A catalyst for pyrolysis of 1,2-dichloroethane (1,2-DCE) to prepare vinyl chloride monomer (VCM), a preparation method, a use, and a regeneration method thereof are provided. The catalyst for pyrolysis of 1,2-DCE to prepare VCM includes a silicon-aluminum molecular sieve. The catalyst for pyrolysis of 1,2-DCE to prepare VCM has high reaction activity and excellent selectivity and solves the problem that the pyrolysis of 1,2-DCE to prepare VCM in the prior art involves high reaction temperature and large energy consumption and is prone to coking and carbon deposition.

A hydrogenolysis bimetallic supported catalyst comprising a first metal, a second metal, and a zeolitic support; wherein the first metal and the second metal are different; and wherein the first metal and the second metal can each independently be selected from the group consisting of iridium (Ir), platinum (Pt), rhodium (Rh), ruthenium (Ru), palladium (Pd), molybdenum (Mo), tungsten (W), nickel (Ni), and cobalt (Co).

This exhaust gas purifying catalyst is provided with a substrate and a catalyst layer formed on a surface of the substrate. The catalyst layer contains zeolite particles that support a metal, and a rare earth element-containing compound that contains a rare earth element. The rare earth element-containing compound is added in such an amount that the molar ratio of the rare earth element relative to Si contained in the zeolite is 0.001 to 0.014 in terms of oxides.

A method for producing a crystalline film comprising zeolite and/or zeolite-like crystals on a porous substrate is described. The method has the steps of: providing a porous support; modifying at least a surface of the top-layer of said porous support by treatment with a composition having one or more cationic polymer(s); rendering at least the outer surface of said porous support hydrophobic by treatment with a composition having one or more hydrophobic agent(s); subjecting said treated porous support to a composition having zeolite and/or zeolite-like crystals thereby depositing and attaching zeolite and/or zeolite-like crystals on said treated porous support, and growing a crystalline film of zeolite and/or zeolite-like crystals on said treated porous support and calcination. Crystalline films find use in a variety of fields such as in the production of membranes, catalysts etc.

A method for producing a crystalline film comprising zeolite and/or zeolite-like crystals on a porous substrate is described. The method has the steps of: providing a porous support; modifying at least a surface of the top-layer of said porous support by treatment with a composition having one or more cationic polymer(s); rendering at least the outer surface of said porous support hydrophobic by treatment with a composition having one or more hydrophobic agent(s); subjecting said treated porous support to a composition having zeolite and/or zeolite-like crystals thereby depositing and attaching zeolite and/or zeolite-like crystals on said treated porous support, and growing a crystalline film of zeolite and/or zeolite-like crystals on said treated porous support and calcination. Crystalline films find use in a variety of fields such as in the production of membranes, catalysts etc.

A small-pore zeolite that is modified with phosphorus, is excellent in hydrothermal durability, and has an 8-membered oxygen ring structure. The 8-membered oxygen ring structure is CHA, AEI, and AFX. The small-pore zeolite incudes at least an aluminum element, a silica element, a phosphorus element, wherein the phosphorus element is defined by expression (1), and the small-pore zeolite has an 8-membered oxygen ring structure being of CHA, AEI, or AFX. The phosphorus element that modifies the zeolite is unevenly distributed and richly contained on the surface layer side of the zeolite. A method for producing a phosphorus element-containing zeolite.

A small-pore zeolite that is modified with phosphorus, is excellent in hydrothermal durability, and has an 8-membered oxygen ring structure. The 8-membered oxygen ring structure is CHA, AEI, and AFX. The small-pore zeolite incudes at least an aluminum element, a silica element, a phosphorus element, wherein the phosphorus element is defined by expression (1), and the small-pore zeolite has an 8-membered oxygen ring structure being of CHA, AEI, or AFX. The phosphorus element that modifies the zeolite is unevenly distributed and richly contained on the surface layer side of the zeolite. A method for producing a phosphorus element-containing zeolite.

Provided is a titanium oxide composition that has a high capability to decompose odor-causing substances, is less likely to cause re-emission of an odor-causing substance(s) due to adsorption of water, and exhibits an excellent particle dispersion stability. The titanium oxide composition contains titanium oxide particles, a component A and a component B. The component A is at least one kind selected from a group of sepiolite and attapulgite, and the component B is at least one kind selected from a group of high silica zeolite and hydrophobic silica. A mass ratio of the component A to the titanium oxide particles is 0.75 to 3.25, and a mass ratio of the component B to the component A is 0.25 to 3.0. Also provided is a member having such titanium oxide composition on its surface.

Provided is a titanium oxide composition that has a high capability to decompose odor-causing substances, is less likely to cause re-emission of an odor-causing substance(s) due to adsorption of water, and exhibits an excellent particle dispersion stability. The titanium oxide composition contains titanium oxide particles, a component A and a component B. The component A is at least one kind selected from a group of sepiolite and attapulgite, and the component B is at least one kind selected from a group of high silica zeolite and hydrophobic silica. A mass ratio of the component A to the titanium oxide particles is 0.75 to 3.25, and a mass ratio of the component B to the component A is 0.25 to 3.0. Also provided is a member having such titanium oxide composition on its surface.

An exhaust gas heating unit for an exhaust system of an internal combustion engine includes a jacket heating conductor element (12) with a jacket (16) and with an electrical heating conductor (14). The electrical heating conductor (14) extends in the jacket (16) and is surrounded by insulating material (18). A heat transfer surface formation (20) is arranged on an outer side of the jacket (16) and is in heat transfer contact with same.