Provided herein is a process for separating alkane isomers from a hydrocarbon mixture in an integrated refining unit, comprising: passing the hydrocarbon mixture through a normal alkane-selective membrane in a single stage to produce a normal alkane-enriched stream and a membrane reject stream; and feeding the normal alkane-enriched stream to a steam cracker to produce olefins; wherein the hydrocarbon mixture comprises n-paraffins and at least two of isoparaffins, cycloparaffins, and aromatics.

A nanobiocatalytic membrane for a filtration system is provided which includes a filtration membrane and a plurality of nanobiocatalyst nanoparticles associated with the membrane, each of the nanobiocatalyst nanoparticles including a core, a coating at least partially surrounding the core, and a plurality of nanobiocatalysts coupled to the coating. Each of the plurality of nanobiocatalysts includes an antibacterial nanoparticle comprising bismuth, and a quorum quenching agent coupled to the antibacterial nanoparticle. A nanobiocatalyst nanoparticle for use with a water purification system is also provided. A method of forming a nanobiocatalytic membrane for a filtration system and a method of using a nanobiocatalytic membrane in a filtration system are also provided.

The invention relates to a metallic membrane for nitrogen separation, the method of making the membrane and methods of using the membrane. The invention also relates to a metallic membrane for disassociation of nitrogen and subsequent reaction with hydrogen to produce ammonia at moderate conditions compared to a conventional Haber-Bosch process.

Apparatus and methods are provided for extracting compounds from raw materials. One such apparatus may include an extraction column where it is a one column, one pass design capable of withstanding high temperatures and pressure. Additionally, the extraction column may also be capable of containing a self-perpetuating energy cycle used to achieve the required solubilization and mass transfer temperatures necessary for optimal extraction. The apparatus may also include a first opening and a second opening to control the flow of incoming solvent and filter extraneous sediment trapped within the fully extracted effluent. Additionally, the apparatus may be configured to create a self-perpetuating and self-sustaining energy cycle by manipulating the pressure and temperature generated within the apparatus. While the generated temperatures may help achieve a dynamic and efficient extraction process, a trailing cool layer of solvent is also present to effectively preserve the heat sensitive compounds extracted from the raw materials.

A dual function composite oxygen transport membrane having a layered structure of mixed conducting oxygen transport materials on a first side of a porous substrate and a reforming catalyst layer on an opposing second side of the porous substrate. The layered structure of the mixed conducting oxygen transport materials contains an intermediate porous layer of mixed conducting oxygen transport materials formed on the porous substrate with a dense impervious layer of mixed conducting oxygen transport materials over the intermediate porous layer, and an optional surface exchange layer of mixed conducting oxygen transport materials over the dense impervious layer. The layered structure and the reforming catalyst layer are formed in separate steps.

A nanobiocatalytic membrane for a filtration system is provided which includes a filtration membrane and a plurality of nanobiocatalyst nanoparticles associated with the membrane, each of the nanobiocatalyst nanoparticles including a core, a coating at least partially surrounding the core, and a plurality of nanobiocatalysts coupled to the coating. Each of the plurality of nanobiocatalysts includes an antibacterial nanoparticle comprising bismuth, and a quorum quenching agent coupled to the antibacterial nanoparticle. A nanobiocatalyst nanoparticle for use with a water purification system is also provided. A method of forming a nanobiocatalytic membrane for a filtration system and a method of using a nanobiocatalytic membrane in a filtration system are also provided.

A method and apparatus for extracting compounds from raw materials with an extraction column is provided. The control and manipulation of pressure exerted and contained within the extraction vessel or column may be vital in obtaining a certain flavor profile or intensity of the effluent extracted from the raw materials. As such, the method may include directing a flow of pressurized solvent into a base of the extraction column and utilizing the flow of pressurized solvent to create a pressure gradient applied to the raw materials. The method may further include compressing the raw materials with hydraulic compression. As the raw materials become further compressed, frictional heating may result allowing most, if not all, of the volatile aromatic heat sensitive compounds and constituencies to be extracted depending on the pressure strength applied to the raw materials. As such, manipulating the pressure gradients for each extraction process allows for distinct and specific flavor profiles to be extracted from the raw materials.

An air filter medium includes a fluororesin porous membrane and a supporting member stacked on top of each other. The air filter medium has a permeability ratio (permeability after disinfection treatment/permeability before disinfection treatment) of 5.0 or less, the permeability ratio being a ratio of permeabilities of the air filter media before and after the disinfection treatment of the fluororesin porous membrane as determined using NaCl particles having a particle size of 0.1 ?m, and a pressure loss ratio (pressure loss after disinfection treatment/pressure loss before disinfection treatment) of 0.83 or more and 1.15 or less, the pressure loss ratio being a ratio of pressure losses of the air filter media before and after the disinfection treatment of the fluororesin porous membrane.

A dual function composite oxygen transport membrane having a layered structure of mixed conducting oxygen transport materials on a first side of a porous substrate and a reforming catalyst layer on an opposing second side of the porous substrate. The layered structure of the mixed conducting oxygen transport materials contains an intermediate porous layer of mixed conducting oxygen transport materials formed on the porous substrate with a dense impervious layer of mixed conducting oxygen transport materials over the intermediate porous layer, and an optional surface exchange layer of mixed conducting oxygen transport materials over the dense impervious layer. The layered structure and the reforming catalyst layer are formed in separate steps.

Embodiments of the present disclosure include a matrix of raw materials that form an interlocking network of varied particle grind sizes that allows the particles to nest and interlock with one another when packed into an extraction vessel, so that most, but not all of the interstitial spacing within the matrix of raw materials is closed. The varied particle sizes may be selected by pre-determined weight ranges and size classifications so that the particle grind sizes achieve the desired consistency uniformity. This may allow the network of particles to act as its own best filtering agent during the extraction process. Moreover, the nesting and interlocking network of the particles within the matrix of raw materials may allow the particles to be effectively packed within the extraction column, thus allowing for an efficient and high quality extraction to be performed consistently each and every time.