Systems including a moisture pump for removing moisture from an inside environment to an outside environment. The moisture pump includes a housing defining a chamber with a heater, a heat spreader, and a desiccant for selectively adsorbing water vapor in the heating chamber when the heater is off and desorbing water vapor into the heating chamber when the heater is on. A valve assembly is also maintained by the housing transitionable between an adsorption position and desorption position. The adsorption position allows water vapor to be selectively transmitted into the heating chamber from the inside environment. The desorption position allows water vapor to be transmitted from the heating chamber for transmission into the outside environment. The adsorption and desorption ports can have asymmetric adsorption and desorption areas.

The present invention describes the process of preparing ceramic materials for absorption of acidic gases, mainly carbon dioxide, in exhaust systems and/or present indoors. Ceramic materials are formed by a mixture of alkali carbonate with alkaline earth metal oxide/hydroxide associated with a binding component, but non-limiting. The alkali carbonate comprises sodium, potassium carbonate, or a mixture of both. The alkaline earth metal oxide/hydroxide may be formed from magnesium oxide or magnesium hydroxide as well as calcium oxide and/or calcium hydroxide.

The use of a palladium-doped zeolite for the adsorption of volatile organic compounds is described wherein the zeolite has a CHA framework type and is polymer-bound. Such zeolites have been found to have particular utility as packaging materials for the adsorption of volatile organic compounds, such as those originating from organic matter.

The present invention provides a porous coordination polymer, wherein the porous coordination polymer is formed of unit lattices; each of the unit lattices has a shape of a cube having eight vertexes and twelve sides; each of the vertexes of the unit lattices consists of a Zn.sub.4O cluster; each of the sides of the unit lattices consists of a .sup.OOCCCCOO.sup. group. At least a part of the unit lattices contains at least one hydrogen molecule only, or the inside of at least a part of the unit lattices is empty. The present invention provides a novel porous coordination polymer, especially, a porous coordination polymer suitable for separating hydrogen molecules from a gaseous mixture of the hydrogen molecules and impurity molecules (e.g., nitrogen molecules, oxygen molecules, or carbon dioxide molecules).

A volatile liquid vapor recovery system is used to recover vapors produced in the loading of shipping vehicles with volatile liquid product from a storage tank. The recovery system uses a primary vessel with an adsorption bed for adsorbing the volatile liquid vapors and venting clean air including oxygen to the atmosphere. The recovery system regenerates the adsorption bed by recovering the volatile liquid vapors from the adsorption bed and directly delivering said vapors to the storage tank. The system may be adapted to remove oxygen from the primary vessel prior to regeneration, such as by purging and venting the primary vessel with a purge gas or by providing a secondary vessel to receive oxygen and vapors from the primary vessel prior to regeneration of the first adsorption bed. Adsorbed volatile liquid vapor from the secondary vessel can be recycled to the primary vessel for conservation.

Disclosed herein a technique for producing a gas mixture for controlling an oxygen concentration in the interior of a container while reducing the overall weight of the apparatus. For this purpose, a gas mixture supply device is provided for a container refrigeration apparatus. The gas mixture supply device is provided with adsorption columns. If one of the first and second adsorption columns is supplied with air, the adsorption columns are pressurized, and nitrogen in the air is adsorbed onto an adsorbent. If air is sucked from the other of the first and second adsorption columns, the adsorption columns are depressurized, and nitrogen adsorbed onto the adsorbent is desorbed. A gas mixture including the nitrogen desorbed from the adsorbent is supplied to the interior of a container.

A method for recovering hydrogen which is capable of efficiently recovering high concentration hydrogen gas by adsorbing and removing hydrocarbon gas such as carbon dioxide from biomass pyrolysis gas under a relatively low pressure, and also capable of storing the recovered high concentration hydrogen gas, preferably, in a cartridge type container that can be used as is as a hydrogen storing container for an apparatus equipped with a fuel cell. The method includes a first purifying stare of purifying biomass pyrolysis gas and a second purifying stage of purifying the obtained purified gas under a pressure equal to or less than the pressure in the first purifying stage to recover gas that contains hydrogen, and further includes a hydrogen storing stage of feeding the gas containing hydrogen recovered in the second purifying stage into the container filled with a hydrogen storage alloy and storing high purity hydrogen.

Embodiments provide a method of storing a compound using a metal organic framework (MOF). The method includes contacting one or more MOFs with a fluid and sorbing one or more compounds, such as O2 and CH4. O2 and CH4 can be sorbed simultaneously or in series. The metal organic framework can be an M-soc-MOF, wherein M can include aluminum, iron, gallium, indium, vanadium, chromium, titanium, or scandium.

One or more embodiments relate to providing substrate for separating a first gas component from a gaseous mixture, said substrate comprising a benzimidazole-linked polymer. Also provided is a method for synthesizing a substrate for separating a first gas component from a gaseous mixture, the method comprising performing a free condensation reaction between an aryl-o-diamine and an aryl-aldehyde to yield a benzimidazole-linked polymer. Other embodiments related to providing a CO.sub.2 separation membrane comprising benzimidazole-linked polymer residing within a matrix.

The invention discloses a method for adsorbing ethylene gas using amorphous granular starch. The method firstly prepares amorphous granular starch, wherein starch slurry is prepared from starch with a ethanol aqueous solution and NaOH solution is added dropwise so as to react at 30 to 35 C. for 20 to 50 minutes; Then the slurry is centrifuged, neutralized with an ethanol hydrochloride solution, washed and dried to obtain the amorphous granular starch. The amorphous granular starch is placed in a high-pressure reactor and ethylene gas is introduced after the reactor is vacuumized to react at 0.8 to 1.5 Mpa and 20 to 30 C. for 15 to 25 h so that starch powder product adsorbing with ethylene is obtained. The test result shows that the content of ethylene in the obtained product can reach more than 30%. The method is simple, highly efficient and cheap for the adsorption process of ethylene, and the product is expected to be widely applied in the field of fruit and vegetable modified atmosphere preservation.