Patent classifications
B01J8/085
Light Treatment of Chromium Catalysts and Related Catalyst Preparation Systems and Polymerization Processes
Catalyst preparation systems and methods for preparing reduced chromium catalysts are disclosed, and can comprise irradiating a supported chromium catalyst containing hexavalent chromium with a light beam having a wavelength within the UV-visible light spectrum. Such reduced chromium catalysts have improved catalytic activity compared to chromium catalysts reduced by other means. The use of the reduced chromium catalyst in polymerization reactor systems and olefin polymerization processes also is disclosed, resulting in polymers with a higher melt index.
Moving bed reactor for processing three phase flows
A moving bed reactor is provided that can allow facilitate performing a reaction involving a three-phase flow under co-axial flow conditions for the solid and liquid portions of the three phase flow, while the gas portion of the three-phase flow is exposed to the solids under radial flow conditions. Methods for using such a moving bed reactor to perform a reaction, such as upgrading of a feed to distillate products, are also provided.
LIQUID-SOLID AXIAL MOVING BED REACTION AND REGENERATION DEVICE, AND SOLID ACID ALKYLATION METHOD
A liquid-solid axial moving bed reaction and regeneration apparatus and a solid acid alkylation process by using the liquid-solid axial moving bed reaction and regeneration apparatus. the liquid-solid axial moving bed reaction and regeneration apparatus comprise:
An axial moving bed reactor (1), a spent catalyst receiver (5), a catalyst regenerator (4) and a regenerated catalyst receiver (6) that are successively connected, wherein, a catalyst outlet of the regenerated catalyst receiver (6) is communicated with a catalyst inlet of the axial moving bed reactor (1);
Wherein, the axial moving bed reactor (1) is provided with at least two catalyst beds (3) arranged up and down, the axial moving bed reactor (1) is provided with a feed inlet (2) above each catalyst bed (3);
A catalyst delivery pipe (16) is arranged between two adjacent catalyst beds (3) so that the catalyst can move from top to bottom in the axial moving bed reactor (1);
A separation component (10) is provided between two adjacent catalyst beds (3), the inside space of the separation component (10) is communicated with the catalyst delivery pipe (16), the separation component (10) is for separating the stream after the reaction in the upstream catalyst bed from the catalyst, the catalyst obtained by the separation with the separation component (10) moves down through the catalyst delivery pipe (16).
LIQUID-SOLID RADIAL MOVING BED REACTION DEVICE AND SOLID ACID ALKYLATION METHOD
A liquid-solid radial moving bed reaction apparatus and a solid acid alkylation process by using the liquid-solid radial moving bed reaction apparatus, the liquid-solid radial moving bed reaction apparatus comprises:
A radial moving bed reactor, a spent catalyst receiver, a catalyst regenerator, and a regenerated catalyst receiver that are successively connected, wherein the catalyst discharging outlet of the regenerated catalyst receiver is communicated with the catalyst inlet of the radial moving bed reactor; a reaction stream distribution zone, a catalyst bed, and a stream-after-the-reaction collection zone are arranged in the radial moving bed reactor from the inside to the outside or from the outside to the inside, the reaction stream distribution zone is communicated with the reaction stream feeding pipeline; the stream-after-the-reaction collection zone is communicated with the stream-after-the-reaction withdrawing pipe;
A component-based mixer is arranged on the reaction stream feeding pipeline; the component-based mixer consists of an upper recycled stream pipe, a lower reaction stream feeding pipe, and a fresh feedstock feeding pipe extending into the reaction stream feeding pipeline, a nozzle of the feeding pipe is arranged at the outlet of the fresh feedstock feeding pipe, a filler and/or a mixing fin is arranged in the reaction stream feeding pipeline, wherein the component-based mixer is located out of the radial moving bed reactor.
Continuous slurry-bed tank reactor and method of using same
A continuous slurry-bed tank reactor, comprising a tank reactor body, an agitator, and tubular separation membranes. A method of using the continuous slurry-bed tank reactor comprising adding a catalyst, feeding reactants, stopping feeding the reactants, starting a heating system, changing directions of the reactants flowing through the tubular separation membranes.
Light treatment of chromium catalysts and related catalyst preparation systems and polymerization processes
Catalyst preparation systems and methods for preparing reduced chromium catalysts are disclosed, and can comprise irradiating a supported chromium catalyst containing hexavalent chromium with a light beam having a wavelength within the UV-visible light spectrum. Such reduced chromium catalysts have improved catalytic activity compared to chromium catalysts reduced by other means. The use of the reduced chromium catalyst in polymerization reactor systems and olefin polymerization processes also is disclosed, resulting in polymers with a higher melt index.
Method for manufacturing nonylcyclohexanol
A method for manufacturing nonylcyclohexanol is provided. The method includes steps as follows: adding a liquid phase reactant into a reactor, and the liquid phase reactant includes a molten nonylphenol and a catalyst; introducing a gas phase reactant to maintain a pressure of the gas phase reactant to be from 36.5 bar to 70 bar, and the gas phase reactant consists of hydrogen; rotating a hollow stirring shaft of the reactor at a temperature of from 100° C. to 130° C. so that the gas phase reactant is transported through a channel formed in the hollow stirring shaft into the liquid phase reactant for carrying out a reaction; obtaining a product that contains nonylcyclohexanol. A conversion rate of the nonylcyclohexanol is higher than or equal to 99.0%.
METHOD AND APPARATUS FOR PREPARING COMPOSITE
A method and apparatus for preparing a composite, in which the angle between the apparatus base and the apparatus body is adjusted by the elevator device, the solid raw material is loaded into the reactor by the solid feeding device, the main reaction gas, the auxiliary gas and the carrier gas are introduced from the front gas intake unit into the main reaction zone at a preset ratio, followed by the active material deposited on solid particles, the post-processing reaction gas is introduced from the middle gas intake unit to the post-processing reaction zone to form a functional layer on the active material, the prepared composite powder is separated and collected from the gas-solid mixture in the collection device. The exhaust gas is released from the exhaust manifold into an exhaust gas treatment system after minority powder filtered by the filter.
Method For Manufacturing Ammonium Sulphate And Calcium Carbonate From Phosphogypsum
The invention relates to a method for manufacturing ammonium sulphate and calcium carbonate from phosphogypsum, characterised in that it comprises the following steps: —dispersing phosphogypsum in water to form a phosphogypsum liquid suspension, —sparging gaseous carbon dioxide and gaseous ammonia in the phosphogypsum liquid suspension to precipitate calcium carbonate, —filtering the phosphogypsum liquid suspension to produce a filtrate comprising ammonium sulphate, and a solid residue comprising the calcium carbonate precipitate, —evaporating the filtrate to produce ammonium sulphate and drying the solid residue to produce calcium carbonate.
High severity fluidized catalytic cracking systems and processes for producing olefins from petroleum feeds
Systems and processes are disclosed for producing petrochemical products, such as ethylene, propene and other olefins from crude oil in high severity fluid catalytic cracking (HSFCC) units. Processes include separating a crude oil into a light fraction and a heavy fraction, cracking the light fraction and heavy fraction in separation separate cracking reaction zones, and regenerating the cracking catalysts in a two-zone having a first regeneration zone for the first catalyst (heavy fraction) and a second regeneration zone for the second catalyst (light fraction) separate from the first regeneration zone. Flue gas from the first catalyst regeneration zone is passed to the second regeneration zone to provide additional heat to raise the temperature of the second catalyst of the light fraction side. The disclosed systems and processes enable different catalysts and operating conditions to be utilized for the light fraction and the heavy fraction of a crude oil feed.