A process for separating heavy metals from a phosphoric starting material includes, in a step (i), heating the starting material to a temperature between 700 and 1,100° C. in a first reactor and withdrawing combustion gas. In a step (ii), the heated starting material at the temperature between 700 and 1,100° C. is transferred to a second reactor, chlorides of alkaline and alkaline earth metals are added and process gas is withdrawn.

A process for separating heavy metals from a phosphoric starting material includes, in a step (i), heating the starting material to a temperature between 700 and 1,100° C. in a first reactor and withdrawing combustion gas. In a step (ii), the heated starting material at the temperature between 700 and 1,100° C. is transferred to a second reactor, chlorides of alkaline and alkaline earth metals are added and process gas is withdrawn.

A classifying fluid bed granulation unit includes a perforated bed floor; a fluid bed section; a solid feed inlet or internal crushing device; a fluidization air inlet; a liquid solution or melt feed inlet and nozzles; an air outlet; and a product outlet; wherein the fluid bed section comprises at least one particle classification element comprising one or more vertically inclined channels having top and bottom end feed openings, and wherein the one or more vertically inclined channels have upper and lower side slots. In operation of the above fluid bed granulation unit, each channel of the element is separating particles into large particle and small particle fractions and transporting the large particle fraction upwards and the small particle fraction downwards in each channel, and the large particle and small particle fractions are transported out of the upper and lower side slots, respectively.

A classifying fluid bed granulation unit includes a perforated bed floor; a fluid bed section; a solid feed inlet or internal crushing device; a fluidization air inlet; a liquid solution or melt feed inlet and nozzles; an air outlet; and a product outlet; wherein the fluid bed section comprises at least one particle classification element comprising one or more vertically inclined channels having top and bottom end feed openings, and wherein the one or more vertically inclined channels have upper and lower side slots. In operation of the above fluid bed granulation unit, each channel of the element is separating particles into large particle and small particle fractions and transporting the large particle fraction upwards and the small particle fraction downwards in each channel, and the large particle and small particle fractions are transported out of the upper and lower side slots, respectively.

The invention concerns a fluid distribution device (1) comprising: at least one inlet tube (2) comprising openings (7) and having a first and a second end (3, 4); a cap (5) comprising a principal body (6) with a lenticular shape and with a circular section elongated by a skirt (8) extending in the direction of the second end (4) towards the first end (3) of the inlet tube (2), said cap (5) having an outer surface and an inner surface, the cap being integral with the second end (4) of the tube via the inner surface and the principal body (6) being provided with a plurality of holes (10);
and in which the cap (5) comprises at least one deflection means (14) disposed on its outer surface and configured to direct or maintain the gas towards or at the periphery of said cap (5).

The invention concerns a fluid distribution device (1) comprising: at least one inlet tube (2) comprising openings (7) and having a first and a second end (3, 4); a cap (5) comprising a principal body (6) with a lenticular shape and with a circular section elongated by a skirt (8) extending in the direction of the second end (4) towards the first end (3) of the inlet tube (2), said cap (5) having an outer surface and an inner surface, the cap being integral with the second end (4) of the tube via the inner surface and the principal body (6) being provided with a plurality of holes (10);
and in which the cap (5) comprises at least one deflection means (14) disposed on its outer surface and configured to direct or maintain the gas towards or at the periphery of said cap (5).

Processes of catalytically pyrolyzing solid hydrocarbonaceous materials in a downflow fluid bed reactor and regenerating the catalyst in an upflow fluidized bed reactor are described. Systems and compositions useful in the catalytic pyrolysis of plastics are also described.

Processes of catalytically pyrolyzing solid hydrocarbonaceous materials in a downflow fluid bed reactor and regenerating the catalyst in an upflow fluidized bed reactor are described. Systems and compositions useful in the catalytic pyrolysis of plastics are also described.

The invention relates to a process for transitioning from a first continuous polymerization reaction in a gas phase reactor conducted in the presence of a first catalyst to a second polymerization reaction conducted in the presence of a second catalyst in the gas phase reactor wherein the first and second catalysts are incompatible, the process comprising: (a) discontinuing the introduction of the first catalyst into the gas phase reactor; (b) introducing an effective amount of cyclohexylamine into the reactor to at least partially deactivate the first catalyst; (c) introducing an organometallic compound into the reactor and reacting the organometallic compound with cyclohexylamine; (d) introducing a gas composition into the reactor for the second polymerization reaction and (e) introducing the second catalyst into the reactor.

The invention relates to a process for transitioning from a first continuous polymerization reaction in a gas phase reactor conducted in the presence of a first catalyst to a second polymerization reaction conducted in the presence of a second catalyst in the gas phase reactor wherein the first and second catalysts are incompatible, the process comprising: (a) discontinuing the introduction of the first catalyst into the gas phase reactor; (b) introducing an effective amount of cyclohexylamine into the reactor to at least partially deactivate the first catalyst; (c) introducing an organometallic compound into the reactor and reacting the organometallic compound with cyclohexylamine; (d) introducing a gas composition into the reactor for the second polymerization reaction and (e) introducing the second catalyst into the reactor.