A system and method for discharging a transfer slurry from a first polymerization reactor through a transfer line to a second polymerization reactor, the transfer slurry including at least diluent and a first polyethylene. A product slurry is discharged from the second polymerization reactor, the product slurry including at least diluent, the first polyethylene, and a second polyethylene. The velocity, pressure drop, or pressure loss due to friction in the transfer line is determined, and a process variable adjusted in response to the velocity, pressure drop, or pressure loss not satisfying a specified value.

In a method for the hydrolysis of liquid, organic substrates (1), the substrate to be hydrolysed is introduced into a circulation loop for heating, where an equal amount of hydrolysed substrate (1) is displaced from the circulation loop (6, 7, 8, 9). An appropriate system can have a circulation loop, a feed device, a circulation pump for generating a circulation flow in the circulation loop, and a heater for heating and reheating the circulation flow.

The invention provides a process to form a first composition comprising a first ethylene/-olefin interpolymer and a second ethylene/-olefin interpolymer, said process comprising polymerizing a first mixture comprising ethylene, an -olefin, and optionally a polyene, in a stirred tank reactor to form a first ethylene/-olefin interpolymer, and transferring at least some of the first ethylene/-olefin interpolymer to a loop reactor, and polymerizing, therein, a second mixture comprising ethylene, an alpha-olefin, and optionally a polyene, in the presence of the first ethylene/-olefin interpolymer, to form the first composition comprising the first ethylene/-olefin interpolymer and the second ethylene/-olefin interpolymer. The invention also provides a polymerization reactor configuration comprising at least the following: a stirred tank reactor followed by a loop reactor.

An on-line gas chromatography system for a fixed-bed continuous flow reactor and a method for on-line gas analysis of a catalytic reaction using the gas chromatography system. A reactor flow loop, a gas chromatogram, and a hydrostatic regulator are present in the gas chromatography system, wherein the reactor flow loop contains a fixed-bed reactor, a purge gas source, a feed gas source, and a by-pass line for reaction calibration.

Bromine containing compounds, such as calcium bromide, sodium bromide and the like, are prepared in high purity and more quickly with less waste by using a process with two bromination stages and often a third step wherein the crude product mixture can be adjusted to meet specific product requirements. In the first bromination stage, the majority, but not all, of a substrate is brominated using a reductive bromination reaction, the remaining unreacted substrate is converted to product in the second stage through another a reductive bromination reaction, although the specific reagents may be different, wherein the addition of bromine and a reducing agent are carefully monitored.

Polymerization reactor systems providing integrated liquid-solid sampling systems are disclosed. Methods for operating such polymerization reactor systems and for measuring a property of the liquid portion of liquid-solid mixture are described.

A method of continuous hydrothermal carbonization of sludge containing organic matter involves a step of hydrothermal reaction carried out in a reactor, and at least one cooling step in which the sludge having undergone the hydrothermal reaction step is cooled. The hydrothermal reaction step includes: a step of injection of sludge in which the sludge is injected into the reactor by a first inlet; a step of injection of steam in which steam is injected into the reactor by a second inlet, the second inlet being distinct from the first inlet; a step of circulation, in which a mixture consisting of the sludge and the steam injected into the reactor is placed in circulation within the reactor; a step of continuous extraction of at least a portion of the mixture contained in the reactor by a sludge outlet. Also disclosed is a device for carrying out such a method.

Polymerization reactor systems providing integrated liquid-solid sampling systems are disclosed. Methods for operating such polymerization reactor systems and for measuring a property of the liquid portion of liquid-solid mixture are described.

Process for the polymerization of olefins in a polymerization reactor system including (i) a gas phase reactor having a gas outlet and one or more withdrawal lines for withdrawal of a polymer-containing stream, (ii) a recycle loop for recycling gas exiting the reactor through the gas outlet back to the reactor, (iii) a polymer separation system for separating reactants from the polymer product in the withdrawn polymer-containing stream, and (iv) a recycle system for recycling reactants removed from the reactor in the withdrawn polymer-containing stream back to the reactor. A scavenger is introduced directly into one or more of the recycle loop, the polymer separation system and the recycle system.

Bromine containing compounds, such as calcium bromide, sodium bromide and the like, are prepared in high purity and more quickly with less waste by using a process with two bromination stages and often a third step wherein the crude product mixture can be adjusted to meet specific product requirements. In the first bromination stage, the majority, but not all, of a substrate is brominated using a reductive bromination reaction, the remaining unreacted substrate is converted to product in the second stage through another a reductive bromination reaction, although the specific reagents may be different, wherein the addition of bromine and a reducing agent are carefully monitored.