An adsorption module and associated processes for conducting advanced separations processes such as sorption enhanced water-gas shift (SEWGS). The adsorption module contains at least one angled baffle to create at least two tapered adsorbent beds within the adsorption module. The taper is such that the adsorbent beds' cross-sections within the adsorption module decrease in the direction of feed flow, thereby taking advantage of increased product purity and process efficiency provided by tapered adsorption beds.

A (V)PSA unit for purifying a gas stream by adsorption is provided. The (V)PSA unit comprises, arranged successively in the direction of flow of the feed gas stream, a rotary-structured adsorbent wheel configured so as to drive the gas stream therethrough in an axial manner and allowing the feed gas to dry to a level corresponding to a dew point below 30 C., and an adsorber with a centripetal radial configuration, comprising a bed of particulate adsorbent.

Process and apparatuses for purifying a feed stream containing CO.sub.2 and predominantly hydrogen are provided. In an embodiment, the process includes passing the feed stream through a multilayer adsorbent bed comprising a first adsorbent section, a second adsorbent section downstream from the first adsorbent section and a third adsorbent section downstream from the second adsorbent section. The first adsorbent section comprises an activated carbon layer, the second adsorbent section comprises a layer of molecular sieve of the faujasite structure type with a Si/Al atomic ratio of from 1.5 to 8.0 and the third adsorbent section comprises a layer of molecular sieve of the faujasite structure type with a Si/Al atomic ratio of from 1.0 to 1.5. At least one of N.sub.2, CO.sub.2, CH.sub.4 and CO is adsorbed from the feed stream and a purified hydrogen product is recovered from the multilayer adsorbent bed.

A process for treating a petroleum fraction and for efficiently absorbing an organic halogen compound from a fluid mixture of the organic halogen compound and an inorganic halogen compound derived from crude oil. Also disclosed is an improvement in absorption performance of a halogen-compound-absorbing material, thereby reducing the frequency with which the absorbing material is exchanged. The absorbing agent includes attapulgite (palygorskite) having high absorption performance with respect to organic halogen compounds. Also disclosed is an absorption column in which the aforementioned absorbing agent and a halogen-compound-absorbing agent, that includes zinc oxide, are disposed in series, thereby making it possible to raise the treatment performance with respect to a fluid that contains, in high concentrations, the organic halogen compound in addition to the inorganic halogen compound.

Systems for generation of liquid water are provided. In embodiments, the systems comprise a thermal desiccant unit comprising a porous hygroscopic material located within a housing including a fluid inlet and a fluid outlet, a working fluid that accumulates heat and water vapor upon flowing from fluid inlet of the housing, through the porous hygroscopic material, and to the fluid outlet of the housing, a condenser comprising a fluid inlet and a fluid outlet for condensing water vapor from the working fluid; an enthalpy exchange unit operatively coupled between the thermal desiccant unit and the condenser, wherein the enthalpy exchange unit transfers enthalpy between the working fluid output from the thermal desiccant unit and the working fluid input to the thermal desiccant unit, and, wherein the enthalpy exchange unit transfers enthalpy between the working fluid output from the condenser and the working fluid input to the condenser.

Disclosed herein are new processes for adsorbing oxygen using adsorbent compositions comprising RHO zeolites kinetically selective for oxygen. The RHO zeolites can be used in pressure swing adsorption processes for separating oxygen from oxygen containing streams, such as for, but not limited to, purifying a crude argon feed stream or separating oxygen from an air feed stream.

An air suspension system includes an air suspension, a compressor, a dryer apparatus, and so forth. The dryer apparatus includes a dryer case, an inner cylinder, a first inlet port, a first outlet port, a first desiccant, an outer cylinder, a second inlet port, a second outlet port, a second other-end side filter, a second desiccant, and so forth. The first desiccant comprises a molecular sieve, for example, which exhibits high water adsorption performance at high temperature. On the other hand, the second desiccant comprises silica gel, for example, which exhibits high water adsorption performance at low temperature.

A process for removing halogen compounds, particularly chlorine compounds, from a process fluid, includes the steps of (i) passing a process fluid containing hydrogen halide over a first sorbent to remove hydrogen halide and generate a hydrogen halide depleted process fluid and then, (ii) passing the hydrogen halide depleted process fluid over a second different sorbent to remove organic halide compounds therefrom. A purification system suitable for removing hydrogen halide and organic halide compounds from process fluids is also described.

Disclosed herein are new processes for adsorbing oxygen using adsorbent compositions comprising RHO zeolites kinetically selective for oxygen. The RHO zeolites can be used in pressure swing adsorption processes for separating oxygen from oxygen containing streams, such as for, but not limited to, purifying a crude argon feed stream or separating oxygen from an air feed stream.

Methods and systems of collecting carbon dioxide are disclosed. In one example, a method includes removing water from atmospheric air with a condenser and a desiccant material to produce dry air, adsorbing carbon dioxide to a material from the dry air, releasing the adsorbed carbon dioxide to a vacuum chamber, and transitioning the released carbon dioxide from a gas to a solid in the vacuum chamber.