The specification discloses a highly macroporous catalyst for hydroprocessing and hydroconversion of heavy hydrocarbon feedstocks. The high macroporosity catalyst incudes an inorganic oxide, molybdenum, and nickel components. It has a pore structure such that at least 18% of its total pore volume is in pores of a diameter greater than 5,000 angstroms and at least 25% of its total pore volume is in pores of a diameter greater than 1,000 angstroms. Preferably, the pore structure is bimodal. The catalyst is made by co-mulling the catalytic components with a high molecular weight polyacrylamide followed by forming the co-mulled mixture into a particle or an extrudate. The particle or extrudate is dried and calcined under controlled calcination temperature conditions to yield a calcined particle or extrudate of the high macroporosity catalyst composition.

A gas assisted liquid spray nozzle assembly having a nozzle body that defines a mixing zone, a liquid inlet communicating with the mixing zone from an end, and a pressurized gas inlet communicating with the mixing chamber from an upstream side. The liquid inlet includes a liquid injector extending into the nozzle body having a liquid inlet extension passage and a plurality of discharge orifices adjacent a closed downstream end which define an impingement surface for directing liquid into the mixing zone in transverse relation to a central axis of the mixing zone. The nozzle body and liquid injector define a plurality of concentrating gas discharge passages at respective locations of the injector liquid discharge orifices for causing individual pressurized gas to directly interact with transversely directed liquid into the mixing zone for enhanced atomization and ultimate discharge from a downstream spray tip.

A gas assisted liquid spray nozzle assembly having a nozzle body that defines a mixing zone, a liquid inlet communicating with the mixing zone from a side thereof, and a pressurized gas inlet communicating with the mixing chamber from an upstream end. The liquid inlet includes a liquid inlet extension and diffuser post extending transversely into the mixing zone having a liquid extension passageway and a closed downstream end that defines an internal impingement surface disposed on a central axis of the mixing zone against which liquid impinges and is transversely directed into the mixing zone for atomization by pressurized gas directed centrally through the mixing zone from the gas inlet. The spray nozzle assembly includes a barrel extension zone downstream of said mixing zone with a spray tip for directing the atomized liquid in a predetermined spray pattern.

A process and reactor for arsenic fixation in which a first gas stream comprises oxygen and an iron-containing particulate material. The oxygen and particulate material may be fed to reactor through respective first and second inlets. A second gas stream containing one or more volatile arsenic compounds is fed through a third inlet and mixed with the first gas stream and the particulate material to produce a combined gas stream containing the volatile arsenic compounds and the particulate material. The arsenic compounds are reacted with iron in the particulate material as the combined gas stream flows through the reactor to produce solid iron arsenates which are then recovered. The portion of the reactor including the first, second and third inlets is vertically oriented, and the reactor may include a venturi arrangement having a throat at which the second inlet is located.

A fluidizing apparatus for the treatment of particulate material. The fluidizing apparatus includes a fluidization unit which has a longitudinal axis and a perforated distributor plate which divides the fluidization unit into a distributor chamber and a fluidization chamber arranged above the distributor chamber. The distributor chamber includes a web arranged in the region of a material outlet surface and extending at least partially in the circumferential direction. The distributor plate is arranged movably relative to the fluidization unit.

Methods and systems for producing pyrolysis products from a mixed plastics stream are described herein. The method may include conducting pyrolysis of a plastic feedstock to produce a stream of plastic pyrolysis oil; feeding a catalytic cracking feed stream and a catalyst from a catalyst regenerator into a fluidized bed reactor, where the catalytic cracking feed stream comprises the plastic pyrolysis oil; cracking the catalytic cracking feed stream in the fluidized bed reactor to produce a product stream and a spent catalyst; and transporting the spent catalyst to the catalyst regenerator and regenerating the catalyst in the catalyst regenerator. The product stream comprises olefins having a carbon number of C.sub.2-C.sub.4 and distillate fuel.

The present invention is directed generally to dry cell culture media or feeds in pellet formats which can be reconstituted into liquid media for culturing cells in vitro. Each pellet composition may comprise the same or a different composition; for example, different vitamins, amino acids, buffers, trace salts, pH, iron chelators, etc. The invention also relates to methods of making dry cell culture media by altering ratios of different pellet compositions, or, methods of making modular dry cell culture media, or customizing media formulations for growing a cell type using pellets. According to the invention, media pellets may be easier to handle either before reconstitution, during shipping and handling; and/or during reconstitution. Media pellets may be used in any container like bags including sterile, single use bags for preparing media formulations. The invention also relates to kits and culture systems using media pellets.

A process and reactor for arsenic fixation in which a first gas stream comprises oxygen and an iron-containing particulate material. The oxygen and particulate material may be fed to reactor through respective first and second inlets. A second gas stream containing one or more volatile arsenic compounds is fed through a third inlet and mixed with the first gas stream and the particulate material to produce a combined gas stream containing the volatile arsenic compounds and the particulate material. The arsenic compounds are reacted with iron in the particulate material as the combined gas stream flows through the reactor to produce solid iron arsenates which are then recovered. The portion of the reactor including the first, second and third inlets is vertically oriented, and the reactor may include a venturi arrangement having a throat at which the second inlet is located.

Methods and systems for producing pyrolysis products from a mixed plastics stream are described herein. The method may include conducting pyrolysis of a plastic feedstock to produce a stream of plastic pyrolysis oil; feeding a catalytic cracking feed stream and a catalyst from a catalyst regenerator into a fluidized bed reactor, where the catalytic cracking feed stream comprises the plastic pyrolysis oil; cracking the catalytic cracking feed stream in the fluidized bed reactor to produce a product stream and a spent catalyst; and transporting the spent catalyst to the catalyst regenerator and regenerating the catalyst in the catalyst regenerator. The product stream comprises olefins having a carbon number of C.sub.2-C.sub.4 and distillate fuel.

The disclosure provides a flushing process for removing polymer fouling from a reactor including a gas distributor proximal to the bottom thereof and an internal condenser proximal to the top thereof, the method including, for a first flushing time period, injecting a flushing solvent into the reactor and withdrawing the flushing solvent from a reactor outlet proximal to the internal condenser to induce an upward movement of flushing solvent, the withdrawn flushing solvent containing a first polymer content. After the first flushing time period is complete, for a second flushing time period, the process includes injecting a flushing solvent into the reactor and withdrawing the flushing solvent from a reactor outlet proximal to the gas distributor to induce a downward movement of flushing solvent, the withdrawn flushing solvent containing a second polymer content.