A catalyst that includes heterogeneous metal carbide nanomaterials and a novel preparation method to synthesize the metal carbide nanomaterials under relatively mild conditions to form an encapsulated transition metal and/or transition metal carbide nanoclusters in a support and/or binder. The catalyst may include confined platinum carbide nanoclusters. The preparation may include the treatment of encapsulated platinum nanoclusters with ethane at elevated temperatures. The catalysts may be used for catalytic hydrocarbon conversions, which include but are not limited to, ethane aromatization, and for selective hydrogenation, with negligible green oil production.

The present invention is directed at the conversion of ammonium nitrate and related compounds upon reaction with methane into compounds such as ethyl acetate, ammonia, nitrogen and hydrogen. The reaction may proceed within a fluid-solid type reactor. The reaction may be facilitated in the presence of inert or catalytic solids.

In a process for steam reforming of oxygenates, especially at low steam-to-carbon (S/C) ratios, a feed gas containing oxygenates, such as ethanol, is converted into syngas over a ternary carbide catalyst. Then the reformed gas is either transformed into desired chemicals or mixed into the feed stream to the reformer in a plant, such as an ammonia or methanol plant. The preferred ternary carbide is nickel zinc carbide.

In a process for steam reforming of oxygenates, especially at low steam-to-carbon (S/C) ratios, a feed gas containing oxygenates, such as ethanol, is converted into syngas over a ternary carbide catalyst. Then the reformed gas is either transformed into desired chemicals or mixed into the feed stream to the reformer in a plant, such as an ammonia or methanol plant. The preferred ternary carbide is nickel zinc carbide.

A method 10 for processing hydrocarbons for recycling includes the steps of: a) heating solid and/or liquid hydrocarbons in a chamber 16 in the absence of air, to convert at least some of the hydrocarbons into hydrocarbon gas; b) reacting the hydrocarbon gas in a reactor 20 or conduit with a catalyst 22 including a transition metal or transition metal salt, and a carbide, to break the hydrocarbon gas down into hydrocarbon products; and c) collecting the hydrocarbon products or conveying the hydrocarbon products elsewhere for use.

In a process for steam reforming of oxygenates, especially at low steam-to-carbon (S/C) ratios, a feed gas containing oxygenates, such as ethanol, is converted into syngas over a ternary carbide catalyst. Then the reformed gas is either transformed into desired chemicals or mixed into the feed stream to the reformer in a plant, such as an ammonia or methanol plant. The preferred ternary carbide is nickel zinc carbide.

In a process for steam reforming of oxygenates, especially at low steam-to-carbon (S/C) ratios, a feed gas containing oxygenates, such as ethanol, is converted into syngas over a ternary carbide catalyst. Then the reformed gas is either transformed into desired chemicals or mixed into the feed stream to the reformer in a plant, such as an ammonia or methanol plant. The preferred ternary carbide is nickel zinc carbide.

The invention is mainly related to a synthesis method of supported two-dimensional transition metal carbides for Fenton-like catalysis, which includes the following steps: (1) preparing two-dimensional transition metal carbides powders; (2) dispersing the two-dimensional transition metal carbides powders into intercalants solution to perform an intercalation reaction, and then centrifuging, washing, and freeze-drying to obtain intercalated products; (3) dispersing a certain quality previously obtained intercalated powders into ultrapure water and heating for pre-reaction, and then adding hydrogen peroxide solution to the pre-reacted mixed solution under ice-water bath for secondary etching, resting, centrifuging and gently decanting a supernatant to obtain the final Fenton-like catalysts.

The invention is mainly related to a synthesis method of supported two-dimensional transition metal carbides for Fenton-like catalysis, which includes the following steps: (1) preparing two-dimensional transition metal carbides powders; (2) dispersing the two-dimensional transition metal carbides powders into intercalants solution to perform an intercalation reaction, and then centrifuging, washing, and freeze-drying to obtain intercalated products; (3) dispersing a certain quality previously obtained intercalated powders into ultrapure water and heating for pre-reaction, and then adding hydrogen peroxide solution to the pre-reacted mixed solution under ice-water bath for secondary etching, resting, centrifuging and gently decanting a supernatant to obtain the final Fenton-like catalysts.

Described herein are coatings. The coatings can, for example, catalyze carbon gasification. In some examples, the coatings comprise: a first region having a first thickness, the first region comprising a manganese oxide, a chromium-manganese oxide, or a combination thereof; a second region having a second thickness, the second region comprising Ni, Fe, W, Cr, Co, Mn, Ti, Mo, V, Nb, Zr, Si, C, or a combination thereof; and an alkaline earth metal, an alkaline earth oxide, an alkaline earth carbonate, an alkaline earth silicate, molybdemun, a molybdenum oxide, a molybdenum carbide, a mixed-metal perovskite, a mixed metal inorganic oxide, or a combination thereof.