B01J23/74

Method of preparing wide-temperature catalyst for preferential oxidation of carbon monoxide in hydrogen-enriched atmosphere, and product and use lthereof

This invention provides a preparation method of a catalyst for preferential oxidization of CO in a hydrogen-enriched atmosphere, and a catalyst product obtained from the method and its applications thereof. Particularly, in this invention, a wide-temperature catalyst for preferential oxidization of CO in a hydrogen-enriched atmosphere is obtained by depositing one or more of an iron oxide, cobalt oxide, and nickel oxide as a promoter onto the surface of a supported Pt-group noble metal catalyst precursor via chemical vapor deposition or atomic layer deposition. In the wide-temperature catalyst, the active noble metal component has a content of 0.1 to 10 wt %, and the promoter has a content of 0.1 to 10 wt % in terms of the metal element thereof. In the reaction of preferential oxidation of CO in a hydrogen-enriched atmosphere, the catalyst prepared by this invention can exhibit excellent catalytic performance and can achieve high conversion of CO with high selectivity in a wide temperature range of −80 to 200° C., for example. Also, the catalyst can remain stable for a long time even in a case where steam and CO.sub.2 are present in the hydrogen-enriched atmosphere.

PROCESS AND DEVICE FOR REDUCING ENVIRONMENTAL CONTAMINATES IN HEAVY MARINE FUEL OIL

A process for reducing the environmental contaminants in a ISO 8217 compliant Feedstock Heavy Marine Fuel Oil, the process involving: mixing a quantity of the Feedstock Heavy Marine Fuel Oil with a quantity of Activating Gas mixture to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture from the feedstock mixture; separating the Product Heavy Marine Fuel Oil liquid components of the Process Mixture from the gaseous components and by-product hydrocarbon components of the Process Mixture and, discharging the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil is compliant with ISO 8217 for residual marine fuel oils and has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 % wt. to 0.5 % wt.. The Product Heavy Marine Fuel Oil can be used as or as a blending stock for an ISO 8217 compliant, IMO MARPOL Annex VI (revised) compliant low sulfur or ultralow sulfur heavy marine fuel oil. A device for conducting the process is also disclosed.

PROCESS AND DEVICE FOR REDUCING ENVIRONMENTAL CONTAMINATES IN HEAVY MARINE FUEL OIL

A process for reducing the environmental contaminants in a ISO 8217 compliant Feedstock Heavy Marine Fuel Oil, the process involving: mixing a quantity of the Feedstock Heavy Marine Fuel Oil with a quantity of Activating Gas mixture to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture from the feedstock mixture; separating the Product Heavy Marine Fuel Oil liquid components of the Process Mixture from the gaseous components and by-product hydrocarbon components of the Process Mixture and, discharging the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil is compliant with ISO 8217 for residual marine fuel oils and has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 % wt. to 0.5 % wt.. The Product Heavy Marine Fuel Oil can be used as or as a blending stock for an ISO 8217 compliant, IMO MARPOL Annex VI (revised) compliant low sulfur or ultralow sulfur heavy marine fuel oil. A device for conducting the process is also disclosed.

IRON REMOVAL FROM CARBON NANOTUBES AND METAL CATALYST RECYCLE
20230102474 · 2023-03-30 · ·

The present disclosure provides a method for purifying nanostructured material comprising carbon nanotubes, metal impurities and amorphous carbon impurities. The method generally includes oxidizing the unpurified nanostructured material to remove the amorphous carbon and thereby exposing the metal impurities and subsequently contacting the nanostructured material with carbon monoxide to volatilize the metal impurities and thereby substantially remove them from the nanostructured material.

CATALYST MEDIUM COMPRISING HOLLOW MICROSPHERES
20230035172 · 2023-02-02 · ·

The present invention relates to a calcined medium, in particular a catalyst or a catalyst medium or an adsorbent/absorbent mass, in particular in the form of extrudates, pellets, granules or beads, the medium comprising a porous matrix comprising carbonates, clays, zeolites, oxides, or metal and/or silicon hydroxides, and the matrix incorporating hollow mineral microspheres having a different composition in a content of between 0.3 and 50% by weight, in particular between 0.5 and 15% by weight, of the matrix.

CATALYTIC REACTOR SYSTEM AND CATALYST FOR CONVERSION OF CAPTURED C02 AND RENEWABLE H2 INTO LOW-CARBON SYNGAS

The present invention describes an improved catalytic reactor system with an improved catalyst that transforms CO.sub.2 and low carbon H.sub.2 into low-carbon syngas with greater than an 80% CO.sub.2 conversion efficiency, resulting in the reduction of plant capital and operating costs compared to processes described in the current art. The inside surface of the adiabatic catalytic reactors is lined with an insulating, non-reactive surface which does not react with the syngas and effect catalyst performance. The improved catalyst is robust, has a high CO.sub.2 conversion efficiency, and exhibits little or no degradation in performance over long periods of operation. The low-carbon syngas is used to produce low-carbon fuels (e.g., diesel fuel, jet fuel, gasoline, kerosene, others), chemicals, and other products resulting in a significant reduction in greenhouse gas emissions compared to fossil fuel derived products.

MULTI-LAYER FILTRATION SYSTEM AND FILTER UNIT COMPRISING SAME
20220339471 · 2022-10-27 ·

Proposed is a multi-layer filtration system including a metal catalyst filter unit, a carbon filter unit, and an inorganic compound filter unit. The metal catalyst filter unit includes at least one among metals including Ni, Co, Fe, Cu, Cr, Mg, Zn, Ba, Au, Ag, Pd, Pt, Ru, Mn, and Ti, oxides thereof, and mixtures thereof. The carbon filter unit includes at least one of activated carbon or activated carbon fiber. The inorganic compound filter unit includes an inorganic compound capable of adsorbing toxic gas. The multi-layer filtration system has good removal effect for toxic gas. A filter module including the multi-layer filtration system and a gas mask including the multi-layer filtration system are also proposed.

MULTI-LAYER FILTRATION SYSTEM AND FILTER UNIT COMPRISING SAME
20220339471 · 2022-10-27 ·

Proposed is a multi-layer filtration system including a metal catalyst filter unit, a carbon filter unit, and an inorganic compound filter unit. The metal catalyst filter unit includes at least one among metals including Ni, Co, Fe, Cu, Cr, Mg, Zn, Ba, Au, Ag, Pd, Pt, Ru, Mn, and Ti, oxides thereof, and mixtures thereof. The carbon filter unit includes at least one of activated carbon or activated carbon fiber. The inorganic compound filter unit includes an inorganic compound capable of adsorbing toxic gas. The multi-layer filtration system has good removal effect for toxic gas. A filter module including the multi-layer filtration system and a gas mask including the multi-layer filtration system are also proposed.

MULTI-STAGE PROCESS AND DEVICE UTILIZING STRUCTURED CATALYST BEDS AND REACTIVE DISTILLATION FOR THE PRODUCTION OF A LOW SULFUR HEAVY MARINE FUEL OIL

A multi-stage process for the production of a Product Heavy Marine Fuel Oil compliant with ISO 8217: 2017 as a Table 2 residual marine fuel from a high sulfur Feedstock Heavy Marine Fuel Oil compliant with ISO 8217: 2017 as a Table 2 residual marine fuel except for the sulfur level, involving hydrotreating under reactive distillation conditions in a Reaction System composed of one or more reaction vessels. The reactive distillation conditions allow more than 75% by mass of the Process Mixture to exit the bottom of the reaction vessel as Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a maximum sulfur content (ISO 14596 or ISO 8754) less than 0.5 mass %. A process plant for conducting the process for conducting the process is disclosed.

MULTI-STAGE PROCESS AND DEVICE UTILIZING STRUCTURED CATALYST BEDS AND REACTIVE DISTILLATION FOR THE PRODUCTION OF A LOW SULFUR HEAVY MARINE FUEL OIL

A multi-stage process for the production of a Product Heavy Marine Fuel Oil compliant with ISO 8217: 2017 as a Table 2 residual marine fuel from a high sulfur Feedstock Heavy Marine Fuel Oil compliant with ISO 8217: 2017 as a Table 2 residual marine fuel except for the sulfur level, involving hydrotreating under reactive distillation conditions in a Reaction System composed of one or more reaction vessels. The reactive distillation conditions allow more than 75% by mass of the Process Mixture to exit the bottom of the reaction vessel as Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a maximum sulfur content (ISO 14596 or ISO 8754) less than 0.5 mass %. A process plant for conducting the process for conducting the process is disclosed.