B01J23/89

NANO-TO-NANO FE/PPM Pd CATALYSIS OF CROSS-COUPLING REACTIONS IN WATER
20170341069 · 2017-11-30 ·

In one embodiment, the present application discloses a catalyst composition comprising: a) a reaction solvent or a reaction medium; b) organometallic nanoparticles comprising: i) a nanoparticle (NP) catalyst, prepared by a reduction of an iron salt in an organic solvent, wherein the catalyst comprises at least one other metal selected from the group consisting of Pd, Pt, Au, Ni, Co, Cu, Mn, Rh, Ir, Ru and Os or mixtures thereof; c) a ligand; and d) a surfactant; wherein the metal or mixtures thereof is present in less than or equal to 50,000 ppm relative to the iron salt.

Method for preparing nano metal/metal oxide loaded molecular sieve catalyst

The present disclosure provides a method for preparing a molecular sieve catalyst. A water-in-oil micro-emulsion including a continuous phase containing an organic solvent and a dispersed phase containing an aqueous solution containing one or more metal salts and a water-soluble organic carbon source is prepared, hydrolyzed, and azeotropically distilled to form a mixture solution. The mixture solution is heated to carbonize the water-soluble organic carbon source to form nanoparticles each having a core-shell structure including a carbon-shelled metal-oxide. The nanoparticles containing the carbon-shelled metal-oxide are dispersed in a molecular sieve precursor solution. A nanoparticle-loaded molecular sieve is formed from the molecular sieve precursor solution containing the nanoparticles, and then calcined to remove carbon there-from to form a metal-oxide loaded molecular sieve.

Fischer-tropsch synthesis catalyst, method for producing same, and method for producing hydrocarbon

A process for producing a Fischer-Tropsch synthesis catalyst according to the present invention comprises a step of calcining a carrier precursor containing silica calcined at a temperature T.sub.1 and a zirconium compound at a temperature T.sub.2 to obtain a carrier; and a step of calcining a catalyst precursor containing the carrier and a cobalt compound and/or a ruthenium compound at a temperature T.sub.3, wherein the content of the zirconium compound in the carrier precursor is 0.01 to 7% by mass in terms of zirconium oxide based on the total mass of the catalyst, and T.sub.1, T.sub.2, and T.sub.3 satisfy conditions represented by expressions (1) to (3):
T.sub.1≧T.sub.3  (1)
250° C.≦T.sub.2≦450° C.  (2)
250° C.≦T.sub.3≦450° C.  (3).

CATALYST FOR DECOMPOSING PERFLUORINATED COMPOUNDS AND METHOD OF MANUFACTURING THE CATALYST

A catalyst for decomposing perfluorinated compounds includes an alumina carrier, at least one metal carried on the alumina carrier and selected from the group consisting of Zn, Ni, W, Zr, Ti, Ga, Nb, Co, Mo, V, Cr, Mn, Fe, and Cu, S carried on the alumina carrier, and rare-earth metals carried on the alumina carrier.

Methods for preparation and use of liquid synthesis catalysts
11666893 · 2023-06-06 ·

Described herein are catalysts relating to liquid synthesis, methods of their preparation, and methods of their use. In an embodiment according to the present disclosure, a method of producing a catalyst for liquid synthesis comprises: providing a silica oxide support; pretreating the silica oxide support to remove air and moisture; impregnating the pretreated silica oxide support with cobalt from a cobalt source using a cobalt impregnation method; and calcinating the impregnated silica oxide support in an oven with a temperature ramping profile, wherein the calcinating comprises feeding air into the oven.

CATALYST CARRIER AND METHOD FOR PRODUCING THE SAME

A catalyst carrier, an electrode catalyst, an electrode including the catalyst, a membrane electrode assembly including the electrode, and a fuel cell including the membrane electrode assembly. The catalyst carrier includes a carbon material having a chain structure including a chain of carbon particles, and an oxide-carbon composite particle in which a carbon particle encloses a particle of an oxide of a group IV element on the periodic table, the oxide-carbon composite particle being contained in the carbon material. The catalyst carrier has a BET specific surface area of 450 to 1100 m.sup.2/g.

CATALYST CARRIER AND METHOD FOR PRODUCING THE SAME

A catalyst carrier, an electrode catalyst, an electrode including the catalyst, a membrane electrode assembly including the electrode, and a fuel cell including the membrane electrode assembly. The catalyst carrier includes a carbon material having a chain structure including a chain of carbon particles, and an oxide-carbon composite particle in which a carbon particle encloses a particle of an oxide of a group IV element on the periodic table, the oxide-carbon composite particle being contained in the carbon material. The catalyst carrier has a BET specific surface area of 450 to 1100 m.sup.2/g.

PROCESS FOR THE PREPARATION OF 2, 3, 3, 3-TETRAFLUOROPROPENE

Disclosed is a process for the preparation of 2,3,3,3-tetrafluoropropene, comprising the following two reaction steps: a. a compound having the formula CF.sub.3-xCl.sub.xCF.sub.2-yCl.sub.yCH.sub.2Cl undergoes gas-phase fluorination with hydrogen fluoride through n serially-connected reaction vessels in the presence of a compound catalyst producing 2,3-dichloro-1,1,1,2-tetrafluoropropane, 1,2,3-trichloro-1,1,2-trifluoropropane, and 1,3-dichloro-1,1,2,2-tetrafluoropropane; in said formula, x=1, 2, 3, y=1, 2, and 3≦x+y≦5; b. the 2,3-dichloro-1,1,1,2-tetrafluoropropane, 1,2,3-trichloro-1,1,2-trifluoropropane, and 1,3-dichloro-1,1,2,2-tetrafluoropropane undergo gas-phase dehalogenation with hydrogen in the presence of a dehalogenation catalyst, producing 2,3,3,3-tetrafluoropropene and 3-chloro-2,3,3-trifluoropropene, then separation and refining are performed, producing 2,3,3,3-tetrafluoropropene. The present invention is primarily used to produce 2,3,3,3-tetrafluoropropene.

ELECTRODE CATALYST, GAS DIFFUSION ELECTRODE-FORMING COMPOSITION, GAS DIFFUSION ELECTRODE, MEMBRANE ELECTRODE ASSEMBLY, AND FUEL CELL STACK

Provided is an electrode catalyst in which the contents of chlorine (Cl) species and bromine (Br) species are reduced to a predetermined level or lower, capable of exhibiting sufficient catalyst performance. The electrode catalyst has a core-shell structure including a support, a core part formed on the support and a shell part formed to cover at least a part of the surface of the core part. A concentration of bromine (Br) species of the electrode catalyst as measured by X-ray fluorescence (XRF) spectroscopy is 400 ppm or less, and a concentration of chlorine (Cl) species of the electrode catalyst as measured by X-ray fluorescence (XRF) spectroscopy is 900 ppm or less.

CARBON DIOXIDE REDUCTION CATALYST AND CARBON DIOXIDE REDUCTION METHOD

The present invention provides a carbon dioxide reduction catalyst that is used in reduction reactions of carbon dioxide and that has high methanol selectivity. A carbon dioxide reduction catalyst according to the present invention is used in producing methanol by reduction reactions of carbon dioxide, and contains Au and Cu as catalyst components and ZnO as a carrier. It is preferable that the catalyst components contain 7-25 mol % of Au as a catalyst component. This makes it possible to obtain high methanol selectivity—for example, selectivity of not less than 80%. The carbon dioxide reduction catalyst makes it possible to obtain high methanol selectivity even under the conditions of not more than 240° C. and not more than 50 bar.