Patent classifications
B01J8/04
Method, tube bundle reactor and reactor system for carrying out catalytic gas phase reactions
A method for carrying out catalytic gas phase reactions including providing a tube bundle reactor which has a bundle of reaction tubes that are filled with a catalyst charge and are cooled by a heat transfer medium, conveying a reaction gas through the catalyst charge, the reaction gas flowing into each reaction tube divided into two part flows introduced in the axial direction of the reaction tube at different points in the catalyst charge the catalyst charge has at least two catalyst layers of different activity, wherein the activity of the first catalyst layer, in the flow direction of the reaction gas, is lower than the activity of the at least one other catalyst layer and in step a first part flow is introduced into the first catalyst layer and each further part flow is introduced past the first catalyst layer into the at least one further catalyst layer.
GAS PRODUCTION APPARATUS, GAS PRODUCTION SYSTEM, AND GAS PRODUCTION METHOD
A gas production apparatus and a gas production system capable of continuously and stably manufacturing a produced gas containing carbon monoxide from a raw material gas containing carbon dioxide are provided. A gas production apparatus 1 is an apparatus that manufactures a produced gas containing carbon monoxide by bringing a raw material gas containing carbon dioxide into contact with a reducing agent containing a metal oxide that reduces carbon dioxide. The gas production apparatus includes a reaction section 4 that includes a plurality of reactors 4a and 4b and a reducing agent arranged in the reactors 4a and 4b, and that is capable of switching between the raw material gas and the reducing gas to be supplied to each of the reactors 4a and 4b. When a predetermined amount of raw material gas is supplied to the reactors 4a and 4b, or when the conversion efficiency of carbon dioxide to carbon monoxide falls below a predetermined value, the gas production apparatus is configured to switch between the raw material gas and the reducing gas to be supplied to each reactor 4a and 4b.
GAS PRODUCTION APPARATUS, GAS PRODUCTION SYSTEM, AND GAS PRODUCTION METHOD
A gas production apparatus and a gas production system capable of continuously and stably manufacturing a produced gas containing carbon monoxide from a raw material gas containing carbon dioxide are provided. A gas production apparatus 1 is an apparatus that manufactures a produced gas containing carbon monoxide by bringing a raw material gas containing carbon dioxide into contact with a reducing agent containing a metal oxide that reduces carbon dioxide. The gas production apparatus includes a reaction section 4 that includes a plurality of reactors 4a and 4b and a reducing agent arranged in the reactors 4a and 4b, and that is capable of switching between the raw material gas and the reducing gas to be supplied to each of the reactors 4a and 4b. When a predetermined amount of raw material gas is supplied to the reactors 4a and 4b, or when the conversion efficiency of carbon dioxide to carbon monoxide falls below a predetermined value, the gas production apparatus is configured to switch between the raw material gas and the reducing gas to be supplied to each reactor 4a and 4b.
REACTOR FOR THE CATALYTIC TREATMENT OF A GAS STREAM
A reactor may have a catalyst bed for the catalytic treatment of a gas stream, with the catalyst bed extending substantially over a cross section of the reactor. Gas to be treated may axially fly through the catalyst bed. A carrier structure for the catalyst bed that is at least partly floatingly mounted in the reactor may include a sieve element and, radially outwardly, carrier elements fixedly joined to the reactor wall below the sieve element. The sieve element provides a resting surface for the catalyst bed. The sieve element terminates, radially outwardly, at a distance from the reactor wall. The carrier structure also includes support elements for the sieve element that are floatingly mounted in the reactor. An improved floating mounting is thus provided where not only the sieve element itself but also further parts of the carrier structure are mounted to prevent stresses due to thermal expansion.
FIXED BED REACTOR SYSTEM FOR OXIDATIVE DEHYDROGENATION OF ETHANE
A fixed bed reactor system for the oxidative dehydrogenation of ethane, comprising a catalyst bed wherein the catalyst capacity profile increases along the length of catalyst bed from the upstream end to the downstream end. The catalyst bed may include one or more sections, across one or more fixed bed reactors, that are identified by a change in catalyst capacity. Catalyst capacity, or the ability to convert ethane into ethylene, may be altered by changing the dilution ratio, void fraction, and or the 35% conversion temperature. A method for loading a fixed bed reactor with an increasing catalyst capacity is also described.
AN OCM REACTOR SYSTEM CONTAINING A MULTI COMPONENT CATALYST SYSTEM
The invention relates to a reactor system for oxidative coupling of methane (OCM), comprising: reactor system for oxidative coupling of methane (OCM), comprising: (a) an inlet configured to receive a reactant mixture; (b) a reaction chamber having an upstream end and a downstream end such that the reaction chamber extends from the upstream end to the downstream end, and the reaction chamber comprises a catalyst bed having a catalyst composition having at least two catalyst components: (i) a low selectivity catalyst component; and (ii) a high selectivity catalyst component; and (c) an outlet configured to recover a C.sub.2+ hydrocarbon product mixture from the reactor system; wherein the reactor system is configured such that the reactant mixture substantially contacts the high selectivity catalyst component prior to contacting the low selectivity catalyst component. The invention further describes a process for the production of C.sub.2+ hydrocarbon product mixture using the present reactor system.
METHOD AND APPARATUS FOR SELECTIVE ALCOHOL UPGRADING
Methods for utilizing carbon dioxide to produce multi-carbon products are disclosed. The systems and methods of the present disclosure involve: reducing CO.sub.2 to produce a first product mixture comprising an alcohol product mixture comprising one or more alcohols and a paraffin product mixture comprising one or more paraffins; dehydrating the alcohol product mixture to form an olefin product mixture comprising one or more olefins; oligomerizing the olefin product mixture to form a higher olefin product mixture comprising unsaturated paraffins and optionally aromatics; and reducing the higher olefin product mixture to form a higher hydrocarbon product mixture comprising unsaturated paraffins and optionally aromatics. Catalyst materials and reaction conditions for individual steps are disclosed to optimize yield for ethanol or jet fuel range hydrocarbons.
LIGHT ALKANES TO TRANSPORTATION FUEL
The present disclosure relates generally to processes and systems for producing liquid transportation fuels by converting a feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. Isopentane and smaller hydrocarbons are separated to form a first fraction while n-pentane and larger components of the feed stock form a second fraction. Each fraction is then catalytically-activated in a separate reaction zone with a separate catalyst, where the conditions maintained in each zone maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first fraction is activated at a lower temperature than the second fraction. Certain embodiments additionally comprise mixing at least a portion of the two effluents and contacting with either an oligomerization catalyst or alkylation catalyst to provide enhanced yields of upgraded hydrocarbon products that are suitable for use as a blend component of liquid transportation fuels or other value-added chemical products.
METHOD AND APPARATUS FOR QUANTITATIVELY ANALYZING A GASEOUS PROCESS STREAM
The present invention relates to method and an apparatus for quantitatively analyzing a gaseous process stream, in particular a stream from a process for producing ethylene carbonate and/or ethylene glycol, in particular where such stream comprises gaseous organic iodides.
Multi-stage device and process for production of a low sulfur heavy marine fuel oil
A multi-stage process for the production of an ISO 8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a Reaction System composed of one or more reactor vessels selected from a group reactor wherein said one or more reactor vessels contains one or more reaction sections configured to promote the transformation of the Feedstock Heavy Marine Fuel Oil to the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a Environmental Contaminate level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed that can utilize a modular reactor vessel.