Patent classifications
B01J23/89
Catalyst and process for thermo-neutral reforming of petroleum-based liquid hydrocarbons
A process for producing a hydrogen-rich gas stream from a liquid hydrocarbon stream, the process comprising the steps of introducing the liquid hydrocarbon stream to a dual catalytic zone, the liquid hydrocarbon stream comprises liquid hydrocarbons selected from the group consisting of liquid petroleum gas (LPG), light naphtha, heavy naphtha, gasoline, kerosene, diesel, and combinations of the same, the dual catalytic zone comprises: a combustion zone comprising a seven component catalyst, and a steam reforming zone, the steam reforming zone comprising a steam reforming catalyst; introducing steam to the dual catalytic zone, introducing an oxygen-rich gas to the dual catalytic zone; contacting the liquid hydrocarbon stream, steam, and oxygen-rich gas with the seven component catalyst to produce a combustion zone fluid; and contacting the combustion zone fluid with the steam reforming catalyst to produce the hydrogen-rich gas stream, wherein the hydrogen-rich gas stream comprises hydrogen.
Method for preparing ternary alloy catalyst with polydopamine coating and ternary alloy catalyst prepared thereby
Disclosed is a method for preparing a ternary alloy catalyst with polydopamine coating and a ternary alloy catalyst prepared thereby. The method for preparing a ternary alloy catalyst according to the present disclosure may provide a ternary alloy catalyst with increased resistance to carbon monoxide (CO) poisoning in which polydopamine is utilized as a coating material for a ternary alloy catalyst having a core-shell structure containing platinum to suppress the growth of particles during subsequent high-temperature heat treatment, and nickel (Ni), which is a transition metal, is diffused inside to form a core, thereby effectively preventing elution of nickel under an acidic condition.
Segregation induced core-shell structure
A process for synthesis of PtNi high surface area core/shell particles. The processing including formation of PtNi nanoparticles, exposure of the PtNi nanoparticles to oxygen to form a nickel oxide coating on the nanoparticles at the same time the segregation of Ni to surface induces a Pt-skin with PtNi core structure, removal of the nickel oxide coating to form PtNi core/Pt shell (or Pt-skin) structure.
CATALYST FOR THE GENERATION OF HYDROGEN AND/OR SYNTHESIS GAS, METHOD FOR OBTAINING SAME AND USE IN A STEAM REFORMING PROCESS
The present invention addresses to a catalyst, and the method for obtaining the same, for generating hydrogen and/or syngas. More specifically, the present invention describes a catalyst based on nickel, molybdenum and tungsten, for steam reforming processes of natural gas or other hydrocarbon streams (refinery gas, propane, butane, naphtha or any mixture thereof) that presents high resistance to deactivation by coke deposition. According to the present invention, the catalyst has NiMoW as its active phase, in bulk form and/or supported on an alumina oxide and other high surface area oxide supports, and may also contain other promoters. Furthermore, the present invention teaches the production of a catalyst whose active phase of NiMoW has high activity for hydrocarbon steam reforming reaction.
CATALYTIC DECOMPOSITION DEVICE AND INTEGRATED WASTE GAS TREATMENT SYSTEM
An integrated waste gas treatment system includes an adsorption/desorption device that receives a waste gas that includes an organic compound and an organic nitrogen compound exhausted from a semiconductor manufacturing facility, where the adsorption/desorption device adsorbs the organic compound and the organic nitrogen compound and concentrates and desorbs the organic compound and the organic nitrogen compound, and a catalytic decomposition device disposed adjacent to the adsorption/desorption device, where the catalytic decomposition device includes a catalytic chamber that provides a gas passage through which a gas desorbed from the adsorption/desorption device flows and an oxidation-reduction catalyst disposed in the gas passage that removes the organic compound and the organic nitrogen compound from the desorbed gas. The organic compound and the organic nitrogen compound are subjected to an oxidation treatment by the oxidation-reduction catalyst, and nitrogen oxides generated by the oxidation treatment are removed by a selective reduction reaction.
Oxidation catalyst for a diesel engine exhaust
An oxidation catalyst for treating an exhaust gas produced by a diesel engine comprises a catalytic region and a substrate, wherein the catalytic region comprises a catalytic material comprising: bismuth (Bi) or an oxide thereof; a Group 8 metal or an oxide thereof; a platinum group metal (PGM) selected from the group consisting of (i) platinum (Pt), (ii) palladium (Pd) and (iii) platinum (Pt) and palladium (Pd); and a support material, which comprises alumina, silica, a mixed oxide of alumina and a refractory oxide, a mixed oxide of silica and a refractory oxide, a composite oxide of alumina and a refractory oxide, a composite oxide of silica and a refractory oxide, alumina doped with a refractory oxide or silica doped with a refractory oxide.
Method and apparatus for manufacturing core-shell catalyst
The present disclosure relates to a method and an apparatus for manufacturing a core-shell catalyst, and more particularly, to a method and an apparatus for manufacturing a core-shell catalyst, in which a particle in the form of a core-shell in which the metal nanoparticle is coated with platinum is manufactured by substituting copper and platinum through a method of manufacturing a metal nanoparticle by emitting a laser beam to a metal ingot, and providing a particular electric potential value, and as a result, it is possible to continuously produce nanoscale uniform core-shell catalysts in large quantities.
NOVEL ZONED CATALYSTS FOR CNG ENGINE EXHAUST GAS TREATMENTS WITH IMPROVED AMMONIA EMISSION CONTROL
A three-way catalyst article, and its use in an exhaust system for compressed natural gas engines, is disclosed. The catalyst article for treating exhaust gas from compressed natural gas (CNG) engine comprising: a substrate comprising an inlet end, an outlet end with an axial length L; a first catalytic region beginning at the outlet end and extending for less than the axial length L, wherein the first catalytic region comprises a first zeolite; and a second catalytic region beginning at the inlet end, wherein the second catalytic region comprises a second platinum group metal (PGM) component, a second oxygen storage capacity (OSC) material, and a second inorganic oxide; wherein the second PGM component is selected from the group consisting of palladium, platinum, rhodium or a combination thereof.
Nitrogen oxide sorbent and exhaust gas cleaning catalyst
A nitrogen oxide storage material comprising: Mg.sub.1-yAl.sub.2O.sub.4-y, wherein y is a number satisfying 0≤y≤0.2, a noble metal, an oxide of a metal other than the noble metal, and a barium compound, the noble metal, the oxide, and the barium compound being loaded on Mg.sub.1-yAl.sub.2O.sub.4-y. The metal oxide comprises at least one metal oxide selected from zirconium oxide, praseodymium oxide, niobium oxide, and iron oxide.
HIGH PERFORMANCE PLATINUM-BASED CATALYST COMBINED WITH CARBON SUPPORT ENGINEERING
Provided herein are improved Pt-based electrochemical catalyst (or electrocatalyst) for ORR, exhibiting a combination of high activity and high stability, along with reduced usage of scarce Pt. The Pt-based electrocatalyst is loaded on a catalyst support, which is developed through carbon engineering to impart improved performance to the Pt-based electrocatalyst.