A carbon composite material, including a plurality of spaced graphene sheets, each respective sheet having opposed generally planar surfaces, and a plurality of functionalized carbonaceous particles. At least some functionalized carbonaceous particles are disposed between any two adjacent graphene sheets, and each respective at least some functionalized carbonaceous particle is attached to both respective any two adjacent graphene sheets. Each respective graphene sheet comprises at least one layer of graphene and at least portions of respective any two adjacent graphene sheets are oriented substantially parallel with one another.

A fluid storage and dispensing apparatus including a fluid storage and dispensing vessel having a rectangular parallelepiped shape, and an integrated gas cabinet assembly including such fluid storage and dispensing apparatus and/or a point-of-use ventilation gas scrubber in the vented gas cabinet. By the use of physical adsorbent and chemical sorbent media, the gas cabinet can be enhanced in safety of operation, e.g., where the process gas supplied from the gas cabinet is of a toxic or otherwise hazardous character.

A process for reducing coke formation during hydrocarbon upgrading reactions using a double-wall reactor comprising the steps of feeding a heated feed water to a shell-side volume of the double-wall reactor to produce a heat transfer stream, the double-wall reactor comprising an exterior wall and an interior wall, a reaction section volume, a heating element configured to heat the heat transfer stream, wherein heat is transferred from the heat transfer stream to the reaction section volume, feeding the hot water return exiting the shell-side volume through a filter; mixing the filtered water stream with a heated hydrocarbon feedstock; feeding the mixed stream to the reaction section volume in a configuration counter-current to the heat transfer stream; reacting the reaction flow stream at a reaction temperature, wherein the heat transferred to the reaction section volume is operable to maintain the reaction temperature above the critical temperature of water.

A carbon adsorbent adapted for adsorptive storage and subsequent desorptive release of a decomposition-susceptible gas is described. Such carbon adsorbent comprises porosity in which mesopore volume is less than 0.25 cm.sup.3/gm of carbon adsorbent, in which the porosity comprises at least 80% by volume micropores, and at least 65% by volume of the micropores have pore diameter in a range of from 0.3 to 0.72 nm. The carbon adsorbent has a nitrogen adsorption BET surface area greater than 800 m.sup.2/g of carbon adsorbent, measured at 77 K, and a bulk density that is greater than 0.55 g/cc of carbon adsorbent. The carbon adsorbent can be utilized in gas storage and dispensing packages of varying type, to provide a safe and reliable source of decomposition-susceptible gas, e.g., acetylene for applications such as gas welding/cutting applications, atomic absorption spectroscopy applications, chemical synthesis and microelectronic products manufacturing.

A methane microporous carbon adsorbent comprising a thermally-treated CVD carbon having a shape in the form of a negative replica of a crystalline zeolite has a BET specific surface area, a micropore volume, a micropore to mesopore volume ratio, a stored methane value and a methane delivered value and a sequential carbon synthesis method for forming the methane microporous carbon adsorbent. Introducing an organic precursor gas for a chemical vapor deposition (CVD) period to a crystalline zeolite that is maintained at a CVD temperature forms the carbon-zeolite composite. Introducing a non-reactive gas for a thermal treatment period to the carbon-zeolite composite maintained at a thermal treatment temperature forms the thermally-treated carbon-zeolite composite. Introducing an aqueous strong mineral acid mixture to the thermally-treated carbon-zeolite composite forms the methane microporous carbon adsorbent.

A sealed container (1) includes at least an outer container (2) and a gas adsorption device (4) being provided in a sealed space (3) within the outer container (2) and being capable of adsorbing a gas. The gas adsorption device (4) includes at least a copper ion-exchanged ZSM-5 type zeolite and a primary material having a lower gas barrier property than the outer container (2) does.

Disclosed is a metal-organic framework composite including a host metal-organic framework, and nano metal-organic frameworks embedded In the host metal-organic framework. The host metal-organic framework and the nana metal-organic frameworks include different metals and organic ligands. The metal-organic framework composite has a structure in which the nano metal-organic frameworks are embedded in the host metal-organic framework. Due to this structure, defects are formed at the interfaces between the host metal-organic framework and the nano metal-organic frameworks, enabling the application of the metal-organic framework composite to gas storages with greatly improved gas storage efficiency. The metal-organic framework composite can be used as a gas adsorbent with very high efficiency due to its very large specific surface area. In addition, the metal-organic framework composite has high storage capacities for hydrogen, carbon dioxide, and methane and is thus very attractive from the viewpoint of industrial application. The metals and the ligands can be combined to make the metal-organic framework composite highly resistant to pressure, temperature, and water. Therefore, the metal-organic framework composite can also be applied to filters that can directly capture carbon dioxide from factory chimneys or can adsorb pollutants in water. Also disclosed are a method for producing the metal-organic framework composite and a gas storage using the metal-organic framework composite.

The invention relates to a tubular filter that absorbs ethylene or other gases for refrigerated transport containers, formed by a cylindrical tube of plastic mesh (2) with hermetic caps (3) at both ends, which contains granules that absorb ethylene or other gases, the mesh (2) having a structural configuration formed by an inner crown (20) having a circular filament (201), and an outer crown (21) having a wing-shaped filament (211), the base thereof being wider than the distal end thereof, thereby facilitating the entry of air flow into the tube. It further comprises a support accessory (4) fixed in the container for which the filter (1) is intended, and it has an aerodynamic shape that helps to increase air flow through the filter (1) and liquid collection means.

Methods of butane delivery, methods for reducing VOC emissions resulting from such delivery, and methods for debutanizing nitrogen gas used to expel butane from butane storage tanks.

A filter device for a gas container removes foreign substances mixed with gas in the gas container, and is integrally mounted with the gas container so as to ensure a maximum capacity of the gas container while providing a larger gas filter compared to existing external gas filters.