A method for the management of phosphogypsum consists in that a reactor (2) is charged with apatite and/or phosphorite phosphogypsum and with an aqueous or ammoniacal solution of ammonium carbonate and/or bicarbonate from a pre-reactor (1), at 1: (0.1-4) ratio of phosphogypsum to the aqueous or ammoniacal solution of ammonium carbonate and/or bicarbonate, the entire contents are stirred at 10 C. to 200 C. for at least 2 minutes, CO.sub.2 being released in the course of the process is directed to the pre-reactor (1), and the post-reaction mixture is directed to a filter (3) to obtain an aqueous ammonium sulphate solution, whereas the precipitate from the filter (3) is heat-treated, followed by dissolving it in nitric acid in a reactor (5), and the resultant suspension is filtered through a filter (6) to obtain an aqueous calcium nitrate solution, and CO.sub.2 being released in the reactor (5) is recirculated to the pre-reactor (1) wherein CO.sub.2 is reacted with ammonia in an aqueous solution to obtain the aqueous or ammoniacal solution of carbonate and/or bicarbonate which is directed to the reactor (2), with the process for obtaining the aqueous or ammoniacal solution of ammonium carbonate and/or bicarbonate being conducted until the pH 7-12 of the solution is reached.

A cascade reactor scheme with acid and hydrocarbon flowing in reverse directions. The systems and processes for alkylation of olefins herein may include providing a first olefin to a first alkylation zone, and a second olefin to a second alkylation zone. Isoparaffin may be provided to the first alkylation zone. The isoparaffin and first olefin may be contacted with a partially spent sulfuric acid in the first alkylation zone to form a spent acid phase and a first hydrocarbon phase including alkylate and unreacted isoparaffin. The first hydrocarbon phase and second olefin may be contacted with a sulfuric acid feed in the second alkylation zone to form a second hydrocarbon phase, also including alkylate and unreacted isoparaffin, and the partially spent sulfuric acid that is fed to the first alkylation zone. Further, the second hydrocarbon phase may be separated, recovering an isoparaffin fraction and an alkylate product fraction.

A skid-mounted depressurizing system includes a main process module, a mechanical control system, a thermodynamic balance system and an intelligent control system. The main process module includes multiple main process pipelines, each of the multiple main process pipelines is provided with a pressure reducing valve set. During depressurization, process medium enters at least one of the multiple main process pipelines, the mechanical control system outputs a torque according to the control instruction of the intelligent control system to control each valve of the multiple main process pipelines to perform an action switch and an opening degree adjustment, the thermodynamic balance system is configured to provide the medium of different properties to the multiple main process pipelines according to the control instruction of the intelligent control system to control temperature, pressure, cleanliness degree and/or sealing degree of the main process module.

A supercritical water oxidation-flame piloted vortex reactor has a hydrothermal flame produced within the interior of the reactor fed by a fuel including a waste water stream, and has a subcritical wash stream, including water below its critical point, that creates an upward helical flow in the material within the reactor. The hydrothermal flame and upward helical flow produce within the reactor a supercritical core region, a subcritical outer region around the core region, and a transcritical intermediate region between them. The upward helical flow serves to transfer precipitated ionic compounds out of the supercritical core region, through the transcritical intermediate region, and into the subcritical outer region where they re-dissolve. A processed flow, including purified water, is removed from an upper portion of the supercritical core region by an aspirator.

Reactive diluent fluid (22) is introduced into a stream of synthesis gas (or syngas) produced in a heat-generating unit such as a partial oxidation (POX) reactor (12) to cool the syngas and form a mixture of cooled syngas and reactive diluent fluid. Carbon dioxide and/or carbon components and/or hydrogen in the mixture of cooled syngas and reactive diluent fluid is reacted (26) with at least a portion of the reactive diluent fluid in the mixture to produce carbon monoxide-enriched and/or solid carbon depleted syngas which is fed into a secondary reformer unit (30) such as an enhanced heat transfer reformer in a heat exchange reformer process. An advantage of the invention is that problems with the mechanical integrity of the secondary unit arising from the high temperature of the syngas from the heat-generating unit are avoided.

An object of the present invention is to provide a flow type reaction device which is capable of maintaining reaction efficiency and productivity which are sufficient for practical use for a long time, and reducing the size and cost of the reaction device, and the present invention provides a flow type reaction device (1) for continuously reacting two or more kinds of raw materials, including a mixing section (10) which is configured to mix two or more kinds of the raw materials, and a reaction section (20) which is provided on a secondary side with respect to the mixing section (10), and configured to obtain a product by reacting two or more kinds of the raw materials, the mixing section (10) includes a mixing device (13) which is configured to mix two or more kinds of the raw materials, and two or more supply pipes (L11, L12) which are configured to supply each of two or more kinds of the raw materials to the mixing device (13), the supply pipes (L11, L12) are respectively connected to the mixing device (13), and at least one of the supply pipes (L11) has, in the vicinity of a connection portion of the supply pipe (L11) with the mixing device (13), a suppression mechanism which is configured to suppress movement of a fluid from the mixing device (13) to the supply pipe (L11).

Disclosed are a graphene material production device and a system including the device. The device includes: a first reaction component, a second reaction component and a negative pressure generating component. The first reaction component includes a first reaction chamber and a first material outlet arranged at a bottom of the first reaction chamber. The second reaction component includes a second reaction chamber and a second material inlet. A connecting passage between the first material outlet and the second material inlet is provided with a valve. A suction hole of the negative pressure generating component is provided inside the second reaction chamber. The use of the device in the process of producing a graphene material by a redox method can overcome the problem that the viscous material is difficult to transfer, thereby reducing the production difficulty and effectively improving the production efficiency of graphene materials.

Provided are a fouling inhibitor and a method of oligomerizing an olefin using the same. More particularly, in the method of oligomerizing an olefin, it is possible to minimize a total amount of polymers produced during a reaction and basically inhibit fouling of the polymers produced during the reaction onto an inner wall of a reactor by injecting a predetermined fouling inhibitor.

Reaction device which makes possible the oligomerization of olefins to give linear olefins and preferably linear -olefins, comprising a gas/liquid reactor and a reactor of plug-flow type. The reaction device is also employed in an oligomerization process.

A cascade reactor scheme with acid and hydrocarbon flowing in reverse directions. The systems and processes for alkylation of olefins herein may include providing a first olefin to a first alkylation zone, and a second olefin to a second alkylation zone. Isoparaffin may be provided to the first alkylation zone. The isoparaffin and first olefin may be contacted with a partially spent sulfuric acid in the first alkylation zone to form a spent acid phase and a first hydrocarbon phase including alkylate and unreacted isoparaffin. The first hydrocarbon phase and second olefin may be contacted with a sulfuric acid feed in the second alkylation zone to form a second hydrocarbon phase, also including alkylate and unreacted isoparaffin, and the partially spent sulfuric acid that is fed to the first alkylation zone. Further, the second hydrocarbon phase may be separated, recovering an isoparaffin fraction and an alkylate product fraction.