Metal oxide catalysts comprising various dopants are provided. The catalysts are useful as heterogenous catalysts in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons such as ethane and ethylene. Related methods for use and manufacture of the same are also disclosed.

Disclosed are an electrochemical catalyst capable of lowering the overpotential of the oxygen evolution reaction (OER) during a water splitting reaction in spite of using inexpensive metals (specifically, base metals) instead of conventional noble metal catalysts in the complex water-splitting reactions that require high overpotential, and a water splitting system using the same.

A catalyst used for dehydrogenation of an organic hydrogen-storage material to generate hydrogen, a support for the catalyst, and a preparation process thereof are presented. A hydrogen-storage alloy and a preparation process thereof are provided. A process for providing high-purity hydrogen, a high-efficiently distributed process for producing high-purity and high-pressure hydrogen, a system for providing high-purity and high-pressure hydrogen, a mobile hydrogen supply system, and a distributed hydrogen supply apparatus are also described.

A process prepares an oxygen carrier for a chemical looping process including providing a material A having a first transition metal and/or an oxide of the first transition metal. The first transition metal is selected from chemical element groups 6-11 of the Periodic System. Material A is subjected to a reaction with H2 to reduce the first transition metal and/or oxide to form a reduced material B. Material B is treated with a salt solution of a second transition metal selected to have a standard reduction potential larger than the first transition metal. A portion of the first transition metal in the reduced material B is replaced by the second transition metal. A molar ratio of the first transition metal with respect to the second transition metal in material B ranges between 2:1 and 100:1. An oxygen carrier is obtained with the method and is regenerated using steam.

A method of manufacturing a catalyst article, the method comprising: providing a complex of a polyphenol and a PGM, the PGM comprising rhodium and/or platinum, the polyphenol comprising an ester functional group; providing a support material; applying the complex to the support material to form a loaded support material; disposing the loaded support material on a substrate; and heating the loaded support material to form nanoparticles of the PGM on the support material.

The presently disclosed embodiments relate to the utilization of coal-derived fine mineral matter in chemical recycling of plastics or of solid mixed plastic waste. The instantly disclosed mineral based catalyst benefits the processes of catalytic cracking, gasification and steam reforming to maximize carbon utilization and production of plastics of original quality from recycled or renewable feedstocks while reducing the plastic pollution in the environment. The catalyst can be based on inorganic fine mineral matter, a natural ancient mineral mixture found in coal deposits and containing a plurality of transition metals, such as iron, copper, and manganese, as well as calcium, barium, magnesium, potassium, sodium, which can act as co-catalysts. Addition of the catalyst can convert plastic to syngas at a faction of the energy of conventional technologies.

A catalyst for an oxychlorination process of hydrocarbons, a preparation method thereof, and a method for preparing an oxychlorination compound of hydrocarbons using the same.

Methods of making an iron based catalyst using microwave hydrothermal synthesis are provided. The methods include dissolving iron(III) nitrate, Fe(NO.sub.3).sub.3, in an organic solvent to form a solution. Once dissolved, the methods include a step of neutralizing the solution with an alkaline mineralizing agent to obtain a precipitate. The solution with the precipitate is then subjected to microwave radiation to cause a temperature gradient and a hydrothermal crystallization process to form a synthesized product. The synthesized product is subsequently separated from the mineralizing agent. The method includes washing and drying the synthesized product to obtain particles of sodium iron oxide (NaFeO.sub.2) catalyst that can be used as a composition for a passive NO.sub.x adsorber. A two-stage NO.sub.x abatement device for removal of NO.sub.x from an exhaust gas stream during a cold start operation of an internal combustion engine is also provided.

Methods of making an iron based catalyst using microwave hydrothermal synthesis are provided. The methods include dissolving iron(III) nitrate, Fe(NO.sub.3).sub.3, in an organic solvent to form a solution. Once dissolved, the methods include a step of neutralizing the solution with an alkaline mineralizing agent to obtain a precipitate. The solution with the precipitate is then subjected to microwave radiation to cause a temperature gradient and a hydrothermal crystallization process to form a synthesized product. The synthesized product is subsequently separated from the mineralizing agent. The method includes washing and drying the synthesized product to obtain particles of sodium iron oxide (NaFeO.sub.2) catalyst that can be used as a composition for a passive NO.sub.x adsorber. A two-stage NO.sub.x abatement device for removal of NO.sub.x from an exhaust gas stream during a cold start operation of an internal combustion engine is also provided.

Metal oxide catalysts comprising various dopants are provided. The catalysts are useful as heterogenous catalysts in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons such as ethane and ethylene. Related methods for use and manufacture of the same are also disclosed.