A method of making a titanium dioxide nanowire array includes contacting a substrate with a solvent comprising a titanium (III) precursor, an acid, and an oxidant while microwave heating the solvent, thereby forming a hydrogen titanate H2Ti2O5.H2O nanowire array. The hydrogen titanate nanowire array is annealed to form a titanium dioxide nanowire array. The substrate is seeded with titanium dioxide before starting the hydrothermal synthesis of the hydrogen titanate nanowire array. The titanium dioxide nanowire array is loaded with a platinum group metal to form an exhaust gas catalyst. The titanium dioxide nanowire array can be used to catalyze oxidation of combustion exhaust.

A catalyst-coated, plugged honeycomb body having a honeycomb structure with a matrix of porous walls forming a plurality of channels, at least some of the plurality of channels being plugged to form inlet channels and outlet channels. At least some of the porous walls are filtration walls and at least some of the porous walls are non-filtration walls. A catalyst is preferentially disposed on the non-filtration walls, wherein the catalyst being preferentially disposed comprises CR<0.2 wherein CR is a coating ratio defined as an average percent loading of a washcoat containing the catalyst on and within the filtration walls divided by an average percent loading of the washcoat containing the catalyst on and within the non-filtration walls. Methods and apparatus configured to preferentially apply a catalyst-containing slurry to the non-filtration walls are provided, as are other aspects.

Provided is an exhaust gas purification device that ensures an improved purification performance and a suppressed pressure loss. An exhaust gas purification device of the present disclosure includes a honeycomb substrate and an inflow cell side catalyst layer. disposed on a surface on the inflow cell side in an inflow side region of the partition wall. When a gas permeability coefficient of an inflow side partition wall portion including the inflow side region of the partition wall and the inflow cell side catalyst layer is Ka and a gas permeability coefficient of an outflow side partition wall portion including an outflow side region at least from the predetermined position to an outflow side end of the partition wall is Kb, a ratio Ka/Kb of the gas permeability coefficients is within a range of 0.4 or more and 0.8 or less.

A multi-stage process for transforming a high sulfur ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process that produces a Product Heavy Marine Fuel Oil that can be used as a feedstock for subsequent refinery process such as anode grade coking, needle coking and fluid catalytic cracking. The Product Heavy Marine Fuel Oil exhibits multiple properties desirable as a feedstock for those processes including a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process is also disclosed.

A multi-stage process for transforming a high sulfur ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process that produces a Product Heavy Marine Fuel Oil that can be used as a feedstock for subsequent refinery process such as anode grade coking, needle coking and fluid catalytic cracking. The Product Heavy Marine Fuel Oil exhibits multiple properties desirable as a feedstock for those processes including a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process is also disclosed.

A particulate filter disclosed herein includes a wall-flow structure substrate 10 and a wash coat layer 20 held inside a partition 16 of the substrate 10. The wash coat layer 20 includes an inlet layer 22 formed to have predetermined length L.sub.A and thickness T.sub.A from near an end thereof on an exhaust gas inflow side X1, and an outlet layer 24 formed to have predetermined length L.sub.B and thickness T.sub.B from near an end thereof on an exhaust gas outflow side X2. The inlet layer 22 and the outlet layer 24 partially overlap each other. In the particulate filter disclosed herein, the inlet layer 22 contains a precious metal catalyst, while the outlet layer 24 contains substantially no precious metal catalyst. The length L.sub.A of the inlet layer is 50% or more and 75% or less of a total length L of the partition 16. Thus, the particulate filter is capable of achieving both PM collection performance and pressure-drop reduction performance at high levels.

A process for reducing the environmental contaminants in a ISO 8217: 2017 Table 2 compliant Feedstock Heavy Marine Fuel Oil and resulting product, the process involving: mixing a Feedstock Heavy Marine Fuel Oil with a Activating Gas to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture; separating the Product Heavy Marine Fuel Oil from the Process Mixture and, discharging the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil complies with ISO 8217:2017 Table 2 for residual marine fuel and the Environmental Contaminants, which are selected from the group consisting of: a sulfur; vanadium, nickel, iron, aluminum and silicon and combinations thereof, are less than 0.5 wt. %. The Product Heavy Marine Fuel Oil can be used as blending stock for an ISO 8217:2017 Table 2 compliant, IMO 2020 compliant, low sulfur heavy marine fuel composition.

A process for reducing the environmental contaminants in a ISO 8217: 2017 Table 2 compliant Feedstock Heavy Marine Fuel Oil and resulting product, the process involving: mixing a Feedstock Heavy Marine Fuel Oil with a Activating Gas to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture; separating the Product Heavy Marine Fuel Oil from the Process Mixture and, discharging the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil complies with ISO 8217:2017 Table 2 for residual marine fuel and the Environmental Contaminants, which are selected from the group consisting of: a sulfur; vanadium, nickel, iron, aluminum and silicon and combinations thereof, are less than 0.5 wt. %. The Product Heavy Marine Fuel Oil can be used as blending stock for an ISO 8217:2017 Table 2 compliant, IMO 2020 compliant, low sulfur heavy marine fuel composition.

Provided is a method of manufacturing a supported catalyst and a supported catalyst manufactured using the same. The method may prevent the growth of catalytic metal particles by repeatedly applying heat, so the method is simpler and more economical than conventional processes. Moreover, since the support in the supported catalyst thus manufactured includes a hollow having a predetermined size, an electrode manufactured using the supported catalyst may ensure a desired electrode thickness even when used in a relatively small amount compared to the conventional technology. Moreover, water generated during operation of a fuel cell can be efficiently discharged, so desired mass transfer resistance can be exhibited, and a high electrochemically active surface area (ECSA) and superior catalytic activity can be attained.

Provided is a post-treatment method and system for a core-shell catalyst, which relate to the field of fuel cell materials. The post-treatment method of the present disclosure includes the following steps: a core-shell catalyst is added into an electrolyte solution containing citric acid or ethylenediamine tetraacetic acid, a gas containing oxygen is introduced into the electrolyte solution followed by stirring for a predetermined reaction time, the open circuit potential of the reactor base is recorded during the reaction time, and the open circuit potential should stabilize at 0.90˜1.0 V vs. RHE when the reaction is completed. The molar ratio of citric acid or ethylenediamine tetraacetic acid to platinum of the core-shell catalyst is 10 to 1000:1. A percentage of oxygen in the gas is 10 to 100% by volume. The post-treatment method of the present disclosure can significantly improve the platinum mass activity and PGM mass activity and durability of core-shell catalyst.