Patent classifications
B01J23/18
CATALYST AND METHOD FOR PREPARING LIGHT OLEFIN USING DIRECT CONVERSION OF SYNGAS
A catalyst for preparing light olefin using direct conversion of syngas is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide; and the component II is one or more than one of zeolite of CHA and AEI structures or metal modified CHA and/or AEI zeolite. A weight ratio of the active ingredients in the component Ito the component II is 0.1-20. The reaction process has high product yield and selectivity, wherein the sum of the selectivity of the propylene and butylene reaches 40-75%; and the sum of the selectivity of light olefin comprising ethylene, propylene and butylene can reach 50-90%. Meanwhile, the selectivity of a methane side product is less than 15%.
CATALYST AND METHOD FOR PREPARING LIGHT OLEFIN USING DIRECT CONVERSION OF SYNGAS
A catalyst for preparing light olefin using direct conversion of syngas is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide; and the component II is one or more than one of zeolite of CHA and AEI structures or metal modified CHA and/or AEI zeolite. A weight ratio of the active ingredients in the component Ito the component II is 0.1-20. The reaction process has high product yield and selectivity, wherein the sum of the selectivity of the propylene and butylene reaches 40-75%; and the sum of the selectivity of light olefin comprising ethylene, propylene and butylene can reach 50-90%. Meanwhile, the selectivity of a methane side product is less than 15%.
CARBON DIOXIDE REDUCTION DEVICE, AND POROUS ELECTRODE
A carbon dioxide reduction device of the present invention is a carbon dioxide reduction device comprising a first electrode; at least any one of an electrolyte solution and an ion conducting membrane; and a second electrode, wherein the first electrode is a porous electrode having a porous carbon, and the porous carbon has at least one type of metal-nonmetal element bond represented by M-R, in which M represents a metal element of Groups 4 to 15, and R represents a nonmetal element of Groups 14 to 16.
MULTILAYER CATALYTIC BED FOR THE PARTIAL OXIDATION OF N-BUTANE TO MALEIC ANHYDRIDE
A catalytic bed for the partial oxidation of n-butane to maleic anhydride which comprises at least one first catalytic layer and at least one second catalytic layer, wherein each catalytic layer consists of a vanadium and phosphorus mixed oxide (VPO) catalyst and only the catalyst of the second catalytic layer further comprises tungsten, and wherein the second catalytic layer constitutes 25% to 45% of the total length of the catalytic bed and is arranged consecutively after the first catalytic layer along the direction in which the mixture of gases comprising the oxidation reagents flows. The present invention also relates to a process for producing maleic anhydride by partial oxidation of n-butane which uses the catalytic bed.
MULTILAYER CATALYTIC BED FOR THE PARTIAL OXIDATION OF N-BUTANE TO MALEIC ANHYDRIDE
A catalytic bed for the partial oxidation of n-butane to maleic anhydride which comprises at least one first catalytic layer and at least one second catalytic layer, wherein each catalytic layer consists of a vanadium and phosphorus mixed oxide (VPO) catalyst and only the catalyst of the second catalytic layer further comprises tungsten, and wherein the second catalytic layer constitutes 25% to 45% of the total length of the catalytic bed and is arranged consecutively after the first catalytic layer along the direction in which the mixture of gases comprising the oxidation reagents flows. The present invention also relates to a process for producing maleic anhydride by partial oxidation of n-butane which uses the catalytic bed.
Aromatization Catalyst And Preparation Process And Use Thereof
An aromatization catalyst and preparation process and use thereof is set forth. The catalyst comprises an inorganic oxide and a modified Ga-ZSM-5 zeolite, which comprises a modified ZSM-5 zeolite with a hierarchical macro-meso-microporosity and gallium deposited in channels of and/or on surfaces of the modified ZSM-5 zeolite. The hierarchical porosity of the modified ZSM-5 zeolite in the catalyst can reduce diffusion resistance of products during the aromatization reaction, thereby retarding carbon depositing rate and substantially improving catalytic activity, aromatic hydrocarbon selectivity, stability and lifetime of the catalyst. When being used in aromatization of propane, the catalyst exhibits a high stability, a lifetime of more than 320 hours, and a selectivity to aromatic hydrocarbons of up to 73.3 wt. %.
Aromatization Catalyst And Preparation Process And Use Thereof
An aromatization catalyst and preparation process and use thereof is set forth. The catalyst comprises an inorganic oxide and a modified Ga-ZSM-5 zeolite, which comprises a modified ZSM-5 zeolite with a hierarchical macro-meso-microporosity and gallium deposited in channels of and/or on surfaces of the modified ZSM-5 zeolite. The hierarchical porosity of the modified ZSM-5 zeolite in the catalyst can reduce diffusion resistance of products during the aromatization reaction, thereby retarding carbon depositing rate and substantially improving catalytic activity, aromatic hydrocarbon selectivity, stability and lifetime of the catalyst. When being used in aromatization of propane, the catalyst exhibits a high stability, a lifetime of more than 320 hours, and a selectivity to aromatic hydrocarbons of up to 73.3 wt. %.
Catalyst System for Producing Cyclic Carbonates and Method Related Thereto
The present invention provides a catalyst system for producing cyclic carbonates from carbon dioxide (CO.sub.2) and epoxide-based compounds comprising: a pre-catalyst; and a co-catalyst wherein said pre catalyst is BiCl.sub.3 and said co-catalyst is selected from tetra-n-butylammonium bromide (TBAB), tetra-n-butylammonium iodide (TBAI), tetra-n-butylphosphonium bromide (PBu.sub.4Br), tetra-n-butylphosphonium iodide (PBu.sub.4I) or mixtures thereof.
SEMI-DULL POLYESTER DRAWN YARNS AND PREPARING METHOD THEREOF
A type of semi-dull polyester drawn yarns and preparing method thereof are disclosed. The preparing method is to melt spinning a modified polyester with FDY technique, wherein the modified polyester is the product of the esterification and the successive polycondensation reactions of evenly mixed terephthalic acid, ethylene glycol, main chain silicated diol, fluorinated dicarboxylic acid, matting agent and doped Bi.sub.2O.sub.3, in which the main chain silicated diol could be dimethylsiloxane diol, dimethyldiphenyldisiloxane glycol or tetramethyldisiloxane diol, and in which the fluorinated dicarboxylic acids could be 2,2-difluoro-1,3-malonic acid, 2,2-difluoro-1,4-succinic acid, 2,2-difluoro-1,5-glutaric acid or 2,2,3,3-tetrafluoro-1,4-succinic acid. The obtained fiber has a dye uptake of 87.5-91.8% when dyed at 120 C., and has an intrinsic viscosity drop of 18-26% when stored at 25 C. and R.H. 65% for 60 months. This invention features a method with ease of application and a product with good dyeing and degradation performance.
SEMI-DULL POLYESTER DRAWN YARNS AND PREPARING METHOD THEREOF
A type of semi-dull polyester drawn yarns and preparing method thereof are disclosed. The preparing method is to melt spinning a modified polyester with FDY technique, wherein the modified polyester is the product of the esterification and the successive polycondensation reactions of evenly mixed terephthalic acid, ethylene glycol, main chain silicated diol, fluorinated dicarboxylic acid, matting agent and doped Bi.sub.2O.sub.3, in which the main chain silicated diol could be dimethylsiloxane diol, dimethyldiphenyldisiloxane glycol or tetramethyldisiloxane diol, and in which the fluorinated dicarboxylic acids could be 2,2-difluoro-1,3-malonic acid, 2,2-difluoro-1,4-succinic acid, 2,2-difluoro-1,5-glutaric acid or 2,2,3,3-tetrafluoro-1,4-succinic acid. The obtained fiber has a dye uptake of 87.5-91.8% when dyed at 120 C., and has an intrinsic viscosity drop of 18-26% when stored at 25 C. and R.H. 65% for 60 months. This invention features a method with ease of application and a product with good dyeing and degradation performance.