B01J29/83

HYBRID CATALYSTS COMPRISING A ZEOLITE AND A MIXED METAL OXIDE COMPONENT FOR CONVERTING SYNGAS INTO C2 AND C3 OLEFINS

A hybrid catalyst including a metal oxide catalyst component comprising chromium, zinc, and at least one additional metal selected from the group consisting of aluminum and gallium, and a microporous catalyst component that is a molecular sieve having 8-MR pore openings. The metal oxide catalyst component includes anatomic ratio of chromium:zinc (Cr:Zn) from 0.35 to 1.00, and the at least one additional metal is present in an amount from 25.0 at % to 40.0 at %. A process for preparing C2 and C3 olefins comprising: a) introducing a feed stream comprising hydrogen gas and a carbon-containing gas selected from the group consisting of carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor; and b) converting the feed stream into a product stream comprising C2 and C3 olefins in the reaction zone in the presence of said hybrid catalyst.

HYBRID CATALYSTS COMPRISING A MIXED METAL OXIDE COMPONENT FOR PRODUCTION OF C2 AND C3 HYDROCARBONS

A hybrid catalyst including a metal oxide catalyst component comprising chromium, zinc, and at least one additional metal selected from the group consisting of iron and manganese, and a microporous catalyst component that is a molecular sieve having 8-MR pore openings. The at least one additional metal is present in an amount from 5.0 at % to 20.0 at %.

Aromatization catalyst, preparation method, regeneration method thereof, and aromatization method

The present disclosure provides an aromatization catalyst, a preparation method, a regeneration method and an aromatization method thereof. The preparation method comprises steps of: mixing a zeolite molecular sieve with a binder to obtain a catalyst precursor; the catalyst precursor is successively subjected to an ion exchange modification and a first modification treatment, and then subjected to a hydrothermal treatment, and further subjected to active metal loading and a second modification treatment, to obtain the aromatization catalyst. The aromatization catalyst has good carbon deposition resistance and high aromatization activity, and enables an aromatization reaction to be completed under mild conditions, and has high aromatic selectivity, and the liquid yield is above 98.5%.

Aromatization catalyst, preparation method, regeneration method thereof, and aromatization method

The present disclosure provides an aromatization catalyst, a preparation method, a regeneration method and an aromatization method thereof. The preparation method comprises steps of: mixing a zeolite molecular sieve with a binder to obtain a catalyst precursor; the catalyst precursor is successively subjected to an ion exchange modification and a first modification treatment, and then subjected to a hydrothermal treatment, and further subjected to active metal loading and a second modification treatment, to obtain the aromatization catalyst. The aromatization catalyst has good carbon deposition resistance and high aromatization activity, and enables an aromatization reaction to be completed under mild conditions, and has high aromatic selectivity, and the liquid yield is above 98.5%.

SCR CATALYST FOR THE TREATMENT OF AN EXHAUST GAS OF A DIESEL ENGINE

An SCR catalyst for treating diesel exhaust gas has: a flow-through substrate with an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end and a plurality of passages defined by internal walls of the flow through substrate extending therethrough; a first coating disposed on the internal wall surface of the substrate, the surface defining the interface between the internal walls and passages, the first coating extending over 40 to 100% of the substrate axial length, the first coating having an 8-membered ring pore zeolitic material with copper and/or iron; a second coating extending over 20 to 100% of the substrate axial length, the second coating having a first oxidic material with titania, wherein at least 75 wt. % of the second coating is titania, calculated as TiO.sub.2, and 0 to 0.01 wt. % of the second coating is vanadium oxides, calculated as V.sub.2O.sub.5.

PALLADIUM/ZEOLITE-BASED PASSIVE NITROGEN OXIDE ADSORBER CATALYST FOR PURIFYING EXHAUST GAS

The invention relates to a catalyst which comprises a carrier substrate, palladium, and a zeolite, the largest channels of which are formed by 10 tetradrically coordinated atoms; to the use of said catalyst as a passive nitrogen oxide adsorber, an exhaust gas system which contains said catalyst and an SCR catalyst, and to a method for purifying the exhaust gas of motor vehicles using said exhaust gas system.

CATALYST AND METHOD FOR PREPARING LIGHT OLEFIN USING DIRECT CONVERSION OF SYNGAS
20210121859 · 2021-04-29 ·

A catalyst for preparing light olefin using direct conversion of syngas is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide; and the component II is one or more than one of zeolite of CHA and AEI structures or metal modified CHA and/or AEI zeolite. A weight ratio of the active ingredients in the component Ito the component II is 0.1-20. The reaction process has high product yield and selectivity, wherein the sum of the selectivity of the propylene and butylene reaches 40-75%; and the sum of the selectivity of light olefin comprising ethylene, propylene and butylene can reach 50-90%. Meanwhile, the selectivity of a methane side product is less than 15%.

CATALYST AND METHOD FOR PREPARING LIGHT OLEFIN USING DIRECT CONVERSION OF SYNGAS
20210121859 · 2021-04-29 ·

A catalyst for preparing light olefin using direct conversion of syngas is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide; and the component II is one or more than one of zeolite of CHA and AEI structures or metal modified CHA and/or AEI zeolite. A weight ratio of the active ingredients in the component Ito the component II is 0.1-20. The reaction process has high product yield and selectivity, wherein the sum of the selectivity of the propylene and butylene reaches 40-75%; and the sum of the selectivity of light olefin comprising ethylene, propylene and butylene can reach 50-90%. Meanwhile, the selectivity of a methane side product is less than 15%.

MIXED ZEOLITE-CONTAINING SCR CATALYST
20210114007 · 2021-04-22 · ·

The present disclosure generally provides selective catalytic reduction (SCR) catalyst compositions, catalyst articles and catalyst systems including such catalyst articles for treating engine exhaust gas. In particular, the SCR catalyst composition includes a first zeolite and a second zeolite and has not been subjected to temperatures above 650° C. The first zeolite includes a promoter metal and has a first framework structure and at least a portion of the second zeolite is in a form selected from H.sup.+ form, NH.sub.4.sup.+ form, alkali metal form, alkaline earth metal form, and combinations thereof and has a second framework structure. The first framework structure and the second framework structure are different.

Aluminophosphate-based zeolite membrane synthesis method

A method of synthesis for an aluminophosphate-based zeolite membrane includes a steps of preparing a mixed solution with a pH greater than or equal to 6 and less than or equal to 9 by mixing an acidic phosphorous source with an alkali source, a steps of preparing a starting material solution by adding and mixing an aluminum source to the prepared mixed solution, and a steps of synthesizing an aluminophosphate-based zeolite membrane by hydrothermally synthesizing the starting material solution.