The method of fabricating a photocatalyst for water splitting includes electrospinning a Zn-based solution mixed with CdS nanoparticles and then calcining to produce CdS nanoparticle decorated ZnO nanofibers having significant photocatalytic activity for water splitting reactions. The photocatalyst fabricated according to the method can produce H.sub.2 at a rate of 820 molh.sup.1g.sup.1 catalyst from aqueous solution under light irradiation.

Photocatalysts for reduction of carbon dioxide and water are provided that can be tuned to produce certain reaction products, including hydrogen, alcohol, aldehyde, and/or hydrocarbon products. These photocatalysts can form artificial photosystems and can be incorporated into devices that reduce carbon dioxide and water for production of various fuels. Doped wide-bandgap semiconductor nanotubes are provided along with synthesis methods. A variety of optical, electronic and magnetic dopants (substitutional and interstitial, energetically shallow and deep) are incorporated into hollow nanotubes, ranging from a few dopants to heavily-doped semiconductors. The resulting wide-bandgap nanotubes, with desired electronic (p- or n-doped), optical (ultraviolet bandgap to infrared absorption in co-doped nanotubes), and magnetic (from paramagnetic to ferromagnetic) properties, can be used in photovoltaics, display technologies, photocatalysis, and spintronic applications.

Photocatalysts for reduction of carbon dioxide and water are provided that can be tuned to produce certain reaction products, including hydrogen, alcohol, aldehyde, and/or hydrocarbon products. These photocatalysts can form artificial photosystems and can be incorporated into devices that reduce carbon dioxide and water for production of various fuels. Doped wide-bandgap semiconductor nanotubes are provided along with synthesis methods. A variety of optical, electronic and magnetic dopants (substitutional and interstitial, energetically shallow and deep) are incorporated into hollow nanotubes, ranging from a few dopants to heavily-doped semiconductors. The resulting wide-bandgap nanotubes, with desired electronic (p- or n-doped), optical (ultraviolet bandgap to infrared absorption in co-doped nanotubes), and magnetic (from paramagnetic to ferromagnetic) properties, can be used in photovoltaics, display technologies, photocatalysis, and spintronic applications.

To provide a photocatalyst decomposition apparatus that can supply a liquid phase containing a substance to be decomposed by a photocatalyst and that can perform decomposition of the substance more efficiently than in the related art. A photocatalyst decomposition system according to the invention includes: a gas phase generation apparatus configured to convert a liquid phase containing a decomposition object into a gas phase; and a photocatalyst member configured to come into contact with the gas phase to decompose the decomposition object by light from a light source. The photocatalyst member includes a base material formed of a porous material and a photocatalyst layer provided on a surface of the base material.

To provide a photocatalyst decomposition apparatus that can supply a liquid phase containing a substance to be decomposed by a photocatalyst and that can perform decomposition of the substance more efficiently than in the related art. A photocatalyst decomposition system according to the invention includes: a gas phase generation apparatus configured to convert a liquid phase containing a decomposition object into a gas phase; and a photocatalyst member configured to come into contact with the gas phase to decompose the decomposition object by light from a light source. The photocatalyst member includes a base material formed of a porous material and a photocatalyst layer provided on a surface of the base material.

The present invention provides a semi-conducting biogenic hybrid catalyst capable of reducing CO.sub.2 into fuel precursors. Specifically, the present application involves a method for bio-assisted conversion of CO.sub.2 to fuel precursors using said semiconducting biogenic hybrid catalyst in batch and continuous mode.

The present invention provides a semi-conducting biogenic hybrid catalyst capable of reducing CO.sub.2 into fuel precursors. Specifically, the present application involves a method for bio-assisted conversion of CO.sub.2 to fuel precursors using said semiconducting biogenic hybrid catalyst in batch and continuous mode.

Disclosed is a catalyst and methods for the oxidative coupling of methane (OCM) reaction using elemental sulfur as a soft oxidant. The process can provide ethylene from methane with high conversion and selectivity.

Disclosed is a catalyst and methods for the oxidative coupling of methane (OCM) reaction using elemental sulfur as a soft oxidant. The process can provide ethylene from methane with high conversion and selectivity.

Methods, reactor tubes, reactors, and systems for catalysis are disclosed. A reactor tube includes an outer shell defining a catalyst bed, a catalyst within the catalyst bed, and an inner tube extending through the catalyst bed. An interior of the inner tube is isolated from the catalyst within the catalyst bed. Methods of activating a catalyst are also disclosed herein.