The present invention provides a system for the capture and purification CO.sub.2 and a purification unit for said system, wherein said purification unit comprises: a first filter having a first container and a first filler material; a second filter having a second container and a second filler material, downstream of said first filter; a third filter having a third container and a third filler material, downstream of said second filter, said third filter having, additionally, a heating element thermally coupled to said third filler material; and control means of said heating element; wherein said first filler material is silica; wherein said second filler material is zeolite; and wherein said third filler material is a metal-organic framework modified with activated carbon.

A water harvesting device includes at least a first adsorption column including a first inlet, a first outlet, and a first interior region. A sorbent material is located within the first interior region of the first adsorption column. The sorbent material includes a metal organic framework (MOF) material including a plurality of metal ions or clusters of metal ions coordinated to one or more organic linkers, a plurality of nanofabrics comprising a hydrogel material, or a combination thereof.

Systems for generation of liquid water are provided. In embodiments, the systems comprise a thermal desiccant unit comprising a porous hygroscopic material located within a housing including a fluid inlet and a fluid outlet, a working fluid that accumulates heat and water vapor upon flowing from fluid inlet of the housing, through the porous hygroscopic material, and to the fluid outlet of the housing, a condenser comprising a fluid inlet and a fluid outlet for condensing water vapor from the working fluid; an enthalpy exchange unit operatively coupled between the thermal desiccant unit and the condenser, wherein the enthalpy exchange unit transfers enthalpy between the working fluid output from the thermal desiccant unit and the working fluid input to the thermal desiccant unit, and, wherein the enthalpy exchange unit transfers enthalpy between the working fluid output from the condenser and the working fluid input to the condenser.

Methods and systems of collecting carbon dioxide are disclosed. In one example, a method includes removing water from atmospheric air with a condenser and a desiccant material to produce dry air, adsorbing carbon dioxide to a material from the dry air, releasing the adsorbed carbon dioxide to a vacuum chamber, and transitioning the released carbon dioxide from a gas to a solid in the vacuum chamber.

Disclosed are embodiments of a filter unit containing a water adsorbent material in the form of water adsorbent particles in a packed bed and a gas adsorbent material in the form of gas adsorbent particles in a packed bed. In embodiments, the gas adsorbent material is downstream from the water adsorbent material in a direction of operation. Further disclosed are methods of preparing and using the filter units.

Systems for generation of liquid water are provided. In embodiments, the systems comprise a thermal desiccant unit comprising a porous hygroscopic material located within a housing including a fluid inlet and a fluid outlet, a working fluid that accumulates heat and water vapor upon flowing from fluid inlet of the housing, through the porous hygroscopic material, and to the fluid outlet of the housing, a condenser comprising a fluid inlet and a fluid outlet for condensing water vapor from the working fluid; an enthalpy exchange unit operatively coupled between the thermal desiccant unit and the condenser, wherein the enthalpy exchange unit transfers enthalpy between the working fluid output from the thermal desiccant unit and the working fluid input to the thermal desiccant unit, and, wherein the enthalpy exchange unit transfers enthalpy between the working fluid output from the condenser and the working fluid input to the condenser.

A system and method for sulfur recovery, including hydrogenating Claus tail gas, quenching the hydrogenated gas, adsorbing water and hydrogen sulfide from the quenched gas, and regenerating adsorbent with carbon dioxide and/or nitrogen and heating the adsorbent in a regeneration temperature ramp to desorb primarily hydrogen sulfide in a first part of the temperature ramp.

Methods and systems for capture of CO.sub.2 from a hydrated gaseous stream are described. Systems can be utilized for direct air capture of CO.sub.2 and incorporate a low energy temperature-vacuum swing adsorption (TVSA) process. A TVSA process can include a multi-step CO.sub.2 capture bed regeneration process that includes depressurization of the bed, heating of the bed, venting and purging of the bed, and cooling of the bed. Multiple beds can be cycled between CO.sub.2 capture and regeneration, during which captured CO.sub.2 is recovered. Off-gas from a CO.sub.2 capture bed can be used in regenerating a parallel bed for increased efficiency.

A multi-stage process to remove contaminant gases from raw methane streams is provided. The present technology is an innovative solution to recover and purify biogas by use of a process having at least two pressure swing adsorption stages. Taking advantage of the presence of carbon dioxide in the raw biogas streams, nitrogen and oxygen are bulky removed in the first stage, using selective adsorbents, and a nitrogen and oxygen-depleted intermediate stream is yielded to the second stage. The second stage employs an adsorbent or adsorbents to selectively remove carbon dioxide and trace amounts of remaining nitrogen and oxygen, thus producing a purer methane stream that meets pipeline and natural gas specifications

A water harvesting device includes at least a first adsorption column including a first inlet, a first outlet, and a first interior region. A sorbent material is located within the first interior region of the first adsorption column. The sorbent material includes a metal organic framework (MOF) material including a plurality of metal ions or clusters of metal ions coordinated to one or more organic linkers, a plurality of nanofabrics comprising a hydrogel material, or a combination thereof.