Patent classifications
B01J27/138
Processes for Producing Fluorided Solid Oxides and Uses Thereof in Metallocene-Based Catalyst Systems
Disclosed herein are methods for preparing fluorided solid oxides by contacting an acidic fluorine-containing compound with an inorganic base to form an aqueous mixture having a pH of at least 4, followed by contacting a solid oxide with the aqueous mixture to produce the fluorided solid oxide. Also disclosed are methods for preparing fluorided solid oxides by contacting an acidic fluorine-containing compound with a solid oxide to produce a mixture, followed by contacting the mixture with a inorganic base to produce the fluorided solid oxide at a pH of at least about 4. The fluorided solid oxide can be used as an activator component in a catalyst system for the polymerization of olefins.
MULTIDIMENSIONAL MULTILAYERED UPCONVERSION NANOARCHITECTONICS WITH TUNEABLE ND CONTENT FOR EFFICIENT PHOTOCATALYTIC PHENOLIC DEGRADATION UNDER AMBIENT CONDITIONS
Provided herein are multilayered, multidimensional upconversion nanomaterial compositions and methods. In certain aspects and embodiments, the compositions and methods are useful in the photolytic degradation of a phenolic pollutant (e.g., phenol).
MULTIDIMENSIONAL MULTILAYERED UPCONVERSION NANOARCHITECTONICS WITH TUNEABLE ND CONTENT FOR EFFICIENT PHOTOCATALYTIC PHENOLIC DEGRADATION UNDER AMBIENT CONDITIONS
Provided herein are multilayered, multidimensional upconversion nanomaterial compositions and methods. In certain aspects and embodiments, the compositions and methods are useful in the photolytic degradation of a phenolic pollutant (e.g., phenol).
Processes for Producing Fluorided Solid Oxides and Uses Thereof in Metallocene-Based Catalyst Systems
Disclosed herein are methods for preparing fluorided solid oxides by contacting an acidic fluorine-containing compound with an inorganic base to form an aqueous mixture having a pH of at least 4, followed by contacting a solid oxide with the aqueous mixture to produce the fluorided solid oxide. Also disclosed are methods for preparing fluorided solid oxides by contacting an acidic fluorine-containing compound with a solid oxide to produce a mixture, followed by contacting the mixture with a inorganic base to produce the fluorided solid oxide at a pH of at least about 4. The fluorided solid oxide can be used as an activator component in a catalyst system for the polymerization of olefins.
Processes for Producing Fluorided Solid Oxides and Uses Thereof in Metallocene-Based Catalyst Systems
Disclosed herein are methods for preparing fluorided solid oxides by contacting an acidic fluorine-containing compound with an inorganic base to form an aqueous mixture having a pH of at least 4, followed by contacting a solid oxide with the aqueous mixture to produce the fluorided solid oxide. Also disclosed are methods for preparing fluorided solid oxides by contacting an acidic fluorine-containing compound with a solid oxide to produce a mixture, followed by contacting the mixture with a inorganic base to produce the fluorided solid oxide at a pH of at least about 4. The fluorided solid oxide can be used as an activator component in a catalyst system for the polymerization of olefins.
PREPARATION OF (METH)ACRYLIC ACID ESTERS
The invention relates to a method for preparation of (meth)acrylic acid esters from (meth)acrylic acid anhydrides.
PREPARATION OF (METH)ACRYLIC ACID ESTERS
The invention relates to a method for preparation of (meth)acrylic acid esters from (meth)acrylic acid anhydrides.
Processes for producing fluorided solid oxides and uses thereof in metallocene-based catalyst systems
Disclosed herein are methods for preparing fluorided solid oxides by contacting an acidic fluorine-containing compound with an inorganic base to form an aqueous mixture having a pH of at least 4, followed by contacting a solid oxide with the aqueous mixture to produce the fluorided solid oxide. Also disclosed are methods for preparing fluorided solid oxides by contacting an acidic fluorine-containing compound with a solid oxide to produce a mixture, followed by contacting the mixture with a inorganic base to produce the fluorided solid oxide at a pH of at least about 4. The fluorided solid oxide can be used as an activator component in a catalyst system for the polymerization of olefins.
Processes for producing fluorided solid oxides and uses thereof in metallocene-based catalyst systems
Disclosed herein are methods for preparing fluorided solid oxides by contacting an acidic fluorine-containing compound with an inorganic base to form an aqueous mixture having a pH of at least 4, followed by contacting a solid oxide with the aqueous mixture to produce the fluorided solid oxide. Also disclosed are methods for preparing fluorided solid oxides by contacting an acidic fluorine-containing compound with a solid oxide to produce a mixture, followed by contacting the mixture with a inorganic base to produce the fluorided solid oxide at a pH of at least about 4. The fluorided solid oxide can be used as an activator component in a catalyst system for the polymerization of olefins.
CATALYST FOR PREPARING 2,3,3,3,-TETRAFLUOROPROPENE BY GAS-PHASE HYDRODECHLORINATION
Disclosed is a catalyst for preparing 2,3,3,3-tetrafluoropropene by gas-phase hydrodechlorination, which solves the problem of the high costs and easy deactivation of traditional chlorofluorocarbon hydrodechlorination catalysts. The disclosed catalyst is characterized in consisting of an active component and a carrier, wherein the active component is a combination of one or more of the metals: Ni, Mo, W, Co, Cr, Cu, Ce, La, Mn and Fe. The catalyst in the present invention has excellent performance, high activity, good stability and a low reaction temperature, effectively reduces reaction energy consumption, and has industrial application value.