed for increased efficiency.

The present invention is directed to an intensified process cycle that utilizes the adsorption beds present to a substantially greater degree allowing the processing of significantly more gas and/or the generation of significantly more product. The elimination of purge steps, reduction in equalization step times, and introduction of overlapping feed and equalization steps which normally cause a degradation in performance for equilibrium-based cycles, frees extra step for other actions to be taken, such as additional equalization steps, etc.

An evaporative emission control canister system comprises an initial adsorbent volume having an effective incremental adsorption capacity at 25 C. of greater than 35 grams n-butane/L between vapor concentration of 5 vol % and 50 vol % n-butane, and at least one subsequent adsorbent volume having an effective incremental adsorption capacity at 25 C. of less than 35 grams n-butane/L between vapor concentration of 5 vol % and 50 vol % n-butane, an effective butane working capacity (BWC) of less than 3 g/dL, and a g-total BWC of between 2 grams and 6 grams. The evaporative emission control canister system has a two-day diurnal breathing loss (DBL) emissions of no more than 20 mg at no more than 210 liters of purge applied after the 40 g/hr butane loading step.

The present disclosure relates to a pressure swing adsorption apparatus for hydrogen purification from decomposed ammonia gas and a hydrogen purification method using the same, and more particularly, the pressure swing adsorption apparatus of the present disclosure includes a plurality of adsorption towers including a pretreatment unit and a hydrogen purification unit wherein the adsorption towers of the pretreatment unit and the hydrogen purification unit are packed with different adsorbents, thereby achieving high purity hydrogen purification from mixed hydrogen gas produced after ammonia decomposition, making it easy to replace the adsorbent for ammonia removal, minimizing the likelihood that the lifetime of the adsorbent in the hydrogen purification unit is drastically reduced by a very small amount of ammonia, and actively responding to a large change in ammonia concentration in the raw material.

Additionally, a hydrogen purification method using the pressure swing adsorption apparatus of the present disclosure physically adsorbs and removes impurities such as moisture (H.sub.2O), ammonia (NH.sub.3) and nitrogen (N.sub.2) included in mixed hydrogen gas produced after ammonia decomposition below extremely small amounts, thereby achieving high purity hydrogen purification with improved selective adsorption of moisture, ammonia and nitrogen and maximized hydrogen recovery rate and productivity. In addition, since the temperature swing adsorption process is not introduced, there is no need for a heat source for regeneration, thereby reducing the driving cost.

A sorption filter element for a sorption filter device includes at least two sorption bodies with at least one sorbent, the at least two sorption bodies being arranged in a V-shape and enclosing an intermediate space that is open at a head side thereof, and an outer sealing element running around an outer circumference of the head side. The sorption filter element further includes an inner sealing surface arranged at the head side and running around a circumference delimiting the intermediate space at the head side, the inner sealing surface being axially set back relative to the outer sealing element and being arranged within the intermediate space.

Systems and methods are provided for performing CO.sub.2 sorption and desorption using a sorbent structure with an integrated heat pump. The integrated heat pump can allow at least a portion of the heat generated during sorption to be recovered by forming steam from water. The steam raised during the sorption process can then be compressed and optionally heated to raise the temperature of the steam. The compressed and optionally heated steam can then be used as at least a portion of the steam for desorption of CO.sub.2 in the same sorbent bed or a different sorbent bed. By recovering the heat of sorption to raise steam, substantial energy savings can be achieved relative to a conventional process.