The present invention relates to a new process for the preparation of melamine-formaldehyde free microcapsules. Microcapsules obtainable by said process are also an object of the invention. Perfuming compositions and consumer products comprising said capsules, in particular perfumed consumer products in the form of home care or personal care products, are also part of the invention.

The present invention relates to methods and systems for isolation of species in semi-permeable capsules and processing of encapsulated species through series of steps and/or reactions. To produce capsules, first aqueous two-phase system (ATPS) droplets are generated using microfluidics system and then the hydrogel shell layer is hardened by inducing polymerization. As exemplified in this invention to achieve concentric ATPS droplet formation density-matched PEGDA and Dextran polymer solutions can be used. Once a capsule is formed, its composition can be changed by adding new reagents or replacing out old ones (e.g. by resuspending capsules in desired aqueous solution). The hydrogel shell of semi-permeable capsules can be dissolved at selected step during multi-step procedures in order to release the encapsulated species. The present invention exemplifies the isolation of individual cells within capsules and using the encapsulated cells for genotypic and phenotypic analysis. Finally, the present invention also exemplifies the use of capsules in multi-step procedures to perform complex biological reactions.

A method comprises providing an aqueous solution having an alkaline pH and providing an oil including at least one silsesquioxane compound. The oil is added to the aqueous solution. The oil forms a plurality of silsesquioxane oil droplets suspended in the aqueous solution such that an internal osmotic pressure is generated inside the oil droplets via a chemical reaction. The aqueous solution is allowed to osmotically diffuse into the plurality of oil droplets for a predetermined time. The silsesquioxane oil droplets are polymerized by cross-linking the at least one silsesquioxane compound included in the silsesquioxane oil droplets to form a plurality of solidified microcapsules containing the aqueous solution therewithin.

A method comprises providing an aqueous solution having an alkaline pH and providing an oil including at least one silsesquioxane compound. The oil is added to the aqueous solution. The oil forms a plurality of silsesquioxane oil droplets suspended in the aqueous solution such that an internal osmotic pressure is generated inside the oil droplets via a chemical reaction. The aqueous solution is allowed to osmotically diffuse into the plurality of oil droplets for a predetermined time. The silsesquioxane oil droplets are polymerized by cross-linking the at least one silsesquioxane compound included in the silsesquioxane oil droplets to form a plurality of solidified microcapsules containing the aqueous solution therewithin.

The invention relates to a security pigment of core-shell particles, comprising a core based on a thermoplastic material, a shell based on a condensation polymer, and an organic or metalorganic feature substance present in dissolved or finely distributed form in the core, wherein the mass fraction of the shell amounts to more than 25%, preferably 50%, particularly more than 100%, in relation to the mass of the core. The invention further relates to a method for producing the core-shell particles and to value documents having the core-shell particles.

The present invention relates to a process for producing a plurality of hollow inorganic nanoparticles, which process comprises: (a) contacting a first monomer and a second monomer in a solvent to produce a composition comprising the solvent and a plurality of polymer nanoparticles; (b) adding an inorganic compound precursor to the composition comprising the solvent and the plurality of polymer nanoparticles to produce a composition comprising the solvent and a plurality of inorganic compound-coated polymer nanoparticles; (c) adding an additional amount of the first and second monomers to the composition comprising the solvent and the plurality of inorganic compound-coated polymer nanoparticles to produce a composition comprising the solvent and a plurality of composite nanoparticles; and (d) heating the plurality of composite nanoparticles to produce the plurality of hollow inorganic nanoparticles, wherein in step (a) the first monomer and the second monomer are contacted in the solvent at a temperature of at least 30 C. The present invention also relates to plurality of hollow inorganic nanoparticles and uses thereof.

Purified polyurea capsules that encapsulate active materials for use in personal care, fine fragrance, or deodorant products are provided as are methods for producing the same.

Purified polyurea capsules that encapsulate active materials for use in personal care, fine fragrance, or deodorant products are provided as are methods for producing the same.

Polyurea capsules that encapsulate active materials in polymeric walls resulting from the polymerization of an aliphatic polyisocyanate and a cross-linking agent such as a diamine, amphoteric amine or guanidine amine/salt are provided as are consumer products containing said polyurea capsules and for methods for producing such capsules.

The invention relates to a method for producing microcapsules, comprising the following steps: (a) providing a first aqueous preparation containing at least one prepolymer; (b) providing a second non-aqueous preparation containing the active substance to be encapsulated; (c) mixing the aqueous and the non-aqueous phases in the presence of at least one emulsifier and/or stabilizer in order to form an emulsion; (d) polymerizing the at least one prepolymer contained in the emulsion from step (c) in order to obtain a dispersion of microcapsules that enclose the active substance; (e) hardening and cross-linking the microcapsules obtained in step (d); and optionally (f) removing the microcapsules from the dispersion and drying the microcapsules, the method being characterized in that the emulsion is formed in the presence of at least one 1,2-diol in step (c).