A manufacturing method of a meltblown fiber membrane includes the following step. A meltblown film is made to pass between a first pressing roller and a second pressing roller, such that a calendering process is performed on the meltblown film, in which the meltblown film includes a plurality of meltblown fibers, each of the meltblown fibers includes a high-fluidity polyester and a modified polyester, a melt index of the high-fluidity polyester under a temperature of 230? C. ranges from 350 g/10 min to 550 g/10 min, a melt index of the modified polyester under a temperature of 230? C. ranges from 200 g/10 min to 400 g/10 min, and a roller temperature of each of the first pressing roller and the second pressing roller ranges from 100? C. to 155? C.

An electrochemical system utilizes an anion conducting layer disposed between an anode and a cathode for transporting a working fluid. The working fluid may include carbon dioxide that is dissolved in water and is partially converted to carbonic acid that is equilibrium with bicarbonate anion. An electrical potential across the anode and cathode creates a pH gradient that drives the bicarbonate anion across the anion conducting layer to the cathode, wherein it is reformed into carbon dioxide. Therefore, carbon dioxide is pumped across the anion conducting layer.

The present disclosure discloses a device for biaxially-oriented stretching polytetrafluoroethylene hollow fiber membranes and the method thereof. The device may include a lubricant removing oven and a tube blank heating oven mounted at the outlet end of the push-compression mold, a core extension extending from the core into the lubricant removing oven and the tube blank heating oven, and a speed regulating guide wheel mounted at the outlet of the tube blank heating oven. A tube blank is extruded from a push-compression machine, inserted on the core extension for removal of lubricant in the lubricant removing oven, heated in the tube blank heating oven, transversely stretched by means of the bulked core, and then wound onto the speed regulating guide wheel for longitudinal stretching. Both transverse and longitudinal stretching can be realized for polytetrafluoroethylene tube blanks, overcoming disadvantages of traditional processing devices that can merely perform longitudinal stretching.

The present invention is directed to a method for treating a surface of a filled microporous membrane. The microporous membrane includes a polyolefinic matrix, inorganic filler distributed throughout the matrix, and a network of interconnecting pores throughout the membrane. The method includes sequentially (1) contacting the membrane with a first treatment composition comprising an epoxy-silane which is in intimate contact with the inorganic filler; (2) subjecting the membrane of (1) to conditions sufficient to effect a first reaction between the inorganic filler and the silane groups of the epoxy-silane compound; (3) contacting the membrane of (2) with a second treatment composition comprising polyalkylene polyamine, an amine functional polysaccharide and/or an amino silane; and (4) subjecting the membrane of (3) to conditions sufficient to effect a second reaction. Treated membranes also are provided.

The invention provides mixed matrix membranes (MMMs) for olefin/paraffin separation and methodes of making and using the same. The MMMs comprise a continuous polymer matrix with metal doped zeolite nano-particles. A separation technology based upon the composite membranes is effective for propylene and other olefin separation from olefin/paraffin mixtures, and the separation is more energy-efficient than the conventional cryogenic technique.

The invention provides mixed matrix membranes (MMMs) for olefin/paraffin separation and methodes of making and using the same. The MMMs comprise a continuous polymer matrix with metal doped zeolite nano-particles. A separation technology based upon the composite membranes is effective for propylene and other olefin separation from olefin/paraffin mixtures, and the separation is more energy-efficient than the conventional cryogenic technique.

Zeolite membrane sheets for separation of mixtures containing water are provided, as well as methods for making the same. Thin, but robust, zeolite membrane sheets having an inter-grown zeolite crystal film directly on a thin, less than 200 micron thick, porous support sheet free of any surface pores with a size above 10 microns. The zeolite membrane film thickness is less than about 10 microns above the support surface and less than about 5 microns below the support surface. Methods of preparing the membrane are disclosed which include coating of the support sheet surface with a seed coating solution containing the parent zeolite crystals with mean particle sizes from about 0.5 to 2.0 microns at loading of 0.05-0.5 mg/cm2 and subsequent growth of the seeded sheet in a growth reactor loaded with a growth solution over a temperature range of about 45? C. to about 120? C.

Provided is a zeolite membrane manufactured by: subjecting a porous body to heat treatment at 400? C. or more in the presence of oxygen as pretreatment, before adhering zeolite seed crystals to a surface of the porous body; storing the porous body under an environment of humidity of 30% or more for 12 hours or more after the heat treatment; and subsequently adhering the zeolite seed crystals to the porous body. The zeolite membrane having oxygen eight-membered rings, which is manufactured by subjecting the porous body to the heat treatment, provides a value that is obtained by dividing a permeance of CF.sub.4 by a permeance of CO.sub.2 to be 0.015 or less, and has fewer defects.

A method of synthesizing cellulose nano-crystals from date palm seeds includes providing washed and dried date palm seeds, milling the date palm seeds to a fine powder, adding a bleaching agent to the fine powder to separate cellulose from the powder, placing the cellulose in a container with an acid solution to form a mixture, heating the mixture, isolating cellulose crystals from the mixture, and reducing the particle size of the cellulose crystals in the solution to provide cellulose nano-crystals. The particle size can be reduced by adding the cellulose crystals to a quantity of water to form a solution, and ultrasonicating the solution at about 90% amplitude for about 45 minutes to form cellulose nano-crystals. The cellulose nano-crystals can have a size ranging from about 5 nm to about 100 nm.

Disclosed is a polyvinylidene fluoride/ultra-high molecular weight polyethylene blend microporous membrane and preparation method thereof, which belongs to the field of microporous membrane. The blend microporous membrane has good hydrophobicity, mechanical properties and permeability. The preparation method includes: preparing a suspension by polyvinylidene fluoride, ultra-high molecular weight polyethylene, antioxidant and diluent; then feeding the obtained suspension into a twin-screw extruder, and the cast membrane gel extruded from the outlet is directly injected into a metal mold for injection molding; the mold temperature and the outlet temperature of the extruder are the same, and the cavity surface of the mold has micro-prism array structure; then cooling the mold in aqueous medium to obtain a nascent gel membrane; drying the obtained nascent gel membrane in a freeze dryer after removal of the diluents by extraction. The prepared membrane can be used in the membrane separation technology such as membrane distillation.