B01J21/063

Hydrotreating catalyst with a titanium containing carrier and sulfur containing organic additive

Generally, it is disclosed a catalyst for use in a hydrotreating hydrocarbon feedstocks and the method of making such catalyst. It is generically provided that the catalyst comprises at least one Group VIB metal component, at least one Group VIII metal component, about (1) to (about (30) wt % C, and preferably about (1) to about (20) wt % C, and more preferably about (5) to about 15 wt % C of one or more sulfur containing organic additive and a titanium-containing carrier component, wherein the amount of the titanium component is in the range of about (3) to (about (60) wt %, expressed as an oxide (Ti0.sub.2) and based on the total weight of the catalyst. The titanium-containing carrier is formed by co-extruding or precipitating a titanium source with a Al203 precursor to form a porous support material comprising Al.sub.20.sub.3 or by impregnating a titanium source onto a porous support material comprising Al.sub.20.sub.3.

P-type TiO2/n-type WO3 heterojunction catalyst, its preparation and use in photochemical synthesis of fuels

Provided is a p-type TiO.sub.2/n-type WO.sub.3 heterojunction catalyst and a preparation method and use thereof. The catalyst comprises p-type TiO.sub.2 and n-type WO.sub.3 supported on a surface of the p-type TiO.sub.2.

Transition metal carbides for catalytic methane activation

A MXene support for a noble metal that forms a catalyst having active sites comprising single metal-layer nanostructures. The catalyst is stable under conditions for methane conversion to higher hydrocarbons and provides reduced coke formation. The results show a supported metal catalyst using the MXene where Pt atoms form one or more layers of atoms on the surface of the Mo.sub.2TiC.sub.2T.sub.x support after it is reduced at 750° C. The catalyst shows high selectivity for C.sub.2-hydrocarbons with reduced coke formation, which can cost effectively convert methane into other valuable products.

PGM catalyst coupled with a non-PGM catalyst with HC oxidation capability
11517854 · 2022-12-06 · ·

The present invention relates to a diesel oxidation catalyst comprising a substrate and a wash-coat comprising a first layer and a second layer, wherein the substrate has a substrate length, a front end and a rear end, the washcoat comprising the first layer comprising a first metal oxide and comprising a platinum group metal supported on a metal oxide support material; the second layer comprising a second metal oxide and comprising one or more of an oxidic compound of vanadium, an oxidic compound of tungsten and a zeolitic material comprising one or more of Fe and Cu; wherein the first layer is at least partially disposed directly on the substrate, or is at least partially disposed directly on an intermediate layer which is disposed directly on the substrate over the entire length of the substrate, on x % of the length of the substrate from the front end of the substrate, and wherein the second layer is at least partially disposed directly on the substrate, or is at least partially disposed directly on the intermediate layer which is disposed directly on the substrate over the entire length of the substrate, on y % of the length of the substrate from the rear end of the substrate, wherein x is in the range of from 25 to 75 and y is in the range of from 25 to 75 and wherein x+y is in the range of from 95 to 105, wherein the intermediate layer comprises alumina.

Process for producing a Fischer-Tropsch synthesis catalyst

The present invention relates to a process for conveniently preparing a supported cobalt-containing Fischer-Tropsch synthesis catalyst having improved activity and selectivity for C.sub.5+ hydrocarbons. In one aspect, the present invention provides a process for preparing a supported cobalt-containing Fischer-Tropsch synthesis catalyst, said process comprising the steps of: (a) impregnating a support material with: i) a cobalt-containing compound and ii) acetic acid, or a manganese salt of acetic acid, in a single impregnation step to form an impregnated support material; and (b) drying and calcining the impregnated support material; wherein the support material impregnated in step (a) has not previously been modified with a source of metal other than cobalt; and wherein when the cobalt-containing compound is cobalt hydroxide, a manganese salt of acetic acid is not used in step (a) of the process.

DIESEL OXIDATION CATALYST
20220379293 · 2022-12-01 ·

The present invention relates to a diesel oxidation catalyst comprising a carrier body having a length L extending between a first end face and a second end face, and differently composed material zones A and B arranged on the carrier body, wherein material zone A comprises platinum and palladium applied to a cerium-titanium mixed oxide, and material zone B comprises platinum and palladium applied to a carrier oxide B.

DEHYDROGENATION CATALYST
20220379287 · 2022-12-01 ·

A dehydrogenation catalyst for producing propylene by a dehydrogenation reaction of propane, the dehydrogenation catalyst including a platinum element and an element M1 and may contain an element M2 as active components, wherein the element M1 is one or more elements selected from the group consisting of a gallium element, a cobalt element, a copper element, a germanium element, a tin element and an iron element, the element M2 is one or more elements selected from the group consisting of a lead element and a calcium element, and the platinum element and the element M1 form an alloy.

Olefin epoxidation catalyst, preparation method therefor, and application thereof

The present invention relates to a preparation method for an olefin epoxidation catalyst, comprising: (1) preparing a titanium-silicon gel; (2) performing pore-enlarging treatment to the titanium-silicon gel by using organic amine or liquid ammonia, and drying, calcinating to obtain a titanium-silicon composite oxide; (3) optionally performing alcohol solution of organic alkali metal salt treatment; and (4) optionally performing gas-phase silanization treatment. The catalyst prepared by the method of the present invention has adjustable variability for pore size, so that the activity thereof for epoxidation reactions of the olefin molecules with different dynamic diameters is higher; the surface acidity of the catalyst can be reduced effectively through two-step modification to the catalyst, so that the catalyst has higher selectivity for epoxidation product.

Ultraviolet activated photocatalytic materials; their use in volatile compound decomposition
11511267 · 2022-11-29 · ·

Described herein are heterogeneous materials comprising a mixture of a first n-type semiconductor and a second n-type semiconductor. The first n-type semiconductor may be a single or plural phase TiO.sub.2 material. The second n-type semiconductor includes a metal titanate and/or a noble metal. Upon activation with ultraviolet light, the photocatalytic material mixtures described herein efficiently decompose volatile chemical compounds. Furthermore, the photocatalytic materials disclosed herein are observably more stable, relative to known semiconductor materials, to inactivation by deposition.

LED ultraviolet germicidal lamp
11511006 · 2022-11-29 · ·

A LED ultraviolet germicidal lamp includes a bracket, a power box, a driving light source, a heat sink, an ultraviolet light source, a lampshade, a quartz glass, a catalyst gauze, and a lamp frame. The bracket is connected to the heat sink, and the power box and the driving light source are provided in the bracket in sequence from outside to inside. The driving light source is provided in the power box and is connected to the power box by bolts. The heat sink is connected to the power box and is provided at a lower end of the power box. Titanium dioxide is used as the catalyst and is catalyzed by the UVC light source. Hydroxyl radicals produced when nanoscale titanium dioxide catalyst gauze is exposed to the UVC light source destroy bacteria and viruses.