The invention relates to an esterification unit (150) and esterification process for producing crude methyl methacrylate (MMA) from methacrylamide (MAM), which enable particularly to improve the yield, meaning that the organics spent acids are low; and at the same time, providing crude MMA with rather good quality, meaning that MMA concentration in crude MMA is rather high and preferably from 50 wt % to 80 wt %. According to the invention, the esterification unit comprises esterification reactors (1, . . . , 5 (or 6) set up in a serial way so that there is a counter current flow between gaseous phase and liquid phase, the liquid phase flowing from first reactor (1) of the series to last reactor (5 (or 6)), and the gaseous phase flowing from reactor to first reactor (1).

Hydrogen production systems and methods of producing the same are provided. In an exemplary embodiment, a hydrogen production system comprises a reformer reactor that comprises a reformer reactor wall. A plurality of reformer tubes are interconnected to define a reformer lattice that has a reformer inner flow path and a reformer outer flow path. The plurality of reformer tubes are within the reformer reactor and connected to the reformer reactor wall at a plurality of discrete locations. The reformer lattice defines a combustor side that is one of the reformer inner or outer flow paths, and a reformer side that is the other of the reformer inner or outer flow paths. A reformer catalyst is positioned within the reformer side.

An end surface of each first side wall, an end surface of each first middle wall, and an end surface of each first end wall are joined to an adjacent second structure by diffusion bonding, an end surface of each second side wall, an end surface of each second middle wall, and an end surface of each second end wall are joined to an adjacent first structure or a lid structure by diffusion bonding, a thickness of each first side wall is greater than or equal to a thickness of each first middle wall, and a thickness of each second side wall is greater than or equal to a thickness of each second middle wall.

A chemical reactor (e.g. reformer reactor) system includes a manifold (126) for management of a flow of gaseous reaction medium thereto. Manifold (126) includes manifold housing (128) defining manifold chamber (129) and having at least one additional component selected from: a gas distributor (127); a heater; and a cavity having a seal within or adjacent to it.

In an example, a method of butadiene sequestration includes receiving an input stream that includes butadiene. The method includes directing the input stream to a first sulfur dioxide charged zeolite bed for butadiene sequestration via a first chemical reaction of butadiene and sulfur dioxide to form sulfolene.

Hydrogen production systems and methods of producing the same are provided. In an exemplary embodiment, a hydrogen production system comprises a reformer reactor that comprises a reformer reactor wall. A plurality of reformer tubes are interconnected to define a reformer lattice that has a reformer inner flow path and a reformer outer flow path. The plurality of reformer tubes are within the reformer reactor and connected to the reformer reactor wall at a plurality of discrete locations. The reformer lattice defines a combustor side that is one of the reformer inner or outer flow paths, and a reformer side that is the other of the reformer inner or outer flow paths. A reformer catalyst is positioned within the reformer side.

The invention relates to a process for the production of urea ammonium nitrate, a system and a method of modifying a plant. The process comprises treating ammonia-containing off-gas resulting from the production of ammonium nitrate (AN off-gas) with acidic scrubbing liquid in a finishing treatment section having a gas inlet in fluid communication with a gas outlet of a finishing section of a urea production unit, wherein the finishing section is adapted to solidify urea liquid, and wherein said finishing treatment section is adapted to subject ammonia-containing off-gas of the finishing section to treatment with an acidic scrubbing liquid.

Processes and system for producing biofuels and coproducts are described herein. The processes include pretreating a feedstock comprising fatty acid glycerides and free fatty acids to remove contaminants, contacting the feedstock with alcohols and a solid acidic catalyst to produce a biofuel comprising fatty acid alkyl esters, and purifying the biofuel and coproducts from the resulting reaction mixture.

A reactor module includes a pre-reactor and a membrane reactor disposed downstream of the pre-reactor. The membrane reactor includes a separation membrane. In the pre-reactor, an intermediate gas is generated from a source gas containing hydrogen and carbon oxide. The intermediate gas contains a liquid fuel, water vapor, and residual source gas. In the membrane reactor, the liquid fuel and water vapor are generated from the residual source gas. The separation membrane allows the water vapor contained in the intermediate gas and a product generated from the residual source gas to pass therethrough.

In accordance with the present invention, there is provided a process for producing hydrogen and graphitic carbon from a hydrocarbon gas comprising: contacting at a temperature between 600? C. and 1000? C. the catalyst with the hydrocarbon gas to catalytically convert at least a portion of the hydrocarbon gas to hydrogen and graphitic carbon, wherein the catalyst is a low grade iron oxide.