A submerged propylene hydration micro-interface strengthening reaction system and a method are proposed. The system includes a reactor, a first micro-interface generator and a second micro-interface generator. Through the micro-interface generators, the propylene is broken to form micron-scale bubbles, which are mixed with reactants and deionized water to form a gas-liquid emulsion, so as to increase a phase boundary area between gas and liquid phases, and achieve a strengthening mass transfer effect under a lower preset operating condition. The micro-scale bubbles can be fully mixed with the deionized water to from a gas-liquid emulsion. By fully mixing gas and liquid phases, it can ensure that the deionized water in the system is in full contact with propylene, and they are fully in contact with the catalyst, which effectively improves the efficiency of preparing isopropanol.

A load-following reactor system and associated facilities for improved control of a reactor under varying loads. The load-following reactor may be a tube-cooled reactor for methanol synthesis. A reactant may be controlled by at least one valve element such that a portion of the reactant is fed to the reactor through the reactor tubes, and a portion of the reactant is fed to the reactor after being heated in a heat exchanger. The heated portion of the reactant may be fed to the reactor after the tubes. The valve element may be controlled based on a temperature of the reactor and/or a flowrate of reactant feed to adapt the temperature of the reactor to the changing reactant flowrate.

Described herein is a system (100) for storage and releasing of carbon dioxide comprising at least one solids reactor (1), at least one compressor (7, 8) for compressing the carbon dioxide-containing gas or fluid, respectively, which is introduced through the inlet (3) of the solids reactor, wherein the compressor (7, 8) is constructed in such a way that it adiabatically expands the gas or fluid, respectively, depleted of carbon dioxide that is discharged from the reactor by means of the outlet (2) of the solids reactor, and at least one countercurrent recuperator (6), which is constructed for the heat exchange of the compressed exhaust gas or fluid, respectively, that contains carbon dioxide and the gas or fluid, respectively, depleted of carbon dioxide.

Described is furthermore a solids reactor for storage and releasing carbon dioxide, comprising a gas-tight or fluid-tight, respectively, housing, which has an interior, at least one inlet for feeding in fluids and at least one outlet for discharging of gases or fluids, respectively, wherein the interior of the housing is filled with at least two different solids, wherein one solid is provided for storing thermal energy and the other solid is provided for regenerative storage and releasing of carbon dioxide.

Furthermore described is a method for storage and releasing of carbon dioxide.

A method for producing plasmonic nanomaterials that are catalytically or photocatalytically active by fabricating plasmonic nanostructures on substrates using electrodeposition into a nano-template structure and forming a plurality of nanorods in an array, wherein the nanorods are made from materials chosen from the group consisting of materials that are plasmonic and/or catalytic, and materials that are catalytically activated by depositing pure elemental metals, alloys, or alternating layers of different metals or alloys, and producing catalytic plasmonic nanomaterials. Catalytic plasmonic nanomaterials made from the above method. An optical reactor device that utilizes catalytic nanomaterials for photocatalytic synthesis of methanol or ammonia. A method of photocatalytic synthesis of methanol and ammonia by using catalytic plasmonic nanomaterial to convert CO.sub.2 and H.sub.2 to methanol and N.sub.2 and H.sub.2 to ammonia using optical power. A hybrid plasma-plasmonic reactor for the utilization of CO.sub.2 and CH.sub.4 to produce methanol, ethylene, and acetic acid.

Hydrogen generation assemblies, hydrogen purification devices, and their components, and methods of manufacturing those assemblies, devices, and components are disclosed. In some embodiments, the devices may include an insulation base having insulating material and at least one passage that extends through the insulating material. In some embodiments, the at least one passage may be in fluid communication with a combustion region.

In a urea synthesis process, temperature distribution in a submerged condenser is reduced. The process includes: synthesizing urea from NH.sub.3 and CO.sub.2 to generate a urea synthesis solution; by heating the solution, decomposing ammonium carbamate and separating a gaseous mixture containing NH.sub.3 and CO.sub.2 from the solution to obtain a solution higher in urea concentration than the solution obtained in the synthesizing; with use of a submerged condenser including a shell and tube heat exchange structure including a U-tube, absorbing and condensing at least a part of the gaseous mixture in an absorption medium on a shell side, and generating steam on a tube side with use of heat generated during the condensation; and recycling at least a part of liquid, obtained from the shell side, to the synthesizing, wherein water is supplied to the tube side of the condenser at a mass flow rate that is three times or more of the steam generation rate.

A process and apparatus for converting an alkane to an olefin. In one embodiment, the process involves oxidative coupling of an alkane, e.g., methane, with an oxidant, such as air, to produce an olefin having twice the number of carbon atoms as the alkane, e.g., ethylene. In another embodiment, the process involves oxidative dehydrogenation of an alkane, e.g., ethane, with an oxidant to form an olefin having the same number of carbon atoms as the alkane, e.g., ethylene. The process involves passing a flow of the oxidant from a first flow passage through a porous medium; diffusing a flow of the alkane from a second flow passage into the porous medium; and contacting the reactant alkane and the oxidant in the presence of a catalyst within the porous medium to produce the olefin.

The present application relates to an apparatus and process for producing dimethyl carbonate, in particular a system (apparatus or process) for DMC synthesis without the need of using a dehydrating agent. More particularly, the feed mixture for the process can be selected from the following options: a) carbon monoxide, methanol and flue gas from the process, b) synthesis gas without CO.sub.2 and flue gas from the process, c) synthesis gas with CO.sub.2 and added synthesis gas from purified flue gas from the process. The process uses a catalyst cluster comprising a specific combination of different groups of heterogeneous catalysts wherein each group has a different function. Also the invention relates to an apparatus comprising a specific combination of heterogeneous catalysts for applying different routes to produce dimethyl carbonate from each feed mixture option, on continuous basis.

Systems are provided that permit temperature control of a catalyst bed for conversion of alcohols to fuel hydrocarbons by modulating the water content of the alcohol feed stream provided to the catalyst bed. In some embodiments a secondary catalyst bed is provided for the conversion of light hydrocarbons found in the initial hydrocarbon product to fuel hydrocarbons that are liquid at ambient temperature and pressure.

A methanol production system of the present disclosure includes: a reformer including a reaction furnace configured to reform methane in a raw material gas to produce a reformed gas containing CO and H.sub.2; a reduced-gas generator configured to reduce CO.sub.2 to produce a reduced gas containing CO; and a methanol-containing gas generator configured to produce a methanol-containing gas which contains methanol from a reformed gas produced in the reaction furnace and a reduced gas produced in the reduced-gas generator.