Provided herein are methods of catalytic hydrosilylation, including triggerable methods, using metal-ligand complexes as catalysts, characterized by formula ML.sub.xD.sub.y; wherein: M is a metal; x is equal to the oxidation state of M; each D is independently a neutral coordinating ligand; y is zero or an integer selected from the range of 1 to 4; and each L is independently a mono-anionic ligand. L may be a .sup.1,.sup.2-,-disubstituted--alkenyl ligand.

Provided are a novel indene-based transition metal complex, a transition metal catalyst composition including the same having high catalyst activity for preparing an ethylene homopolymer or copolymers of ethylene and one or more -olefins, a method for preparing an ethylene homopolymer or copolymers of ethylene and -olefins using the same, and the thus-prepared ethylene homopolymer or copolymers of ethylene and -olefins.

The invention relates to a process for the metathesis of olefins implemented with a catalyst comprising a mesoporous matrix and at least the elements molybdenum and silicon, said elements being incorporated into said matrix by means of at least one precursor comprising molybdenum and silicon and having at least one sequence of SiOMo bonds.

A resin composition includes: (a) a supported platinum catalyst having a structure shown by the following general formula (1) in which a platinum complex is supported on a surface of an inorganic oxide; and (b) a thermoplastic matrix resin. The resin composition is usable as an addition-reaction catalyst capable of imparting sufficient storability and quick curability to an addition-reaction curable composition. ##STR00001##
In the formula, L represents a ligand selected from carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound, and an isocyanide compound; and n represents the number of Ls and an integer from 0 to 2.

A curable organopolysiloxane composition containing dynamic covalent organopolysiloxanes which yields, upon cure, a silicone rubber having adaptive elastomeric and viscous characteristics is claimed. The silicone may be an elastomer or foam. A method of making the silicone rubber and a shaped article made of the cured adaptive viscoelastic silicone rubber composition are also claimed.

A process can prepare an isocyanurate compound by hydrosilylation. The compound is a tris[3-(trialkoxysilyl)propyl] isocyanurate, a tris[3-(alkyldialkoxysilyl)propyl] isocyanurate, and/or a tris[3-(dialkylalkoxysilyl)propyl] isocyanurate, The process includes (A) preparing a mixture of at least one carboxylic acid, a platinum catalyst, and 1,3,5-triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione; (B) heating the mixture to a temperature in the range of 40 to 140 C.; (C) adding at least one H-silane among a hydrotrialkoxysilane, a hydroalkyldialkoxysilane, and a hydrodialkylalkoxysilane to the mixture; (D) adding at least one alcohol to the mixture prepared in step (C); and (E) isolating the isocyanurate compound.

A process can prepare an isocyanurate compound by hydrosilylation. The compound is a tris[3-(trialkoxysilyl)propyl] isocyanurate, a tris[3-(alkyldialkoxysilyl)propyl] isocyanurate, and/or a tris[3-(dialkylalkoxysilyl)propyl] isocyanurate, The process includes (A) preparing a mixture of at least one carboxylic acid, a platinum catalyst, and 1,3,5-triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione; (B) heating the mixture to a temperature in the range of 40 to 140 C.; (C) adding at least one H-silane among a hydrotrialkoxysilane, a hydroalkyldialkoxysilane, and a hydrodialkylalkoxysilane to the mixture; (D) adding at least one alcohol to the mixture prepared in step (C); and (E) isolating the isocyanurate compound.

Silica-coated alumina activator-supports, and catalyst compositions containing these activator-supports, are disclosed. Methods also are provided for preparing silica-coated alumina activator-supports, for preparing catalyst compositions, and for using the catalyst compositions to polymerize olefins.

Silica-coated alumina activator-supports, and catalyst compositions containing these activator-supports, are disclosed. Methods also are provided for preparing silica-coated alumina activator-supports, for preparing catalyst compositions, and for using the catalyst compositions to polymerize olefins.

A catalyst for the hydroformylation of at least one olefin, having a ligand fo the general formula (1) R.sup.1, R.sup.2, R.sup.3 selected from the group including substituted and non-substituted alkyl, substituted and non-substituted aryl, substituted and non-substituted alkenyl, substituted and non-substituted alkinyl, substituted and non-substituted cycloalkyl, and substituted and non-substituted heterocycles, wherein R.sup.1, R.sup.2 and R.sup.3 can each be the same or different, L is selected from a group having a sandwich complex, an oxygen group, substituted and non-substituted alkylene or heterocycles, and substituted aryl or heteroaryl; and aryl and heteroaryl is each substituted with groups which contain at least two heteroatoms and are coupled to the Si via the at least two heteroatoms of the substituents, n=1-10, preferably 1-5, particularly preferably 1, 2, or 3; and the ligand is coupled to the metal M from the group VIIIb of the periodic table of elements via the Si group.